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    • 4. 发明申请
    • NOVEL N-P-PROPARGYLOXYPHENETHYL-THIOACETIC ACID AMIDES
    • 新型N-对 - 丙烯酰氧基苯乙酸 - 柠檬酸
    • WO2002081437A2
    • 2002-10-17
    • PCT/EP2002/003623
    • 2002-04-02
    • SYNGENTA PARTICIPATIONS AGKUNZ, WalterLAMBERTH, ClemensCEDERBAUM, FredrikZELLER, Martin
    • KUNZ, WalterLAMBERTH, ClemensCEDERBAUM, FredrikZELLER, Martin
    • C07C327/44
    • C07C327/44A01N37/36A01N43/08A01N43/10A01N43/12A01N43/30A01N43/32A01N43/40A01N43/54
    • The invention relates to N-propargyloxy-phenethyl thioacetic acid amide derivatives of the general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein R 1 is hydrogen, alkyl, cycloalkyl or optionally substituted aryl, R 2 and R 3 are each independently hydrogen or alkyl, R 4 is alkyl, alkenyl or alkynyl, R 5 , R 6 , R 7 and R 8 are each independently hydrogen or alkyl, R 9 is hydrogen, optionally substituted alkyl, optionally substituted alkenyl or optionally substituted alkynyl, R 10 is optionally substituted aryl or optionally substituted heteroaryl, and Z is hydroxy, optionally substituted aryloxy, optionally substituted alkoxy, optionally substituted alkynyloxy, optionally substituted arylthio, optionally substituted alkylthio, optionally substituted alkynylthio, optionally substituted alkylsulfinyl, optionally substituted alkenysulfinyl, optionally substituted alkynylsulfinyl, optionally substituted alkylsulfonyl, optionally substituted alkenylsulfonyl, optionally substituted alkynylsulfonyl or a group -O-CO-R 11 , -O-CO-O-R 11 or -O-CO -CO-O-R 11 wherein R 11 is hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted heteroaryl. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.
    • 本发明涉及通式(I)的N-炔丙氧基 - 苯乙基硫代乙酰胺衍生物,其包括其旋光异构体和这些异构体的混合物,其中R 1为氢,烷基,环烷基或任选取代的芳基,R 2和R 3各自独立地为 氢或烷基,R4是烷基,烯基或炔基,R5,R6,R7和R8各自独立地是氢或烷基,R9是氢,任选取代的烷基,任选取代的烯基或任选取代的炔基,R 10是任选取代的芳基或任选取代的 杂芳基,Z是羟基,任选取代的芳氧基,任选取代的烷氧基,任选取代的炔氧基,任选取代的芳硫基,任选取代的烷硫基,任选取代的炔硫基,任选取代的烷基亚磺酰基,任选取代的烯基亚磺酰基,任选取代的炔基亚磺酰基,任选取代的烷基磺酰基, ,选择 取代的炔基磺酰基或基团-O-CO-R11,-O-CO-O-R11或-O-CO-CO-O-R11,其中R11是氢,任选取代的烷基,任选取代的环烷基,任选取代的芳基或任选地 取代的杂芳基。 这些化合物具有有用的植物保护性质,并且可有利地用于农业实践中以控制或防止植物病原微生物特别是真菌侵染植物。