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1. 发明申请

WO0249412A8 BRANCHED VAPOR-GROWN CARBON FIBER, ELECTRICALLY CONDUCTIVE TRANSPARENT COMPOSITION AND USE THEREOF 审中-公开
标题翻译：分散式蒸汽碳纤维，电导体透明组合物及其用途
公开(公告)号：WO0249412A8
公开(公告)日：2004-07-29
申请号：PCT/JP0111130
申请日：2001-12-19
申请人： SHOWA DENKO KK , MORITA TOSHIO , INOUE HITOSHI , YAMAMOTO RYUJI
发明人： MORITA TOSHIO , INOUE HITOSHI , YAMAMOTO RYUJI
IPC分类号： C08J5/18 , C01B31/02 , C08K7/06 , C08K7/24 , C08L101/00 , C09D5/24 , D01F9/127 , H01B1/04 , H01B1/24 , C08K3/04
CPC分类号： B82Y30/00 , C08K7/24 , C08K2201/016 , C09D5/24 , D01F9/127 , H01B1/04 , H01B1/24 , Y10T428/2918
摘要： A branched vapor-grown carbon fiber having an outer diameter of 0.5 mu m or less and an aspect ratio of at least 10, the carbon fiber having a compressed specific resistance of 0.02 OMEGA .cm or less, each fiber filament having a hollow cylindrical structure, preferably the carbon fiber containing boron and having a compressed specific resistance of 0.018 OMEGA .cm or less. An electrically conductive transparent composition comprising a resin binder and carbon fiber incorporated into the binder, having transparency and comprising vapor-grown carbon fiber having an outer diameter of 0.01-0.1 mu m, an aspect ratio of 10-15,000, and a compressed specific resistance of 0.02 OMEGA .cm or less, and surface resistivity of 10,000 OMEGA /c or less. An electrically conductive transparent material formed from the aforementioned electrically conductive transparent composition.
摘要翻译：外径为0.5μm以下，长径比为10以上的分支气相生长碳纤维，碳纤维的压缩电阻率为0.02欧姆·厘米或更小，每个纤维丝具有中空的圆柱形结构，优选含有硼的碳纤维，并且其压缩电阻率为0.018欧姆或以下。一种导电透明组合物，其包含结合到粘合剂中的树脂粘合剂和碳纤维，具有透明性并且包含外径为0.01-0.1μm，纵横比为10-15,000的气相生长碳纤维和压缩电阻率的0.02欧姆或以下，OMEGA / c以下的表面电阻率。由上述导电透明组合物形成的导电透明材料。

2. 发明申请

WO2004099477A2 FINE CARBON FIBER WITH LINEARITY AND RESIN COMPOSITE MATERIAL USING THE SAME 审中-公开
标题翻译：具有线性的精细碳纤维和使用其的树脂复合材料
公开(公告)号：WO2004099477A2
公开(公告)日：2004-11-18
申请号：PCT/JP2004006502
申请日：2004-05-07
申请人： SHOWA DENKO KK , YONETAKE KOICHIRO , TAKAHASHI TATSUHIRO , YAMAMOTO RYUJI , MORITA TOSHIO
发明人： YONETAKE KOICHIRO , TAKAHASHI TATSUHIRO , YAMAMOTO RYUJI , MORITA TOSHIO
IPC分类号： C01B31/02 , B29C70/14 , C08K7/06 , C08L101/00 , C08L101/12 , D01F9/127 , D01F9/00
CPC分类号： B82Y30/00 , B29C70/14 , D01F9/127 , D01F9/1276 , D04H13/00 , Y10T428/249924 , Y10T428/249927 , Y10T428/24994 , Y10T428/249945 , Y10T428/2916 , Y10T428/2918 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/30
摘要： The fine carbon fiber obtained by pulverizing vapor grown fine carbon fiber, each fiber including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m /g, wherein the average interlayer distance (d002) is 0.345 nm or less, and the ratio of the peak height (Id) of the band (e.g. 1,341 to 1,349 cm ) in a Raman scattering spectrum to that of the peak height (Ig) of the band (e.g. 1,570 to 1,578 cm ) (Id/Ig) is 0.1 to 2, a bending angle of 30° or less with respect to the axis; a composite material comprising the fine carbon fiber and a resin serving as a matrix, wherein the fine carbon fiber is oriented in one direction through, application of an external force; and a production method and use thereof. The linear fine carbon fiber of the present invention exhibits excellent dispersibility in a matrix and is readily oriented by application of an external force, and therefore, enables to produce a composite material, wherein merely the carbon fiber is or both the fine carbon fiber and the matrix resin are oriented in one direction.
摘要翻译：通过粉碎气相生长的细碳纤维而获得的细碳纤维，每个纤维包括沿其轴线延伸的中空空间，外径为1至1000nm，纵横比为5至1,000，BET比表面积 2〜2000m 2 / g，其中平均层间距离（d002）为0.345nm以下，并且在（a）中，带状的峰高（Id）（例如1,341〜1349cm -1）拉曼散射光谱与带（峰值高度（Ig））（例如1,570-1,578cm -1）（Id / Ig）的峰值散射光谱的比值为0.1〜2，弯曲角度为30°以下轴; 包含细碳纤维和用作基体的树脂的复合材料，其中细碳纤维沿一个方向取向，施加外力; 及其制造方法及其用途。本发明的线状细碳纤维在基体中表现出优异的分散性，并且通过施加外力容易取向，因此能够生产复合材料，其中仅碳纤维为细碳纤维和基质树脂在一个方向上取向。

3. 发明申请

WO2006009316A3 PRODUCTION METHOD OF VAPOR-GROWN VARBON FIBER AND APPARATUS THEREFOR 审中-公开
标题翻译：蒸汽发电变压器光纤的生产方法及其装置
公开(公告)号：WO2006009316A3
公开(公告)日：2006-03-16
申请号：PCT/JP2005013885
申请日：2005-07-22
申请人： SHOWA DENKO KK , KAMBARA EIJI , YOSHIDA TOMOAKI , MORITA TOSHIO
发明人： KAMBARA EIJI , YOSHIDA TOMOAKI , MORITA TOSHIO
IPC分类号： D01F9/127 , D01F9/133
CPC分类号： B82Y30/00 , D01F9/127 , D01F9/1272 , D01F9/1276 , D01F9/133
摘要： The invention provides a method of producing vapor grown carbon fiber by vapor-phase reaction conducted by supplying carbon source compounds and a catalyst or a catalyst precursor into a heating zone, wherein at least one of the carbon source compound and the catalyst or the catalyst precursor is solid at room temperature and the solid compound is supplied in gas form into the heating zone from a material supplier filled with the solid material alone at a constant amount. The production method according to the invention enables efficient and stable production of vapor phase carbon fiber even by using a high-volume production equipment.
摘要翻译：本发明提供了一种通过将碳源化合物和催化剂或催化剂前体供应到加热区中而通过气相反应制造气相生长碳纤维的方法，其中碳源化合物和催化剂或催化剂前体中的至少一种在室温下是固体并且固体化合物以气体形式从固体材料单独以恒定量供应到加热区。根据本发明的生产方法即使通过使用大量生产设备也能够有效且稳定地生产气相碳纤维。

4. 发明申请

WO2004101664A3 POROUS BODY, PRODUCTION METHOD THEREOF AND COMPOSITE MATERIAL USING THE POROUS BODY 审中-公开
标题翻译：多孔体，其生产方法及使用多孔体的复合材料
公开(公告)号：WO2004101664A3
公开(公告)日：2005-05-26
申请号：PCT/JP2004006697
申请日：2004-05-12
申请人： SHOWA DENKO KK , KUROSE TAKASHI , TAKAHASHI TATSUHIRO , SOTOWA CHIAKI , MORITA TOSHIO
发明人： KUROSE TAKASHI , TAKAHASHI TATSUHIRO , SOTOWA CHIAKI , MORITA TOSHIO
IPC分类号： B01J21/18 , B01J31/06 , B01J32/00 , C04B38/00 , C04B41/48 , C04B41/51 , C04B41/83 , C04B41/88 , C08J9/00 , C08J9/26 , C08J9/40 , C08K7/06 , C22C47/08
CPC分类号： C08J9/0085 , B01J21/18 , B01J31/06 , B01J31/061 , B01J31/08 , B01J32/00 , B01J35/002 , B01J35/0033 , B01J35/023 , B01J35/026 , B01J35/06 , B01J35/10 , B01J35/1014 , B01J37/32 , B22F2998/10 , C02F1/283 , C02F2303/185 , C04B38/0045 , C04B41/009 , C04B41/48 , C04B41/4888 , C04B41/51 , C04B41/63 , C04B41/69 , C04B41/83 , C04B41/88 , C04B2111/00793 , C04B2111/0081 , C08J9/26 , C08J9/28 , C08J9/40 , C08J2201/038 , C08J2201/048 , C08J2201/0504 , C08J2305/00 , C08J2375/04 , C22C47/08 , H01M4/9083 , H01M4/926 , H01M8/0234 , Y02P70/56 , Y10S977/842 , Y10T428/249927 , Y10T428/24994 , Y10T428/30 , C04B35/52 , C04B38/04 , C04B40/0078 , C04B14/386 , C04B30/02 , C04B38/00 , C04B38/0074 , C04B38/10 , C04B41/457 , C04B41/4523 , C04B35/83 , C22C47/06 , B22F3/114
摘要： A porous material comprising vapor grown carbon fiber in an amount of 10 to 90 mass%, fiber filaments of the carbon fiber forming a three-dimensional network and having a diameter of 1 to 1,000 nm, an aspect ratio of 5 to 15,000, a specific surface area (by BET method) of 2 to 2,000 m /g, and the ratio of the intensity of the peak at 1,360 cm in a Raman scattering spectrum of the carbon fiber to that of the peak at 1,580 cm in the spectrum(I1360/I1580) is 0.1 to 2.0, wherein the porosity of the porous material (V/V0) is 0.50 to 0.99 and a specific surface area is 5 to 1,000 m /g; and a production method and use thereof. The vapor grown carbon fiber impregnated in the porous material of the present invention does not contain aggregates and a three-dimensional network is formed between the fiber filaments, wherein length of each of the fiber filaments is maintained. Therefore, the vapor grown carbon fiber enables to readily produce a composite material (porous material), in which even a small amount of addition of vapor grown carbon fiber can exhibit sufficient effect.
摘要翻译： 10.一种多孔材料，其含有10〜90质量％的蒸气生长碳纤维，所述碳纤维的纤维丝形成三维网状物，直径为1〜1000nm，长径比为5〜15000，表面积（BET法）为2〜2000m 2 / g，碳纤维的拉曼散射光谱中的1,360cm -1处的峰强度与峰值的峰强度的比值为1,580 （I1360 / I1580）为0.1〜2.0，其中多孔材料（V / V0）的孔隙率为0.50〜0.99，比表面积为5〜1000m 2 / g，及其制造方法及其用途。浸渍在本发明的多孔材料中的蒸气生长的碳纤维不含有聚集体，并且在纤维长丝之间形成三维网络，其中维持每根纤维长度。因此，气相生长碳纤维能够容易地生产即使少量添加气相生长碳纤维也能发挥足够的效果的复合材料（多孔质材料）。

5. 发明专利

AT496573T 未知
公开(公告)号：AT496573T
公开(公告)日：2011-02-15
申请号：AT01271138
申请日：2001-12-19
申请人： SHOWA DENKO KK
发明人： MORITA TOSHIO , INOUE HITOSHI , YAMAMOTO RYUJI
IPC分类号： A61B1/00 , C08J5/18 , C01B31/02 , C08K7/06 , C08K7/24 , C08L101/00 , C09D5/24 , D01F9/127 , H01B1/04 , H01B1/24
摘要： A branched vapor-grown carbon fiber having an outer diameter of 0.5 µm or less and an aspect ratio of at least 10, the carbon fiber having a compressed specific resistance of 0.02 ©.cm or less, each fiber filament having a hollow cylindrical structure, preferably the carbon fiber containing boron and having a compressed specific resistance of 0.018 ©.cm or less. An electrically conductive transparent composition comprising a resin binder and carbon fiber incorporated into the binder, having transparency and comprising vapor-grown carbon fiber having an outer diameter of 0.01-0.1 µm, an aspect ratio of 10-15,000, and a compressed specific resistance of 0.02 Q.cm or less, and surface resistivity of 10,000 ©/–¡ or less. An electrically conductive transparent material formed from the aforementioned electrically conductive transparent composition.

6. 发明专利

DE602004029777D1 CARBONFEINFASER MIT LINEARITÄT SOWIE DARAUF BASIERENDER HARZVERBUNDSTOFF 未知
公开(公告)号：DE602004029777D1
公开(公告)日：2010-12-09
申请号：DE602004029777
申请日：2004-05-07
申请人： SHOWA DENKO KK
发明人： YONETAKE KOICHIRO , TAKAHASHI TATSUHIRO , YAMAMOTO RYUJI , MORITA TOSHIO
IPC分类号： C01B31/02 , D01F9/127 , B29C70/14 , C08K7/06 , C08L101/00 , C08L101/12 , D01D10/02

7. 发明专利

AT428009T 未知
公开(公告)号：AT428009T
公开(公告)日：2009-04-15
申请号：AT02753216
申请日：2002-07-31
申请人： SHOWA DENKO KK
发明人： MORITA TOSHIO , YAMAMOTO RYUJI
IPC分类号： D01F9/127 , C08K7/06
摘要： A fine carbon fiber, the main body of each fiber filament of the fiber having an outer diameter of about 1 to about 500 nm and an aspect ratio of about 10 to about 15,000 and comprising a hollow space extending along its center axis and a multi-layer sheath structure consisting of a plurality of carbon layers, the layers forming concentric rings, wherein the fiber filament has a nodular portion which is formed of outwardly protruding carbon layers or formed of a locally increased number of carbon layers. A similar fine carbon fiber, in which the fiber filament has repeatedly enlarged protruding portions and the filament diameter varies along with the length of the filament, the ratio of the diameter (d'') of a fiber filament of the fiber as measured at the outwardly enlarged portions to the diameter (d) of a fiber filament of the fiber as measured at a position at which no outwardly enlarged portions is present; i.e., d''/d, being about 1.05 to about 3, is also provided.

8. 发明专利

DE602004011042T2 未知
公开(公告)号：DE602004011042T2
公开(公告)日：2009-01-02
申请号：DE602004011042
申请日：2004-04-23
申请人： SHOWA DENKO KK
发明人： TAKAHASHI TATSUHIRO , SATO EIJI , MORITA TOSHIO
IPC分类号： C08K7/06 , C08K7/24 , C08L25/06 , C08L69/00

9. 发明专利

AU1950702A Branched vapor-grown carbon fiber, electrically conductive transparent composition and use thereof 未知
公开(公告)号：AU1950702A
公开(公告)日：2002-07-01
申请号：AU1950702
申请日：2001-12-19
申请人： SHOWA DENKO KK
发明人： MORITA TOSHIO , INOUE HITOSHI , YAMAMOTO RYUJI
IPC分类号： C08J5/18 , C01B31/02 , C08K7/06 , C08K7/24 , C08L101/00 , C09D5/24 , D01F9/127 , H01B1/04 , H01B1/24
摘要： A branched vapor-grown carbon fiber having an outer diameter of 0.5 µm or less and an aspect ratio of at least 10, the carbon fiber having a compressed specific resistance of 0.02 ©.cm or less, each fiber filament having a hollow cylindrical structure, preferably the carbon fiber containing boron and having a compressed specific resistance of 0.018 ©.cm or less. An electrically conductive transparent composition comprising a resin binder and carbon fiber incorporated into the binder, having transparency and comprising vapor-grown carbon fiber having an outer diameter of 0.01-0.1 µm, an aspect ratio of 10-15,000, and a compressed specific resistance of 0.02 Q.cm or less, and surface resistivity of 10,000 ©/–¡ or less. An electrically conductive transparent material formed from the aforementioned electrically conductive transparent composition.

10. 发明专利

DE60143954D1 VERZWEIGTE, AUF DAMPF GEWACHSENE KOHLENSTOFFFASER,UND IHRE VERWENDUNG 未知
公开(公告)号：DE60143954D1
公开(公告)日：2011-03-10
申请号：DE60143954
申请日：2001-12-19
申请人： SHOWA DENKO KK
发明人： MORITA TOSHIO , INOUE HITOSHI , YAMAMOTO RYUJI
IPC分类号： A61B1/00 , C08J5/18 , C01B31/02 , C08K7/06 , C08K7/24 , C08L101/00 , C09D5/24 , D01F9/127 , H01B1/04 , H01B1/24

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