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    • 10. 发明申请
    • PROCESS FOR MANUFACTURING FLUOROPOLYMER HYBRID COMPOSITES
    • 制造氟聚合物混合复合材料的方法
    • WO2014067816A1
    • 2014-05-08
    • PCT/EP2013/072067
    • 2013-10-22
    • SOLVAY SA
    • FRACHE, AlbertoTATA, Jennifer KattyCAMINO, GiovanniBESANA, GiambattistaABUSLEME, Julio A.
    • C08J3/20C08J3/205B32B27/08B32B27/36B32B27/30
    • C08J5/00C08J3/201C08J3/2056C08J2327/16C08J2327/18C08K5/05
    • The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) partially hydrolysing and/or polycondensing, in the presence of an aqueous medium, a metal compound of formula (I): X4-mAYim, wherein X is a hydrocarbon group, Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, A is a metal selected from the group consisting of Si, Ti and Zr, and m is an integer from 1 to 4, so as to obtain an aqueous medium comprising a pre-gelled metal compound comprising one or more inorganic domains consisting of≡A-O-A≡ bonds and one or more residual hydrolysable groups Y [compound (M)], and then (ii) reacting in the molten state at least a fraction of hydroxyl groups of a functional fluoropolymer [polymer (F)] with at least a fraction of hydrolysable groups Y of said pre-gelled metal compound [compound (M)], so as to obtain a fluoropolymer hybrid organic/inorganic composite. The invention also pertains to uses of said fluoropolymer hybrid organic/inorganic composite in several applications.
    • 本发明涉及一种制备含氟聚合物杂化有机/无机复合材料的方法,包括:(i)在含水介质存在下部分水解和/或缩聚式(I)的金属化合物:X4-mayim,其中X 是烃基,Y是选自烷氧基,酰氧基和羟基的可水解基团,A是选自Si,Ti和Zr的金属,m是从 1至4,以获得包含预先凝胶化的金属化合物的水性介质,所述预凝胶化金属化合物包含一个或多个由以下组成的无机区域:AOA≡键和一个或多个残余可水解基团Y [化合物(M)],然后(ii) 在熔融状态下使至少一部分所述预胶化金属化合物[化合物(M)]的可水解基团Y的官能含氟聚合物[聚合物(F)]的羟基的至少一部分反应,以获得 氟聚合物杂化有机/无机复合材料 。 本发明还涉及在几种应用中所述含氟聚合物杂化有机/无机复合材料的用途。