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1. 发明申请

WO2004101664A2 POROUS BODY, PRODUCTION METHOD THEREOF AND COMPOSITE MATERIAL USING THE POROUS BODY 审中-公开
标题翻译：多孔体，其生产方法及使用多孔体的复合材料
公开(公告)号：WO2004101664A2
公开(公告)日：2004-11-25
申请号：PCT/JP2004/006697
申请日：2004-05-12
申请人： SHOWA DENKO K.K. , KUROSE, Takashi , TAKAHASHI, Tatsuhiro , SOTOWA, Chiaki , MORITA, Toshio
发明人： KUROSE, Takashi , TAKAHASHI, Tatsuhiro , SOTOWA, Chiaki , MORITA, Toshio
IPC分类号： C08J9/00
CPC分类号： C08J9/0085 , B01J21/18 , B01J31/06 , B01J31/061 , B01J31/08 , B01J32/00 , B01J35/002 , B01J35/0033 , B01J35/023 , B01J35/026 , B01J35/06 , B01J35/10 , B01J35/1014 , B01J37/32 , B22F2998/10 , C02F1/283 , C02F2303/185 , C04B38/0045 , C04B41/009 , C04B41/48 , C04B41/4888 , C04B41/51 , C04B41/63 , C04B41/69 , C04B41/83 , C04B41/88 , C04B2111/00793 , C04B2111/0081 , C08J9/26 , C08J9/28 , C08J9/40 , C08J2201/038 , C08J2201/048 , C08J2201/0504 , C08J2305/00 , C08J2375/04 , C22C47/08 , H01M4/9083 , H01M4/926 , H01M8/0234 , Y02P70/56 , Y10S977/842 , Y10T428/249927 , Y10T428/24994 , Y10T428/30 , C04B35/52 , C04B38/04 , C04B40/0078 , C04B14/386 , C04B30/02 , C04B38/00 , C04B38/0074 , C04B38/10 , C04B41/457 , C04B41/4523 , C04B35/83 , C22C47/06 , B22F3/114
摘要： A porous material comprising vapor grown carbon fiber in an amount of 10 to 90 mass%, fiber filaments of the carbon fiber forming a three-dimensional network and having a diameter of 1 to 1,000 nm, an aspect ratio of 5 to 15,000, a specific surface area (by BET method) of 2 to 2,000 m 2 /g, and the ratio of the intensity of the peak at 1,360 cm -1 in a Raman scattering spectrum of the carbon fiber to that of the peak at 1,580 cm -1 in the spectrum(I 1360/ I 1580) is 0.1 to 2.0, wherein the porosity of the porous material (V/V 0 ) is 0.50 to 0.99 and a specific surface area is 5 to 1,000 m 2 /g; and a production method and use thereof. The vapor grown carbon fiber impregnated in the porous material of the present invention does not contain aggregates and a three-dimensional network is formed between the fiber filaments, wherein length of each of the fiber filaments is maintained. Therefore, the vapor grown carbon fiber enables to readily produce a composite material (porous material), in which even a small amount of addition of vapor grown carbon fiber can exhibit sufficient effect.
摘要翻译： 10.一种多孔材料，其含有10〜90质量％的蒸气生长碳纤维，所述碳纤维的纤维丝形成三维网状物，直径为1〜1000nm，长径比为5〜15000，表面积（BET法）为2〜2000m 2 / g，碳纤维的拉曼散射光谱中的1,360cm -1处的峰强度与峰值的峰强度的比值为1,580 （I1360 / I1580）为0.1〜2.0，其中多孔材料（V / V0）的孔隙率为0.50〜0.99，比表面积为5〜1000m 2 / g，及其制造方法及其用途。浸渍在本发明的多孔材料中的蒸气生长的碳纤维不含有聚集体，并且在纤维长丝之间形成三维网络，其中维持每根纤维长度。因此，气相生长碳纤维能够容易地生产即使少量添加气相生长碳纤维也能发挥足够的效果的复合材料（多孔质材料）。

2. 发明申请

WO2004094521A1 CARBON FIBER-CONTAINING RESIN DISPERSION SOLUTION AND RESIN COMPOSITE MATERIAL 审中-公开
标题翻译：含碳纤维的树脂分散溶液和树脂复合材料
公开(公告)号：WO2004094521A1
公开(公告)日：2004-11-04
申请号：PCT/JP2004/005898
申请日：2004-04-23
申请人： SHOWA DENKO K.K. , TAKAHASHI, Tatsuhiro , SATO, Eiji , MORITA, Toshio
发明人： TAKAHASHI, Tatsuhiro , SATO, Eiji , MORITA, Toshio
IPC分类号： C08K7/06
CPC分类号： C08K7/06
摘要： A vapor-grown-carbon-fiber-containing dispersion containing vapor grown carbon fiber having a fiber diameter of 0.001 to 5 μm and an aspect ration of 5 to 15,000, a resin soluble in an organic solvent, and an organic solvent having an ET value of 45 or less, which value is a solvent parameter calculated from the absorption spectrum of pyridinium-N-phenol betaine, wherein (1) lumps of the carbon fiber are partially disintegrated to thereby allow individual filaments of the carbon fiber to be present as dispersed or (2) the carbon fiber is present such that carbon fiber lumps having a diameter of 40 μm or less and separated individual carbon fiber filaments are intermingled; a production method of the dispersion; vapor-grown-carbon-fiber-containing resin composite material obtained by the method; and electroconductive material and thermal conductive material using the resin composite material. The present invention enables to prepare a resin solution wherein vapor grown carbon fiber is uniformly dispersed and to easily obtain electroconductive material and thermal conductive material from the dispersed solution.
摘要翻译：将含有纤维直径为0.001〜5μm，外观比例为5〜15,000的气相生长碳纤维，可溶于有机溶剂的树脂和具有ET值的有机溶剂的含有气相生长碳纤维的分散液为45或更小，该值是由吡啶鎓-N-酚甜菜碱的吸收光谱计算的溶剂参数，其中（1）碳纤维块被部分崩解，从而允许碳纤维的单丝以分散的形式存在或者（2）存在碳纤维，使得直径为40μm以下的碳纤维块和分离的单个碳纤维丝混合; 分散体的制造方法; 通过该方法获得的含气态生长碳纤维的树脂复合材料; 导电材料和使用树脂复合材料的导热材料。本发明能够制备其中气相生长碳纤维均匀分散并且容易地从分散溶液获得导电材料和导热材料的树脂溶液。

3. 发明申请

WO2004099477A3 FINE CARBON FIBER WITH LINEARITY AND RESIN COMPOSITE MATERIAL USING THE SAME 审中-公开
公开(公告)号：WO2004099477A3
公开(公告)日：2004-11-18
申请号：PCT/JP2004/006502
申请日：2004-05-07
申请人： SHOWA DENKO K.K. , YONETAKE, Koichiro , TAKAHASHI, Tatsuhiro , YAMAMOTO, Ryuji , MORITA, Toshio
发明人： YONETAKE, Koichiro , TAKAHASHI, Tatsuhiro , YAMAMOTO, Ryuji , MORITA, Toshio
IPC分类号： D01F9/127
摘要： The fine carbon fiber obtained by pulverizing vapor grown fine carbon fiber, each fiber including a hollow space extending along its axis, and having an outer diameter of 1 to 1,000 nm, an aspect ratio of 5 to 1,000, and a BET specific surface area of 2 to 2,000 m 2 /g, wherein the average interlayer distance (d 002 ) is 0.345 nm or less, and the ratio of the peak height (Id) of the band (e.g. 1,341 to 1,349 cm -1 ) in a Raman scattering spectrum to that of the peak height (Ig) of the band (e.g. 1,570 to 1,578 cm -1 ) (Id/Ig) is 0.1 to 2, a bending angle of 30° or less with respect to the axis; a composite material comprising the fine carbon fiber and a resin serving as a matrix, wherein the fine carbon fiber is oriented in one direction through, application of an external force; and a production method and use thereof. The linear fine carbon fiber of the present invention exhibits excellent dispersibility in a matrix and is readily oriented by application of an external force, and therefore, enables to produce a composite material, wherein merely the carbon fiber is or both the fine carbon fiber and the matrix resin are oriented in one direction.

4. 发明申请

WO2004094520A1 RESIN CRYSTALLIZATION PROMOTER AND RESIN COMPOSITION 审中-公开
标题翻译：树脂结晶促进剂和树脂组合物
公开(公告)号：WO2004094520A1
公开(公告)日：2004-11-04
申请号：PCT/JP2004/005895
申请日：2004-04-23
申请人： SHOWA DENKO K.K. , TAKAHASHI, Tatsuhiro , MORITA, Toshio
发明人： TAKAHASHI, Tatsuhiro , MORITA, Toshio
IPC分类号： C08K7/06
CPC分类号： C08K7/06 , C08K2201/016
摘要： The present invention relates to a thermoplastic resin crystallization promoter comprising fine carbon fiber consisting of fiber filaments having a diameter of 0.001 µm to 5 µm and an aspect ratio of 5 to 15,000, a thermoplastic resin composition consisting of the fine carbon fiber and thermoplastic resin and comprising crystallized resin, and a production method thereof. The crystallization promoter comprising the fine carbon fiber of the present invention enables to crystallize even an amorphous resin, which has an irregular molecular structure and therefore is not crystallized, or which exhibits low crystallization degree and therefore is difficult to crystallize by means of a conventional crystallization promoter. The crystallization promoter provides a thermoplastic resin composition, which, when molded, exhibits improved strength and tribological characteristics and is further reinforced when mixed with a filler.
摘要翻译：本发明涉及一种热塑性树脂结晶促进剂，其包含由直径为0.001〜5μm，长径比为5〜15,000的纤维长丝构成的细碳纤维，由碳纤维和热塑性树脂构成的热塑性树脂组合物，包括结晶树脂及其制备方法。包含本发明的细碳纤维的结晶促进剂能够使具有不规则分子结构的非晶性树脂结晶，因此不结晶，或者结晶度低，因此难以通过常规结晶而结晶子。结晶促进剂提供了一种热塑性树脂组合物，其在模制时表现出改进的强度和摩擦学特性，并且当与填料混合时进一步增强。

5. 发明公开

EP1615968A1 RESIN CRYSTALLIZATION PROMOTER AND RESIN COMPOSITION 审中-公开
标题翻译：树脂结晶促进剂和树脂组合物
公开(公告)号：EP1615968A1
公开(公告)日：2006-01-18
申请号：EP04729200.8
申请日：2004-04-23
申请人： Showa Denko K.K.
发明人： TAKAHASHI, Tatsuhiro , MORITA, Toshio
IPC分类号： C08K7/06 , D01F9/127 , H01B1/24
CPC分类号： C08K7/06 , C08K2201/016
摘要： The present invention relates to a thermoplastic resin crystallization promoter comprising fine carbon fiber consisting of fiber filaments having a diameter of 0.001 µm to 5 µm and an aspect ratio of 5 to 15,000, a thermoplastic resin composition consisting of the fine carbon fiber and thermoplastic resin and comprising crystallized resin, and a production method thereof. The crystallization promoter comprising the fine carbon fiber of the present invention enables to crystallize even an amorphous resin, which has an irregular molecular structure and therefore is not crystallized, or which exhibits low crystallization degree and therefore is difficult to crystallize by means of a conventional crystallization promoter. The crystallization promoter provides a thermoplastic resin composition, which, when molded, exhibits improved strength and tribological characteristics and is further reinforced when mixed with a filler.
摘要翻译：本发明涉及一种热塑性树脂结晶化促进剂，该热塑性树脂结晶化促进剂含有由直径为0.001〜5μm，长径比为5〜15,000的纤维丝构成的微细碳纤维，由该微细碳纤维和热塑性树脂构成的热塑性树脂组合物，包含结晶树脂及其制造方法。由本发明的微细碳纤维构成的结晶化促进剂甚至能够使具有不规则分子结构并因此不结晶的无定形树脂结晶，或者由于结晶度低而难以用常规结晶方法结晶子。结晶促进剂提供热塑性树脂组合物，其在模制时表现出改善的强度和摩擦学特性，并且当与填料混合时进一步增强。

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