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    • 3. 发明申请
    • PROCESS FOR PRODUCTION OF ALLYL ACETATE PRODUCTION CATALYST
    • 生产乙酸乙酯生产催化剂的方法
    • WO2008133126A3
    • 2009-07-02
    • PCT/JP2008057388
    • 2008-04-09
    • SHOWA DENKO KKKADOWAKI ETSUKOOGUCHI WATARUNAKAJO TETSUOIWAMA YASUHIRO
    • KADOWAKI ETSUKOOGUCHI WATARUNAKAJO TETSUOIWAMA YASUHIRO
    • B01J37/16
    • B01J23/8946B01J23/60B01J37/16C07C67/055C07C69/007C07C69/155
    • An allyl acetate production catalyst comprising at least (a) palladium, (b) gold, (c) a compound containing at least one element selected from copper, nickel, zinc and cobalt, (d) an alkali metal salt compound and (e) a carrier, is produced by a process comprising step 1 in which a homogeneous solution of a palladium-containing compound and a gold-containing compound is supported on a carrier by contact therewith, step 2 in which the carrier obtained in step 1 is contacted with an alkali solution for impregnation, step 3 in which the carrier obtained in step 2 is subjected to reduction treatment, and step 4 in which a compound containing at least one element selected from copper, nickel, zinc and cobalt and an alkali metal salt compound are supported onto the carrier obtained in step 3. The obtained allyl acetate production catalyst has minimal reduction in activity and improved selectivity, when used for production of allyl acetate from propylene, oxygen and acetic acid.
    • 至少包含(a)钯,(b)金,(c)含有至少一种选自铜,镍,锌和钴的元素的化合物的乙酸烯丙酯生产催化剂,(d)碱金属盐化合物和(e) 通过包括步骤1的方法制备载体,其中含钯化合物和含金化合物的均匀溶液通过接触负载在载体上,步骤2将步骤1中获得的载体与 用于浸渍的碱溶液,其中步骤2中获得的载体进行还原处理的步骤3,以及步骤4,其中含有选自铜,镍,锌和钴中的至少一种元素的化合物和碱金属盐化合物是 负载在步骤3中获得的载体上。当用于从丙烯,氧气和乙酸生产乙酸烯丙酯时,所得到的乙酸烯丙酯生产催化剂的活性降低和选择性提高。