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    • 6. 发明申请
    • MULTILAYER COMPOSITIONS
    • 多层组合物
    • WO2017157749A1
    • 2017-09-21
    • PCT/EP2017/055511
    • 2017-03-09
    • SOLVAY SPECIALTY POLYMERS USA, LLCPOLITECNICO DI MILANO
    • APOSTOLO, MarcoHARKNESS, GregoryMAURI, StefanoORIANI, Andrea, Vittorio
    • C25D5/10C23C18/16C23C18/20C23C18/30C23C18/34C25D5/14
    • C25D5/10C23C18/1653C23C18/2006C23C18/208C23C18/30C23C18/34C25D5/14
    • The present invention relates to a process for obtaining a multilayer composition, to a composition obtainable via such method and to an article comprising said composition. The process comprises at least the following: i. providing a polymeric layer (L1) comprising an aromatic polymer selected from the group consisting of poly(aryl ether sulfone) polymer (P1) and a polyarylene sulphide (P2), and having at least one surface (S1); ii. treating at least the surface (S1) of (L1) with a radio-frequency glow discharge process in the presence of an etching gas medium comprising a nitrogen-containing gas to obtained an etched surface (52); iii. optionally, contacting the etched surface (S2) obtained in step ii. with a composition (LC3) comprising a surfactant to obtain at least a pre-treated surface (S2a); iv. contacting the etched surface (S2) obtained in step ii. or the pre-treated surface (S2a) obtained in step iii. with a liquid composition (LC1) comprising at least a metal (MC) in ionic form and having a pH not less than 9.0, so as to provide an article having at least one surface (S-3) treated with a composition containing metal (MC) in ionic form; v. reducing metal (MC) in ionic form on (S-3) to its metallic form by contacting (S-3) with a liquid composition (LC2) containing a reducing agent; vi. forming by electroless deposition a layer (L2) onto the at least one treated surface obtained in step v., said layer (L2) comprising at least one metal compound (M1) and metal (MC) in ionic form; vii. applying an additional layer (L3) comprising a metal (M2), equal to or different from (M1), directly on layer (L2); and, optionally, viii. applying an additional layer (L4) of a metal (M2) on (L3).
    • 本发明涉及获得多层组合物的方法,通过该方法获得的组合物,以及包含所述组合物的制品。 该过程至少包括以下内容:i。 提供包含选自聚(芳基醚砜)聚合物(P1)和聚亚芳基硫醚(P2)的芳族聚合物并且具有至少一个表面(S1)的聚合物层(L1); II。 在存在包含含氮气体的蚀刻气体介质的情况下用射频辉光放电工艺至少处理(L1)的表面(S1)以获得蚀刻表面(52); III。 任选地,接触在步骤ii中获得的蚀刻表面(S2)。 与包含表面活性剂的组合物(LC3)混合以获得至少预处理表面(S2a); IV。 接触在步骤ii中获得的蚀刻表面(S2)。 或在步骤iii中获得的预处理表面(S2a)。 与包含至少一种离子形式并且具有不小于9.0的pH的金属(MC)的液体组合物(LC1)混合,以提供具有至少一个用含有金属的组合物处理过的表面(S-3)的物品(S-3) MC)以离子形式存在; v。通过使(S-3)与含有还原剂的液体组合物(LC2)接触,将在(S-3)上的离子形式的金属(MC)还原成其金属形式; 六。 通过无电沉积在步骤v中获得的至少一个处理过的表面上形成层(L2),所述层(L2)包含离子形式的至少一种金属化合物(M1)和金属(MC); 七。 直接在层(L2)上施加包含等于或不同于(M1)的金属(M2)的附加层(L3); 并且可选地,viii。 (L3)上施加金属(M2)的附加层(L4)。