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    • 1. 发明申请
    • EXHAUST GAS PROCESSING METHOD
    • 排气处理方法
    • WO1998015340A1
    • 1998-04-16
    • PCT/JP1997003641
    • 1997-10-09
    • SUMITOMO HEAVY INDUSTRIES, LTD.
    • SUMITOMO HEAVY INDUSTRIES, LTD.TAKAHASHI, KazuyoshiYAMADA, ShinichiGOTOU, KouheiWATANABE, TeruoTANAKA, Hiromi
    • B01D53/86
    • B01D53/8609B01D53/88B01D2251/2062
    • To prevent large quantities of ammonia gas from mixing into a collected sulfur oxide, an exhaust gas processing is carried out by dividing an exhaust gas flow into a plurality of branches, charging an ammonia gas into predetermined ones of these branched exhaust gas flows and supplying the exhaust gas into which the ammonia gas is charged to a predetermined portion of a transverse moving layer (52) in which a carbonaceous catalyst is accommodated. The charging quantity of the ammonia gas is adjusted so that the molar ratio of NH4 /S4O absorbed to the carbonaceous catalyst discharged from the bottom of the moving layer (52) and supplied to a regenerator (18) becomes not greater than 1. Since the carbonaceous catalyst absorbs SO4 as the moving layer (52) moves down, the molar ratio of NH4 /SO4 in the carbonaceous catalyst discharged from a moving layer reactor (11) becomes sufficiently small.
    • 为了防止大量氨气混入收集的硫氧化物中,废气处理通过将排气流分成多个分支,将氨气充入这些分支排气流中的预定的一部分,并将 其中氨气被加入其中容纳有碳质催化剂的横向移动层(52)的预定部分的废气。 调节氨气的填充量,使从吸附到移动层(52)的底部排出并供给到再生器(18)的碳质催化剂的NH 4+ / SO 4 2-的摩尔比变成为再生器(18) 不大于1.由于随着移动层(52)向下移动,碳质催化剂吸收SO4 <2->,从移动层反应器排出的碳质催化剂中NH4 + / SO4 <2->的摩尔比 11)变得足够小。
    • 3. 发明公开
    • EXHAUST GAS PROCESSING METHOD
    • 方法ZUR ABGASBEHANDLUNG
    • EP0882491A1
    • 1998-12-09
    • EP97943173.1
    • 1997-10-09
    • SUMITOMO HEAVY INDUSTRIES, LTD.
    • TAKAHASHI, KazuyoshiYAMADA, Shinichi, 1416-4, SusugayaGOTOU, KouheiWATANABE, TeruoTANAKA, Hiromi
    • B01D53/86
    • B01D53/8609B01D53/88B01D2251/2062
    • An exhaust gas treatment process capable of preventing mixture of a large amount of ammonia gas into collected sulfur oxides. An exhaust gas flow is divided into a plurality of exhaust gas flows. Ammonia gas is introduced into exhaust gas of a predetermined exhaust gas flow among the exhaust gas flows. The exhaust gas into which ammonia gas has been introduced is charged for treatment into a predetermined portion of the crossflow type moving layer 52 which accommodates the carbonaceous catalyst. The amount of the ammonia gas that is introduced into exhaust gas is adjusted such that the mole ratio between NH 4 + and SO 4 2- (NH 4 + / SO 4 2- ) adsorbed on the carbonaceous catalyst which is discharged from the bottom portion of the moving layer 52 and charged into a regenerator 18 becomes 1 or less. As the carbonaceous catalyst moves downward in the moving layer 52, the carbonaceous catalyst adsorbs SO 4 2- . Accordingly, the NH 4 + / SO 4 2- mole ratio becomes sufficiently low on the carbonaceous catalyst discharged from a moving-layer reactor 11.
    • 能够防止大量氨气混入收集的硫氧化物中的排气处理工序。 排气流被分成多个废气流。 氨气被引入废气流中的预定废气流的排气中。 向其中引入氨气的废气被加料到容纳碳质催化剂的交叉流动型移动层52的预定部分中。 调节引入排气中的氨气的量,使得吸附在排出的碳质催化剂上的NH 4 +与SO 4 2-(NH 4 + / SO 4 2-)之间的摩尔比 从移动层52的底部充入再生器18中,为1以下。 随着碳质催化剂在移动层52中向下移动,碳质催化剂吸附SO 4 2-。 因此,从移动层反应器11排出的碳质催化剂上的NH 4 + / SO 4 2-摩尔比变得足够低。