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    • 1. 发明申请
    • MICROWAVE DIELECTRIC CERAMIC COMPOSITION
    • 微波电介质陶瓷组合物
    • WO2002059058A1
    • 2002-08-01
    • PCT/JP2001/003588
    • 2001-04-25
    • SUMITOMO SPECIAL METALS CO., LTDFUKAGAWA, TomokiNISHIKAWA, Kazuhiro
    • FUKAGAWA, TomokiNISHIKAWA, Kazuhiro
    • C04B35/462
    • C04B35/475C04B35/462C04B35/465C04B35/50C04B35/6262C04B2235/3201C04B2235/3203C04B2235/3208C04B2235/3213C04B2235/3224C04B2235/3227C04B2235/3232C04B2235/3298
    • An object of the present invention is to obtain a dielectric ceramic composition wherein the dielectric constant ε is large, the temperature coefficient τf of the resonance frequency is close to 0, and which has a large Q value, by adding to and blending with a ceramic composition whose τf of the resonance frequency is large on the plus side a ceramic composition whose temperature coefficient τf is large on the minus side. In an Li 2 O-R 2 O 3 -TiO 2 -based composition where R is one or two or more of Nd, Sm, Pr and La, an improved dielectric constant ε can be achieved by introducing a specific quantity of Bi 2 O 3 , and τf can be shifted to the plus side and in addition a considerable improvement in Qf achieved by introducing a specific quantity of MO (where M is one or two of Ca and Sr). Furthermore, by introducing a specific quantity of Na 2 O together with the MO (where M is one or two of Ca and Sr), in particular in the case of material of εr≥ 150, it is possible to control τf to the vicinity of 0 while maintaining Qf at an high value.
    • 本发明的目的是获得介电常数εε大的谐振频率的温度系数τf接近于0并具有大的Q值的介电陶瓷组合物,通过加入和掺合 在负侧的温度系数τf大的陶瓷组合物的正面上的谐振频率的τf大的陶瓷组合物。 在其中R是Nd,Sm,Pr和La中的一种或两种以上的Li> 2 2 <3> < - TiO 2>组合物中,可以通过引入改进的介电常数ε 特定量的Bi> 2O 3,并且tau f可以转移到正侧,另外通过引入特定量的MO(其中M是Ca和Sr中的一个或两个)实现的Qf的显着改善, 。 此外,通过与MO(其中M是Ca和Sr的一个或两个)一起引入特定量的Na 2 O 3,特别是在εr = 150的材料的情况下,可以控制 τf保持在0附近,同时保持Qf为高值。