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    • 2. 发明公开
    • AUSTENITIC HEAT-RESISTANT ALLOY
    • WÄRMEBESTÄNDIGEAUSTENITISCHE LEGIERUNG
    • EP2511389A1
    • 2012-10-17
    • EP10835974.6
    • 2010-12-08
    • Sumitomo Metal Industries, Ltd.
    • HIRATA, HiroyukiOKADA, HirokazuSEMBA, HiroyukiOGAWA, KazuhiroISEDA, AtsuroYOSHIZAWA, Mitsuru
    • C22C19/05
    • C22C19/055
    • An austenitic heat resistant alloy consisting of, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 0.03 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 4%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 3% or less, Ti: 3% or less, and Nb: 3% or less, the balance being Fe and impurities, and the contents of P and S in the impurities being P: 0.03% or less and S: 0.01% or less, wherein the alloy satisfies 1 ≤ 4xAl + 2xTi + Nb ≤ 12 and P + 0.2×Cr×B ≤ 0.035, is excellent in both of weld crack resistance and toughness of HAZ, and is further excellent in creep strength at high temperatures.
    • 一种奥氏体系耐热合金,以质量%计含有C:0.15%以下,Si:2%以下,Mn:3%以下,Ni:40〜60%,Co:0.03〜25%,Cr:15 %以上且小于28%,Mo:12%以下,W:小于4%,其总含量为0.1〜12%,Nd:0.001〜0.1%,B:0.0005〜0.006 %,N:0.03%以下,O:0.03%以下,选自Al:3%以下,Ti:3%以下,Nb:3%以下,余量为Fe和杂质, 杂质中P和S的含量为:0.03%以下,S:0.01%以下,其中合金满足1‰×4×Al + 2×Ti + Nb‰12,P + 0.2×Cr×B‰¤ 0.035,在焊接龟裂性和HAZ的韧性方面都优异,并且在高温下的蠕变强度更优异。
    • 6. 发明公开
    • HIGH-STRENGTH WELDED STEEL STRUCTURES HAVING EXCELLENT CORROSION RESISTANCE
    • HCHFESTE,GESCHWEISSTE STAHLSTRUKTUREN MIT HERVORRAGENDEM KORROSIONSWIDERSTAND
    • EP0864663A1
    • 1998-09-16
    • EP96932043.1
    • 1996-09-27
    • SUMITOMO METAL INDUSTRIES, LTD.
    • UEDA, MasakatsuOGAWA, KazuhiroKONDO, KunioIGARASHI, Masaaki
    • C22C38/00C22C38/18C22C38/44C22C38/50B23K9/167B23K9/173
    • B23K35/3086Y10T428/12965Y10T428/12979
    • High-strength welded steel structures having excellent SSC and corrosion resistances in a wet carbon dioxide environment having a low H 2 S concentration. (1) A structure having a Vickers hardness of at most 350 and a joint tensil strength of at least 620 Mpa and composed of a base metal comprising a martensitic stainless steel with a martensitic or tempered martensitic structure containing 0.001 to 0.05 % C and 9 to 14 % Cr and a weld metal comprising an austenitic-ferritic stainless steel having a duplex structure composed of austenite and 35 to 75 % by volume of ferrite and containing 22 to 27 % Cr, 7 to 11 % Ni and 1.5 to 5 % Mo, and at most 0.03 % C as an impurity. (2) Another structure according to the above item (1), wherein the base metal comprises the elements described in the above item (1) and further comprises Mn, Ni, sol. Al, Mo, Cu, Ti or the like, and Fe and the weld metal comprises the elements described in the above item (1) and further comprises sol. Al, N, Cu, W or the like, and Fe. (3) Still another structure according to the above item (2), wherein the content of C, Mn, Cr or the like of the base metal is further limited to a narrower range, and so is the content of Mn, Cu, W or the like.
    • 在具有低H2S浓度的湿二氧化碳环境中具有优异的SSC和耐腐蚀性的高强度焊接钢结构。 (1)维氏硬度在350以下且结合张力强度为至少620Mpa的结构体,由含有马氏体或回火马氏体组织的马氏体系不锈钢构成,该马氏体系不锈钢含有0.001〜0.05%的C和9〜 14%Cr和包含由奥氏体和35〜75体积%铁素体组成的双相组织的奥氏体 - 铁素体不锈钢的焊接金属,含有22〜27%的Cr,7〜11%的Ni和1.5〜5%的Mo, 和最多0.03%的C作为杂质。 (2)根据上述(1)所述的另一种结构,其中所述贱金属包括上述(1)中所述的元素,并且还包含Mn,Ni,sol。 Al,Mo,Cu,Ti等,Fe和焊接金属包含上述(1)所述的元素,还含有溶胶。 Al,N,Cu,W等,Fe。 (3)根据上述(2)所述的另一种结构,其中所述贱金属的C,Mn,Cr等的含量进一步限制在较窄的范围内,Mn,Cu,W的含量 或类似物。
    • 7. 发明公开
    • TWO-PHASE STAINLESS STEEL
    • 两相不锈钢
    • EP2476771A1
    • 2012-07-18
    • EP10815306.5
    • 2010-09-01
    • Sumitomo Metal Industries, Ltd.
    • AMAYA, HisashiTAKABE, HidekiOGAWA, Kazuhiro
    • C22C38/00C22C38/58
    • C22C38/44C22C1/02C22C38/001C22C38/02C22C38/42C22C38/58
    • [Problem to be Solved]
      To provide a duplex stainless steel excellent in the weldability during large heat input welding and excellent in the stress corrosion cracking resistance in a chloride environment containing corrosive associated gases.
      [Solution]
      A duplex stainless steel that has a chemical composition consisting, by mass%, of C: 0.03% or less, Si: 0.2 to 1%, Mn: 5.0% or less, P: 0.040% or less, S: 0.010% or less, sol. Al: 0.040% or less, Ni: 4 to 8%, Cr: 20 to 28%, Mo: 0.5 to 2.0%, Cu: more than 2.0% and 4.0% or less and N: 0.1 to 0.35%, and optionally contains one or more selected from among V, Ca, Mg, B and a rare earth metal(s), with the balance being Fe and impurities; wherein the duplex stainless steel satisfies the relations of the following formulas (1) and (2):


      wherein the symbols of elements in formulas (1) and (2) respectively represent the contents (unit: mass%) of the elements in the steel.
    • [要解决的问题]提供一种双相不锈钢,其在大的热输入焊接期间的焊接性优异,并且在含有腐蚀性伴生气体的氯化物环境中具有优异的抗应力腐蚀开裂性。 [解决方案]一种双相不锈钢,其特征在于,以质量%计含有C:0.03%以下,Si:0.2〜1%,Mn:5.0%以下,P:0.040%以下,S:0.010 %或更少,sol。 Al:0.040%以下,Ni:4〜8%,Cr:20〜28%,Mo:0.5〜2.0%,Cu:超过2.0%且4.0%以下,N:0.1〜0.35% 一种或多种选自V,Ca,Mg,B和一种或多种稀土金属,余量为Fe和杂质; 其中所述双相不锈钢满足下式(1)和(2)的关系:其中式(1)和(2)中的元素的符号分别表示钢中元素的含量(单位:质量%) 。
    • 10. 发明公开
    • AUSTENITIC STAINLESS STEEL
    • 奥氏体不锈钢
    • EP2199419A1
    • 2010-06-23
    • EP08836524.2
    • 2008-10-02
    • Sumitomo Metal Industries, Ltd.
    • HIRATA, HiroyukiOGAWA, KazuhiroOSUKI, TakahiroOKADA, HirokazuSEMBA, Hiroyuki
    • C22C38/00C22C38/60
    • C22C38/001C22C38/02C22C38/04C22C38/06C22C38/46C22C38/48C22C38/50C22C38/52C22C38/54
    • An austenitic stainless steel, which comprises by mass%, C: 0.04 to 0.18%, Si ≤ 1.5%, Mn ≤ 2.0%, Ni: 6 to 30%, Cr: 15 to 30%, N: 0.03 to 0.35%, sol. Al ≤ 0.03% and further contains one or more elements selected from Nb ≤ 1.0%, V ≤ 0.5% and Ti ≤ 0.5%, with the balance being Fe and impurities, and among the impurities P ≤ 0.04%, S ≤ 0.03%, Sn ≤ 0.1%, As ≤ 0.01%, Zn 0.01%, Pb ≤ 0.01% and Sb ≤ 0.01%, and satisfy the conditions P1 = S + {(P + Sn)/2} + {(As + Zn + Pb + Sb)/5) ≤ 0.06 and 0.2 ≤ P2 = Nb + 2(V + Ti) ≤ 1.7 - 10 × P1 has high strength and excellent resistance to cracking due to grain boundary embrittlement in the welded portion during the use at high temperatures. Therefore, the said steel can be suitably used as materials for constructing machines and equipment, such as power plant boilers, which are to be used at high temperatures for a long period of time.
    • 以质量%计,含有C:0.04〜0.18%,Si≤1.5%,Mn≤2.0%,Ni:6〜30%,Cr:15〜30%,N:0.03〜0.35%的奥氏体系不锈钢,sol 。 Al≤0.03%,还含有选自Nb≤1.0%,V≤0.5%和Ti≤0.5%中的一种或多种元素,余量为Fe和杂质,其中杂质P≤0.04%,S≤0.03% Sn≤0.1%,As≤0.01%,Zn <0.01%,Pb≤0.01%,Sb≤0.01%,且满足条件P1 = S + {(P + Sn)/ 2} + {(As + Zn + Pb + Sb)/ 5)≤0.06和0.2≤P2= Nb + 2(V + Ti)≤1.7-10×P1具有高强度和优异的抗高温使用期间由于焊接部分的晶界脆化引起的开裂 。 因此,上述钢适合用作构筑长期高温使用的电厂锅炉等机械设备的材料。