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1. 发明授权

US3920770A Rubber modified polyphenylene oxide composition 失效
标题翻译：橡胶改性聚苯乙烯氧化物组合物
公开(公告)号：US3920770A
公开(公告)日：1975-11-18
申请号：US88404169
申请日：1969-12-10
申请人： SUMITOMO CHEMICAL CO
发明人： NAKASHIO SEIZO , MARUTA ISAO , HAYATSU KAZUO , KONO YOICHI
IPC分类号： C08L71/02 , C08L71/12 , C08L83/04 , C08L23/16
CPC分类号： C08L71/123 , C08L71/02 , C08L83/04 , C08L2666/02
摘要： A novel composition which has been improved in elongation and impact resistance is obtained by blending polyphenylene oxide with a small amount of a rubbery polymer, while said composition still retains excellent properties inherent to polyphenylene oxide itself, as they are, for example, thermal resistance, chemical resistance, mechanical and electrical properties. The amount of the rubbery polymer to be blended is less than 10 % by weight, preferably 0.5 to 5 % by weight, based on the weight of the whole composition. As the rubbery polymer, there may be used such rubbery polymers as obtained from conjugated diolefins, olefins, vinyl compounds and alkylene oxide. The above-mentioned two components of composition may be blended together according to a mechanical mixing method, solution mixing method or latex mixing method.

2. 发明授权

US3862263A Production of modified polyphenylene oxide 失效
标题翻译：改性聚苯醚氧化物的生产
公开(公告)号：US3862263A
公开(公告)日：1975-01-21
申请号：US33435673
申请日：1973-02-21
申请人： SUMITOMO CHEMICAL CO
发明人： MARUTA ISAO , NAKASHIO SEIZO , HAYATSU KAZUO , KONO YOICHI
IPC分类号： C08F283/08 , C08F41/12
CPC分类号： C08F283/08 , Y10S525/905 , C08F212/04
摘要： A relatively small amount of styrene can be smoothly graftpolymerized on a polyphenylene oxide with a high graft efficiency and in a high polymerization yield by polymerizing 0.4 to 2 parts by weight of a styrene compound in the presence of 1 part by weight of a polyphenylene oxide, or 15 to 60 parts by weight of a styrene compound in the presence of 40 to 85 parts by weight of a mixture comprising 74 to 96% by weight of a polyphenylene oxide and 26 to 4% by weight of a rubbery polymer, in an aqueous dispersion containing a dispersion stabilizer and a radical initiator. In order to carry out the polymerization reaction more efficiently and more smoothly, it is preferable that the styrene compound in excess of the amount to be contained in the final graft polymer is initially made present in the polymerization system, unreacted styrene compound is removed in the form of an azeotropic mixture with water by distillation in the course of polymerization, thereby leaving the desired amount of styrene in the system, and the reaction is further continued to complete the polymerization. In this manner, a bead-like graft polymer excellent in surface state and having a smaller diameter can be obtained.
摘要翻译：相对少量的苯乙烯可以在接枝效率高的聚苯醚上顺利地接枝聚合，并且通过在1重量份聚苯撑的存在下聚合0.4至2重量份的苯乙烯化合物，以高聚合产率氧化物或15至60重量份的苯乙烯化合物，在40至85重量份的包含74至96重量％的聚苯醚和26至4重量％的橡胶状聚合物的混合物的存在下，在含有分散稳定剂和自由基引发剂的水性分散体。

3. 发明授权

US3700630A Modified polyphenylene oxide and method for production thereof 失效
标题翻译：改性聚氧乙烯氧化物及其生产方法
公开(公告)号：US3700630A
公开(公告)日：1972-10-24
申请号：US3700630D
申请日：1971-08-23
申请人： SUMITOMO CHEMICAL CO
发明人： HAMADA TAKAKI , NAKASHIO SEIZO , MARUTA ISAO , HAYATSU KAZUO , SETO TETSUKI , KONO YOICHI
IPC分类号： C08F283/08 , C08G23/20
CPC分类号： C08F283/08
摘要： MODIFIED POLYPHENYLENE OXIDES EXCELLENT IN PROCESSABILITY AND MOLDABILITY ARE OBTAINED BY GRAFT-POLYMERIZING ON A POLYPHENYLENE OXIDE A STYRENE TYPE COMPOUND OR A MIXTURE OF THE STYRENE TYPE COMPOUND AND AN A-ALKYL SUBSTITUTION PRODUCT OF SAID COMPOUND, IN AN AQUEOUS DISPERSION CONTAING AN ANIONIC OR NONIONIC SURFACTANT, A RADICAL INITIATOR AND A SOLVENT FOR THE POLYPHENYLENE OXIDE.

4. 发明授权

US3578625A Stabilized composition of polyphenylene oxide 失效
标题翻译：聚苯乙烯的稳定组合物
公开(公告)号：US3578625A
公开(公告)日：1971-05-11
申请号：US3578625D
申请日：1968-08-29
申请人： SUMITOMO CHEMICAL CO
发明人： NAKASHIO SEIZO , MARUTA ISAO
IPC分类号： C08K5/00 , C08G51/62
CPC分类号： C08K5/00
摘要： THE PRESENT COMPOSITION OF POLYPHENYLENE OXIDE HAS AN IMPROVED STABILITY AGAINST DETERIORATION OF QUALITY AND IN DISCOLORATION, AND COMPRISES A POLYPHENYLENE OXIDE, 0.005 TO 5/% BY WEIGHT OF AT LEAST ONE KIND OF HINDERED PHENOL AND 0.005 TO 5% BY WEIGHT OF AT LEAST ONE MEMBER SELECTED FROM THE GROUP CONSISTING OF TRIALKYL PHOSPHITES, TRIARYL PHOSPHITES, TRIALKYL THIOPHOSPHITES, TRIARYL THIOPHOSPHITES, THIOPHOSPHITES, THIOETHERS OF CARBOXYLIC ACID ESTERS, THIOETHERS, METAL ALKYLDITHIOCARBAMATES AND METAL ARYLDITHIOCARBAMATES.

5. 发明专利

DE1942393A1 未知
公开(公告)号：DE1942393A1
公开(公告)日：1970-02-26
申请号：DE1942393
申请日：1969-08-20
申请人： SUMITOMO CHEMICAL CO
发明人： MARUTA ISAO , HAYATSU KAZUO , NAKASHIO SEIZO
IPC分类号： C08K5/13 , C08G43/00

6. 发明专利

SU611592A3 METHOD OF PREPARING MODIFIED POLYPHENYLENEOXIDES 未知
公开(公告)号：SU611592A3
公开(公告)日：1978-06-15
申请号：SU1495406
申请日：1970-11-27
申请人： SUMITOMO CHEMICAL CO
发明人： MARUTA ISAO , NAKASIO SEJZO , KHAYATSU KAZUO , KONO JOICHI
IPC分类号： C08F2/18 , C08F283/08

7. 发明专利

CA891560A STABILIZED POLYPHENYLENE OXIDE COMPOSITION 未知
公开(公告)号：CA891560A
公开(公告)日：1972-01-25
申请号：CA891560D
申请人： SUMITOMO CHEMICAL CO
发明人： HAYATSU KAZUO , MARUTA ISAO , NAKASHIO SEIZO

8. 发明专利

DK137542B 未知
公开(公告)号：DK137542B
公开(公告)日：1978-03-20
申请号：DK603370
申请日：1970-11-26
申请人： SUMITOMO CHEMICAL CO
发明人： MARUTA ISAO , NAKASHIO SEIZO , HAYATSU KAZUO , KONO YOICHI
IPC分类号： C08F2/18 , C08F283/08

9. 发明专利

DK134676B 未知
公开(公告)号：DK134676B
公开(公告)日：1976-12-20
申请号：DK410369
申请日：1969-07-29
申请人： SUMITOMO CHEMICAL CO
发明人： HAMADA TAKAKI , NAKASHIO SEIZO , MARUTA ISAO , HAYATSU KAZUO , SOTO TETSUKI , KONO YOICHI
IPC分类号： C08F283/08
摘要： 1,254,337. Grafted polyphenylene oxides. SUMITOMO CHEMICAL CO. Ltd. 6 Aug., 1969 [8 Aug., 1968], No. 39411/69. Heading C3G. A grafted polyphenylene oxide is prepared by contacting 0-1 to 10 parts by weight of one or more styrene monomers represented by the Formula Ia: wherein R 1 , R 2 , R 3 , R 4 and R 5 are individually a hydrogen or halogen atom, or a cyano, nitro, amino, mono- or dialkylamino, -50 3 H, a hydroxy group, unsubstituted or halogen- or cyano-substituted hydrocarbon or unsubstituted or halogen-substituted hydrocarbonoxy group, or 0-1 to 10 parts by weight of a mixture of the styrene monomer or monomers of the Formula Ia and one or more alpha-alkyl substituted styrene monomers represented by the Formula Ib: wherein R 1 , R 2 , R 3 , R 4 and R 5 are as defined above, and R 6 is an alkyl group with a radical initiator in the presence of 1 part by weight polyphenylene oxide having recurring structural units of the formula wherein R 1 1 , R1 2 , R 1 3 and R1 4 are individually a hydrogen or halogen atom or an unsubstituted or halogen- or cyano-substituted hydrocarbon, an unsubstituted or halogen-substituted hydrocarbonoxy, cyano, mono- or dialkylamino or nitro group, in an aqueous medium comprising an anionic or nonionic surfactant, a solvent for said polyphenylene oxide and at least 0-5 times the total weight of the solvent and compounds Ia, or Ia and Ib, and II of water. Specified solvents are benzene, toluene, xylene, chloro- or nitro-benzene, chloroform and carbon tetrachloride In the examples (a) styrene or a mixture thereof with p-methoxystyrene, alpha-methylstyrene or alpha-methyl-p-methyl styrene is grafted on to poly (2,6-dimethyl- 1,4-phenylene oxide) or (b) styrene is grafted on to poly (2,6-diethyl. 1 ,4-phenylene oxide), the grafting being carried out in an aqueous medium containing xylene, a surfactant selected from sodium stearate, sodium myristate, sodium laurate, sodium dodecylbenzenesulphonate, polyoxyethylene-9-octadecene ether, sorbitan monolaurate, lauryl trimethylammonium chloride, polyoxyethylene alkylamine or polyoxyethylene monooleate, a peroxy catalyst or a mixture thereof with a reducing agent and, as dispersion stabilizer, sodium pyrophosphate or sodium carboxymethyl cellulose.

10. 发明专利

CA901719A MODIFIED POLYPHENYLENE OXIDE AND METHOD FOR PRODUCTION THEREOF 未知
公开(公告)号：CA901719A
公开(公告)日：1972-05-30
申请号：CA901719D
申请人： SUMITOMO CHEMICAL CO
发明人： NAKASHIO SEIZO , MARUTA ISAO , HAMADA TAKAKI , HAYATSU KAZUO , SETO TETSUKI , KONO YOICHI
IPC分类号： C08F283/08

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