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    • 1. 发明申请
    • POLYURETHANE (POLYMER HYBRID) DISPERSION WITH REDUCED HYDROPHILICITY, METHOD FOR PRODUCING THE SAME AND THE USE THEREOF
    • 聚氨酯(聚合物混合)具有减少的亲水性的分散性,生产和使用方法发明
    • WO0212364A3
    • 2002-06-20
    • PCT/EP0109135
    • 2001-08-07
    • SKW BAUWERKSTOFFE DEUTSCHLANDRASMUSSEN PIA HFMAIER ALOISSTEIDL NORBERTKERN ALFREDWOLFERTSTETTER FRANZREUSMANN GERHARD
    • REICHEL FRANK DIMAIER ALOISSTEIDL NORBERTKERN ALFREDWOLFERTSTETTER FRANZREUSMANN GERHARD
    • C08G18/08C08G18/12C08G18/48C08G18/66C08L53/00C09D153/00C09D175/04C09J153/00C09D175/08
    • C09D153/00C08G18/0823C08G18/12C08G18/4854C08G18/4879C08G18/6659C08L53/00C08L2666/02C09D175/04C09J153/00C08G18/3228C08L2666/14C08L2666/24
    • The invention relates to a polyurethane (polymer hybrid) dispersion with reduced hydrophilicity that is produced by reacting a) 50 to 100 parts by weight of a hydrophobically modified block copolymer (A)(i) having two or more hydroxyl groups and a molecular weight of from 500 to 6000 Daltons, and/or 50 to 100 parts by weight of a hydrophobic block copolymer (A)(ii) having two or more hydroxyl groups and a molecular weight of from 500 to 6000 Daltons, and/or 50 to 100 parts by weight of a hydrophobically modified random copolymer (A)(iii) having two or more hydroxyl groups and a molecular weight of from 500 to 6000 Daltons, b) 14 to 140 parts by weight of a polyol component (B), c) 25 to 250 parts by weight of a polyisocyanate component (C), d) 2 to 20 parts by weight of a neutralizing component (D), e) 3 to 30 parts by weight of a chain-extender component (E), and f) 100 to 5000 parts by weight of water, to give a solvent-free or a solvent-poor polyurethane dispersion. Optionally, g) the mixture is further reacted with 117.5 to 3200 parts by weight of a monomer component (F), and h) 0.5 to 50 parts by weight of an initiator component (G), to give a solvent-free or solvent-poor polyurethane polymer hybrid dispersion. The use of hydrophobically modified block copolymers and/or hydrophobically modified random copolymers as the polyols allows the production of polyurethane polymer hybrid dispersions that are characterized by reduced hydrophilicity or water retention, no or little solvent content and high solid content.
    • 公开了一种聚氨酯(聚合物杂化)分散体具有降低的亲水性,已通过重量的具有两个或多个羟基经疏水改性的嵌段共聚物(A)(ⅰ)的制备通过使A)50〜100份 (重量)的疏水性嵌段共聚物的基团和500-6000道尔顿的分子量,和/或50至100份的(a)(ii)具有两个或更多个羟基基团和500-6000道尔顿的分子量,和/或 50至100重量份的疏水改性的无规共聚物(a)的(iii)具有两个或更多个羟基基团和500至6000道尔顿的分子量,(b)14-140重量份的多元醇组分b的 ),C)25〜250重量份多异氰酸酯组分(C),D)2至20份(重量)的中和组分(D)中,e)中的(3〜30重量份的扩链剂组分的 e)和f)为100〜5000重量份的水为无溶剂或低溶剂POLYM (按重量计的引发剂组分G的0.5至50份)乙烷分散和任选随后用克)117.5〜3200重量份的单体组分(f)和h)的反应中,无溶剂 可以反应进一步或低溶剂的聚氨酯聚合物混合Despersion。 通过使用疏水改性的嵌段共聚物和/或疏水改性的无规共聚物多元醇作为聚氨酯(聚合物杂化)是具有减小的亲水性或吸水性访问的,其可以由无溶剂或低溶剂的高固体含量有也分散体。
    • 5. 发明申请
    • LIQUID FLUORINE-CONTAINING COMPOSITIONS FOR TREATING THE SURFACES OF MINERAL AND NON-MINERAL SUBSTRATES
    • LIQUID FLUOR CONTAINING COMPOSITIONS FOR矿物的表面处理和非矿物表面
    • WO2006032512A3
    • 2007-06-07
    • PCT/EP2005010287
    • 2005-09-22
    • DEGUSSAMAIER ALOISSTEIDL NORBERTSCHROERS MICHAELWEINELT FRANKSTAUDHAMMER MARITA
    • MAIER ALOISSTEIDL NORBERTSCHROERS MICHAELWEINELT FRANKSTAUDHAMMER MARITA
    • C08G77/24C04B41/49C08G77/26C09D7/47C09D183/08C09D183/10
    • C03C17/28C03C17/326C03C17/328C04B41/4961C08G77/24C08G77/26C09D183/08C09D183/10
    • The invention relates to liquid fluorine-containing compositions which have a fluorine content, based on the solid resin, of approximately 5 to 75 % by weight, for the permanent treatment of porous and non-porous substrates. The inventive compositions are obtainable by a) producing a perfluoroalkyl component (A), b) dissolving approximately 5 to 100 parts by weight of the perfluoroalkyl component (A) obtained in step a) prior, during or after reaction in approximately 0 to 100 parts by weight of a solvent component (K), c 1 ) optionally (partially) hydrolyzing or silanolizing the perfluoroalkyl component (A) obtained in steps a) or b) in the presence of approximately 0 to 50 parts by weight of an aminoalkylalkoxysilane component (E)(i) and/or aminosilane component (E)(ii) with approximately 1 to 50 parts by weight of water, c 2 ) quaternizing the aminofunctional adduct with approximately 5 to 50 parts by weight of an acid component (L) (direct neutralization), c 3 ) optionally removing the released alcohol and/or the solvent component (K), d 1 ) dissolving the reaction product obtained in step c) subsequently or simultaneously in approximately 50 to 1000 parts by weight of water and oligomerizing it, d 2 ) optionally removing the released alcohol and/or the solvent component (K), e) whereby optionally during or after steps a) and/or b) and/or c) and/or d) approximately 0 to 50 parts by weight of a formulation component (M) can be added in any manner and/or approximately 0 to 50 parts by weight of a functionalization component (N) are added and/or co-reacted. The invention makes available vapor-permeable coating systems for permanently treating the surfaces of mineral and non-mineral substrates with oil, water and dirt-repellent surface agents or for modifying them. The inventive liquid fluorine-containing compositions have substantially improved properties of application at the same or lower fluorine content as conventional products.
    • 它将与相关的大约5个氟的固体树脂含量为75重量%为多孔和无孔基材液体含氟组合物,其是可获得的连续表面处理时间由第一一制备)描述为全氟烷(A)成分 b)约5至100份(重量)从步骤a)之前,期间或按重量计的溶剂组分(K)的在约0至100份在反应后解决了,C )如果合适的话,全氟烷组分(a)从步骤a)或(b)以按重量计的氨基的烷氧基硅烷组分(e的存在的大约0〜50份)i)和/或氨基硅烷组分(e)(ii)用 约1至50重量份的水(部分地)水解或silanolisiert,C 2 ),按重量的酸成分(L)的氨基官能加合物与约5至50份季铵化的(直接中和)中,c 3 )如果需要的话,释放的醇及/ O 的溶剂组分(K)被去除,D 1 )c)中随后或同时将反应产物从步骤溶解在水中约50至1000份(重量)和低聚ð 2 )被去除,e)任选地,期间或步骤a)和/或b)和/或c)和/或d)以任何所需方式,如果需要的释放的醇及/或溶剂成分后(K) 约0至50重量份添加的制剂成分(M)和/或约0至50重量份的官能组分(N)中的每一个添加和/或实现。 以这种方式,对于永久油,水和防污表面处理或矿物和非矿物表面改性水蒸汽可渗透的涂层系统是可访问的。 此外,本发明的液体含氟组合物的产品相比,根据现有技术的具有用于相同和下部氟含量显著更好的性能特性。