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1. 发明申请

WO2011036283A2 MANUFACTURE OF DIFLUOROETHYLENE CARBONATE, TRIFLUOROETHYLENE CARBONATE AND TETRAFLUOROETHYLENE CARBONATE 审中-公开
标题翻译：碳酸二甲酯，三氟乙烯碳酸酯和四氟乙烯碳酸酯的制备
公开(公告)号：WO2011036283A2
公开(公告)日：2011-03-31
申请号：PCT/EP2010/064221
申请日：2010-09-27
申请人： SOLVAY FLUOR GmbH , OLSCHIMKE, Jens , SEFFER, Dirk , BOMKAMP, Martin
发明人： OLSCHIMKE, Jens , SEFFER, Dirk , BOMKAMP, Martin
IPC分类号： C07D317/36 , C07D317/42
CPC分类号： C07D317/36 , C07D317/42
摘要： Difluoroethylene carbonate, trifluoroethylene and tetrafluoroethylene carbonate are produced by the reaction between elemental fluorine and ethylene carbonate or fluorinated ethylene carbonates with a lower degree of fluorination.
摘要翻译：二氟乙烯碳酸酯，三氟乙烯和四氟乙烯碳酸酯通过元素氟和碳酸亚乙酯之间的反应或具有较低氟化度的氟化亚乙基碳酸酯的反应来制备。

2. 发明申请

WO2011006822A1 PROCESS FOR THE PREPARATION OF FLUOROALKYL (FLUORO)ALKYL CARBONATES AND CARBAMATES 审中-公开
标题翻译：氟代烷基（氟）烷基碳酸酯和碳酸酯的制备方法
公开(公告)号：WO2011006822A1
公开(公告)日：2011-01-20
申请号：PCT/EP2010/059795
申请日：2010-07-08
申请人： SOLVAY FLUOR GMBH , BOMKAMP, Martin , OLSCHIMKE, Jens
发明人： BOMKAMP, Martin , OLSCHIMKE, Jens
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C69/96 , C07C68/02 , C07C269/04 , C07C271/14
摘要： Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoro formates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoro formates can be prepared from aldehydes and carbonyl fluoride.
摘要翻译：氟代烷基氟代烷基酯和氟取代的氨基甲酸酯，其适合作为锂离子电池中的添加剂或溶剂，由氟烷基氟甲酸酯和相应的醇或胺制备。甲醇是优选的醇，二甲胺和二乙胺是优选的胺。氟甲基甲基碳酸酯是要生产的优选化合物。氟烷基氟甲酸酯可以由醛和碳酰氟制备。

3. 发明申请

WO2011048053A1 METHOD FOR THE MANUFACTURE OF FLUORINATED ETHYLENE CARBONATES 审中-公开
标题翻译：氟化乙烯碳酸盐的制备方法
公开(公告)号：WO2011048053A1
公开(公告)日：2011-04-28
申请号：PCT/EP2010/065642
申请日：2010-10-18
申请人： SOLVAY FLUOR GmbH , BOMKAMP, Martin , OLSCHIMKE, Jens , EICHER, Johannes
发明人： BOMKAMP, Martin , OLSCHIMKE, Jens , EICHER, Johannes
IPC分类号： C07D317/46
CPC分类号： C07D317/46
摘要： Difluoroethylene carbonate, trifluoroethylene carbonate and tetrafluoroethylene carbonate are synthesized from dichloroethylene carbonate, trichloroethylene carbonate and tetrachloroethylene carbonate with fluorinating agents, e.g. alkali metal fluorides, antimony fluorides and especially the HF adducts of amines. The fluorinated carbonates are suitable as additives in lithium ion batteries.
摘要翻译：二氟乙烯碳酸酯，三氟乙烯碳酸酯和四氟乙烯碳酸酯由二氯乙烯碳酸酯，三氯乙烯碳酸酯和四氯乙烯碳酸酯与氟化剂合成。碱金属氟化物，氟化锑，特别是胺的HF加合物。氟化碳酸酯适合用作锂离子电池中的添加剂。

4. 发明申请

WO2010136506A1 PROCESS FOR THE PREPARATION OF 4-FLUORO-4-R-5-R'-1,3-DIOXOLANE-2-ONES 审中-公开
标题翻译：制备4-氟-4-R-5-R'-1,3-二氧杂环己烷-2-酮的方法
公开(公告)号：WO2010136506A1
公开(公告)日：2010-12-02
申请号：PCT/EP2010/057281
申请日：2010-05-26
申请人： SOLVAY FLUOR GMBH , BOMKAMP, Martin , OLSCHIMKE, Jens , BROSCH, Carsten , GROSSMANN, Andreas
发明人： BOMKAMP, Martin , OLSCHIMKE, Jens , BROSCH, Carsten , GROSSMANN, Andreas
IPC分类号： C07D317/42 , C07C69/96 , C07C68/02 , H01M10/36
CPC分类号： H01M10/0525 , C07C68/02 , C07C69/96 , C07D317/42 , H01M10/0567 , H01M10/0568 , H01M10/0569
摘要： The present invention concerns 4-fluoro-4-R-5-R'-1,3-dioxolane-2-ones, wherein R is an alkyl group and R' is H or a C1 to C3 alkyl group, their manufacture, solvent mixtures for lithium ion batteries containing them and conductive salt solutions for lithium ion batteries, e.g. solutions containing LiPF 6 .
摘要翻译：本发明涉及4-氟-4-R-5-R'-1,3-二氧戊环-2-酮，其中R是烷基，R'是H或C1-C3烷基，它们的制备，溶剂含锂离子电池的混合物和锂离子电池的导电盐溶液，例如含LiPF6的溶液。

5. 发明申请

WO2011051275A1 LITHIUM SULFUR BATTERY 审中-公开
标题翻译：锂硫电池
公开(公告)号：WO2011051275A1
公开(公告)日：2011-05-05
申请号：PCT/EP2010/066143
申请日：2010-10-26
申请人： SOLVAY FLUOR GmbH , OLSCHIMKE, Jens , BOMKAMP, Martin , EICHER, Johannes
发明人： OLSCHIMKE, Jens , BOMKAMP, Martin , EICHER, Johannes
IPC分类号： H01M12/08 , H01M10/052 , H01M10/0569 , H01M10/0568 , H01M10/05
CPC分类号： H01M12/08 , H01M4/134 , H01M4/38 , H01M4/381 , H01M4/382 , H01M10/05 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0068 , Y02E60/128 , Y02T10/7011
摘要： A lithium sulfur battery comprising at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, and fluorosubstituted acyclic carbonates fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans- difluoroethylene carbonate, 4,4- difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-l,3-dioxolane-2-one, 4-fluoro-4-ethyl- 1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent my further comprise non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate. The invention also concerns the use of fluorinated compounds as additive for such batteries and specific electrolyte solutions.
摘要翻译：描述了包含至少一种氟取代的化合物的锂硫电池。主要是溶剂的优选氟取代的化合物特别选自氟取代的羧酸酯，氟取代的羧酸酰胺，氟取代的氟代醚，氟取代的氨基甲酸酯，氟取代的环状碳酸酯和氟取代的无环碳酸酯氟取代的醚，全氟烷基磷，氟取代的亚磷酸酯，氟取代的磷酸酯，氟取代的膦酸酯和氟取代的杂环。单氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂我还包括非氟化溶剂，例如碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯。本发明还涉及氟化化合物作为这种电池和特定电解质溶液的添加剂的用途。

6. 发明申请

WO2012146525A1 LITHIUM AIR BATTERY CELL 审中-公开
标题翻译：锂离子电池
公开(公告)号：WO2012146525A1
公开(公告)日：2012-11-01
申请号：PCT/EP2012/057169
申请日：2012-04-19
申请人： SOLVAY SA , EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
发明人： EICHER, Johannes , OLSCHIMKE, Jens , BOMKAMP, Martin , GARCIA-JUAN, Placido
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M8/22 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M12/08 , H01M2220/20 , H01M2300/0028 , H01M2300/0034 , Y02E60/122 , Y02E60/128 , Y02T10/7011
摘要： A lithium-air battery cell with an electrolyte composition comprising LiPO 2 F 2 is described. The electrolyte composition comprises an electrolyte solvent, for example, one or more non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate, and/or one or more fluorinated organic solvents, e.g. fluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise other additives. Also described is a vehicle battery, especially a car battery constituted of a multitude of lithium-air battery cells of the invention. The battery can be used to provide electrical energy to consumers for electric current including an electric motor driving the vehicle.
摘要翻译：描述了具有包含LiPO2F2的电解质组成的锂空气电池单元。电解质组合物包含电解质溶剂，例如一种或多种非氟化溶剂，例如，碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯，和/或一种或多种氟化有机溶剂，例如，氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂可以进一步包含其它添加剂。还描述了一种车辆电池，特别是由本发明的多个锂空气电池单元构成的汽车电池。电池可以用于为消费者提供电能，包括驱动车辆的电动机的电流。

7. 发明申请

WO2011036293A2 COMPOSITION OF A FLUORINATED ORGANIC CARBONATE AND A LEWIS ACID 审中-公开
标题翻译：氟化有机碳酸酯和乳酸的组成
公开(公告)号：WO2011036293A2
公开(公告)日：2011-03-31
申请号：PCT/EP2010/064269
申请日：2010-09-27
申请人： SOLVAY SA , OLSCHIMKE, Jens , BOMKAMP, Martin , GROSSMANN, Andreas
发明人： OLSCHIMKE, Jens , BOMKAMP, Martin , GROSSMANN, Andreas
IPC分类号： C07D317/36 , C07D317/42
CPC分类号： C07D317/36 , C07D317/42
摘要： The present invention provides inter alia a method for handling fluorinated organic carbonates such that degradation reactions are minimized or even completely suppressed and hence initial purity of fluorinated organic carbonatesis essentially maintained during handling. The invention further provides compositions comprising a fluorinated organic carbonate with improved stability against degradation reactions. The compositions comprise equal to or less than 500 ppm of a Lewis acid.
摘要翻译：本发明尤其提供一种处理氟化有机碳酸酯的方法，使得降解反应最小化或甚至完全抑制，因此氟化有机碳酸酯的初始纯度在处理过程中基本保持。本发明进一步提供包含具有改进的降解反应稳定性的氟化有机碳酸酯的组合物。组合物包含等于或小于500ppm的路易斯酸。

8. 发明申请

WO2014177704A1 FLUORINATED CARBONATES AS SOLVENT FOR LITHIUM SULFONIMIDE-BASED ELECTROLYTES 审中-公开
标题翻译：氟化碳酸锂作为硫酸锂电解质溶液
公开(公告)号：WO2014177704A1
公开(公告)日：2014-11-06
申请号：PCT/EP2014/059011
申请日：2014-05-02
申请人： SOLVAY FLUOR GMBH , WESTFÄLISCHE WILHELMS-UNIVERSITÄT MÜNSTER , INSTITUT POLYTECHNIQUE DE GRENOBLE , CNRS - CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人： BOMKAMP, Martin
IPC分类号： H01M10/0569 , H01M10/0568 , H01M10/052 , H01M4/66 , H01G9/022 , H01G11/06 , H01G11/60
CPC分类号： H01M10/0569 , H01G11/06 , H01G11/60 , H01M4/661 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M2300/0034 , H01M2300/0037 , H01M2300/004 , Y02E60/13
摘要： The present invention relates to an electrolyte solution comprising an electrolyte salt and an electrolyte solvent, wherein the electrolyte solvent comprises a fluorinated acyclic dialkyl carbonate, preferably an n-fluoro diethyl carbonate according to formula (1) as follows : C 2 H 5-x F x CO 3 C 2 H 5-y F y (1) wherein 1 ≤ x ≤ 5 and 0 ≤ y ≤ 5; in an amount in the range of ≥ 10 wt % to ≤ 100 wt %, referring to a total amount of the electrolyte solvent of 100 wt %, and the use of such fluorinated acyclic dialkyl carbonates for the prevention or suppresion of aluminum current collector corrosion in an alkali or alkaline earth metal-based electrochemical energy storage device, particularly in a lithium-ion battery or lithium polymer battery containing an electrolyte solution comprising an alkali or alkaline earth metal sulfonimide or sulfonmethide salt.
摘要翻译：本发明涉及包含电解质盐和电解质溶剂的电解质溶液，其中所述电解质溶剂包括氟化无环碳酸二烷基酯，优选根据式（1）的正氟碳酸二乙酯，如下所示：C 2 H 5-x F x CO 3 C 2 H 5 -yFy（ 1）其中1≤x≤5且0≤y≤5; 相对于100重量％的电解质溶剂的总量，使用这种氟代无环状碳酸二烷基酯来防止或抑制铝集电体腐蚀，其量在≥10重量％〜100重量％的范围内特别是在含有碱金属或碱土金属磺酰亚胺或磺胺甲酸盐的电解质溶液的锂离子电池或锂聚合物电池中，具有碱金属或碱土金属的电化学储能装置。

9. 发明申请

WO2013026777A9 FLUOROALKYL S-(FLUORO)ALKYL THIOCARBONATES, A METHOD FOR THE PREPARATION OF FLUOROALKYL S-(FLUORO)ALKYL THIOCARBONATES, AND THEIR USE 审中-公开
公开(公告)号：WO2013026777A9
公开(公告)日：2013-02-28
申请号：PCT/EP2012/066045
申请日：2012-08-16
申请人： SOLVAY SA , BOMKAMP, Martin
发明人： BOMKAMP, Martin
IPC分类号： H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/42 , C07C329/06
摘要： Fluoroalkyl S-alkyl thiocarbonates and fluoroalkyl S-fluoroalkylthiocarbonates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective thioalcohol. Methanethiol, allyl thiol and 2,2,2-trifluorothiol are the preferred thioalcohol. Fluoromethyl S-methyl thiocarbonate, fluoromethyl S-allyl thiocarbonate, fluoromethyl S-2,2,2-trifluoroethyl thiocarbonate and fluoromethyl S-allyl thiocarbonate are the preferred compound to be produced.

10. 发明公开

EP2494648A1 LITHIUM SULFUR BATTERY 审中-公开
标题翻译： LITHIUMSCHWEFELBATTERIE
公开(公告)号：EP2494648A1
公开(公告)日：2012-09-05
申请号：EP10770821.6
申请日：2010-10-26
申请人： Solvay Fluor GmbH
发明人： OLSCHIMKE, Jens , BOMKAMP, Martin , EICHER, Johannes
IPC分类号： H01M12/08 , H01M10/052 , H01M10/0569 , H01M10/0568 , H01M10/05
CPC分类号： H01M12/08 , H01M4/134 , H01M4/38 , H01M4/381 , H01M4/382 , H01M10/05 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , H01M2300/0068 , Y02E60/128 , Y02T10/7011
摘要： A lithium sulfur battery comprising at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, and fluorosubstituted acyclic carbonates fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans- difluoroethylene carbonate, 4,4- difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-l,3-dioxolane-2-one, 4-fluoro-4-ethyl- 1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent my further comprise non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate. The invention also concerns the use of fluorinated compounds as additive for such batteries and specific electrolyte solutions.
摘要翻译：描述了包含至少一种含氟取代化合物的电解质溶剂的锂硫电池。主要是溶剂的优选氟取代的化合物特别选自氟代取代的羧酸酯，氟取代的羧酸酰胺，氟取代的氟代醚，氟代取代的氨基甲酸酯，氟代取代的环状碳酸酯，氟取代的无环碳酸酯，氟取代的醚，全氟烷基磷，氟取代的亚磷酸酯，氟取代的磷酸酯，氟取代的膦酸酯和氟取代的杂环。单氟代碳酸亚乙酯，顺式二氟亚乙基碳酸酯，反式二氟亚乙基碳酸酯，4,4-二氟亚乙基碳酸酯，三氟乙烯碳酸酯，四氟乙烯碳酸酯，4-氟-4-甲基-1,3-二氧戊环-2-酮，4-氟-4- 乙基-1,3-二氧戊环-2-酮，2,2,2-三氟乙基 - 甲基碳酸酯，2,2,2-三氟乙基 - 氟甲基碳酸酯。溶剂可以进一步包含非氟化溶剂，例如碳酸亚乙酯，碳酸二烷基酯或碳酸亚丙酯。使用这种氟化合物作为这种电池和特定电解质溶液的添加剂。

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