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1. 发明公开

EP0745604A3 Room temperature curable fluoropolymer composition; and fluorine-containing organosilicon compounds, a method of producing the same, and room temperature curable silicone composition containing the same 失效
标题翻译： RTV含氟聚合物组合物; 有机硅化合物，它们的制备方法和组合物含有RTV硅含氟
公开(公告)号：EP0745604A3
公开(公告)日：1998-07-29
申请号：EP96108460
申请日：1996-05-28
申请人： SHINETSU CHEMICAL CO
发明人： MATSUDA TAKASHI , SAKAMOTO TAKAFUMI , SATO SHINICHI , KOIKE NORIYUKI , TARUMI YASUO , KIMURA TSUNEO , YAMAMOTO YASUSHI , ARAI MASATOSHI
IPC分类号： C07F7/18 , C07F7/21 , C08G65/00 , C08G65/336 , C08G77/04 , C08L83/00
CPC分类号： C08G65/007 , C07F7/1836 , C07F7/184 , C07F7/1896 , C07F7/21 , C08G65/336
摘要： A room temperature curable fluoropolymer composition is provided which comprises (A) a straight chain fluoropolymer compound containing, in its backbone chain, at least one structure selected from a perfluoroalkylene structure and a perfluoropolyether structure and having a hydrolyzable silyl group at both ends of its molecular chain, (B) an organic compound having at least one carbonyl group per molecule, and (C) one compound selected from (C-1) an organic compound having at least one primary amino group per molecule and (C-2) a compound having at least one proton per molecule and having an acid dissociation constant (pKa) in water of 2 or less. Another room temperature curable composition is also provided which comprises said (A) component, (B') an organosilicon compound having at least two silanol groups per molecule, and (C') a condensation accelerator. These compositions are not only excellent in heat resistance, weatherability, electrical properties, processability, chemical resistance, solvent resistance and oil repellant properties, but also excellent in fast curability and deep-portion curability. A novel compound which is suitable as said fluoropolymer compound (A) is further provided.

2. 发明专利

AT512186T 未知
公开(公告)号：AT512186T
公开(公告)日：2011-06-15
申请号：AT09178350
申请日：2009-12-08
申请人： SHINETSU CHEMICAL CO
发明人： SAKANO YASUNORI , KOIKE NORIYUKI , KISHITA HIROFUMI
IPC分类号： C08G77/04 , C07F7/21 , C09D4/00 , C09D175/16
摘要： The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1): wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that the total of a and b is 3, 4, or 5; R 1 is a group represented by the following formula (2): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ -(C 4 H 8 O) d (C 3 H 6 O) e (C 2 H 4 O) f (CH 2 O) g -€ƒ€ƒ€ƒ€ƒ€ƒ(2) wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that the molecular weight of R 1 is in the range of 30 to 300, and these repeating units may be sequenced at random; R 2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3): wherein R 3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group, R 4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, and n is 1 or 2; Rf is a perfluoropolyether residue represented by the following formula (4): wherein j, k, 1, and m are, independently of each other, an integer of from 0 to 50, provided that the molecular weight of Rf is in the range of 200 to 6000, X is a fluorine atom or a trifluoromethyl group, and these repeating units may be sequenced at random; Z is a divalent organic group; and c is 0 or 1.

3. 发明专利

DE602004030633D1 Reinigung von Amidderivaten 未知
公开(公告)号：DE602004030633D1
公开(公告)日：2011-02-03
申请号：DE602004030633
申请日：2004-04-22
申请人： SHINETSU CHEMICAL CO
发明人： SAKANO YASUNORI , KOIKE NORIYUKI
IPC分类号： C07C231/24 , C07F7/12 , C07F7/20

4. 发明专利

DE602005003714D1 未知
公开(公告)号：DE602005003714D1
公开(公告)日：2008-01-24
申请号：DE602005003714
申请日：2005-06-06
申请人： SHINETSU CHEMICAL CO
发明人： KOIKE NORIYUKI , SAKANO YASUNORI
IPC分类号： C07C33/42 , C07C33/042 , C07C67/14 , C07C69/708 , C07F7/18 , C08G65/331 , C08G65/336
摘要： A fluorine-containing acetylene alcohol represented by the following formula (1), wherein Rf is a linear or branched perfluoroalkyl group having 3 to 100 carbon atoms and may have an ether bond, -C-O-C-, Q is a divalent hydrocarbon group having 1 to 6 carbon atoms, and R 1 is an alkyl group having 1 to 4 carbon atoms, ora fluorine-containing acetylene alcohol represented by the following formula (2), wherein Rf and Q are as defined above, R 1 , R 2 and R 3 may be the same with or different from each other and represent an alkyl group having 1 to 4 carbon atoms, and Z is a divalent organic group having 1 to 20 carbon atoms.

5. 发明专利

DE60127202D1 未知
公开(公告)号：DE60127202D1
公开(公告)日：2007-04-26
申请号：DE60127202
申请日：2001-04-20
申请人： SHINETSU CHEMICAL CO
发明人： KOIKE NORIYUKI , YAMAGUCHI KOICHI , SAKANO YASUNORI
IPC分类号： C07F7/08
摘要： A novel organosilicon compound obtained by introducing an alkylene group or analogue instead of the oxygen atom in an Si-O-Si linkage is capable of hydrosilylation reaction with another compound having a vinyl group to form a hydrosilylated derivative which is less prone to decomposition under acidic or basic conditions.

6. 发明专利

DE60100203T2 未知
公开(公告)号：DE60100203T2
公开(公告)日：2004-02-12
申请号：DE60100203
申请日：2001-07-09
申请人： SHINETSU CHEMICAL CO
发明人： MATSUDA TAKASHI , SATO SHINICHI , KOIKE NORIYUKI
IPC分类号： C09K3/10 , C08F8/42 , C08G65/00 , C08G65/336 , C08K5/13 , C08K5/18 , C08K5/54 , C08L71/00 , C08L83/16 , C08L83/08 , C08L83/10
摘要： A fluoropolyether rubber composition comprising (A) a linear fluoropolyether compound containing at least two alkenyl groups and having a perfluoroalkyl ether structure in its backbone, (B) an organosilicon compound having at least two silicon atom-bound hydrogen atoms which all form H-Si(CaH2a)Si structures wherein "a" is 1, 2 or 3, (C) a hydrosilylation catalyst, and (D) an antidegradant, typically an aromatic secondary amine compound is curable into products having heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency, and weather resistance as well as resistance to acid, alkali and oxidative degradation.

7. 发明专利

DE69523822T2 未知
公开(公告)号：DE69523822T2
公开(公告)日：2002-06-06
申请号：DE69523822
申请日：1995-06-22
申请人： SHINETSU CHEMICAL CO
发明人： SATO SHINICHI , KOIKE NORIYUKI , MATSUDA TAKASHI , KISHITA HIROFUMI , ARAI MASATOSHI
IPC分类号： C07C235/08 , C07D295/185 , C07F7/21 , C08G65/00 , C08G65/336 , C08G69/42 , C08G77/46 , C08L83/08 , C07C233/05 , C08G65/32 , C08L71/02 , C08L77/06 , C08L77/10 , C08L83/04 , C07F7/18
摘要： Novel organic fluorine compounds are of formula (1): wherein R and R are monovalent hydrocarbon groups, Q is a group of formula (2) or (3): wherein R is a divalent hydrocarbon group which may have an intervening oxygen, nitrogen or silicon atom, R and R are divalent hydrocarbon groups, Rf is a divalent perfluoroalkylene or perfluoropolyether group, and letter a is an integer of 0-10. A curable composition comprising (A) a fluorinated amide compound having at least two aliphatic unsaturated groups of formula (1), (B) a fluorinated organohydrogensiloxane containing at least one monovalent perfluoroalkyl ether or perfluoroalkyl group and at least two hydrosilyl groups, and (C) a platinum group compound cures into elastomers solvent and chemical resistance.

8. 发明专利

DE69514888T2 未知
公开(公告)号：DE69514888T2
公开(公告)日：2000-10-05
申请号：DE69514888
申请日：1995-11-10
申请人： SHINETSU CHEMICAL CO
发明人： SATO SHINICHI , KOIKE NORIYUKI
IPC分类号： C07F7/21 , C08F8/42 , C08K5/549 , C08L71/00 , C08L71/02
摘要： This invention provides an organosilicon compound represented by the following general formula (1): wherein R are independently a hydrogen atom or an unsubstituted or substituted monovalent hydrocarbon group such as methyl, phenyl, 3,3,3-trifluoropropyl and 6,6,6,5,5,4,4,3,3-nonafluorohexyl groups, R are independently an alkylene group such as ethylene and propylene groups, Rf is a perfluoroalkylene group, such as -C4F8- and -C6F12-, or a divalent perfluoropolyether group, such as a group having the formula: wherein m and n are each an integer such that m + n is 2 to 200, and Z is a group having the general formula: wherein R are independently the same unsubstituted or substituted monovalent hydrocarbon group as the group R , and a is an integer of 2 to 4. This compound is useful as a crosslinking agent which is used when curing an unsaturated group-containing polymer by hydrosilylation reaction.

9. 发明专利

DE69505332D1 未知
公开(公告)号：DE69505332D1
公开(公告)日：1998-11-19
申请号：DE69505332
申请日：1995-10-30
申请人： SHINETSU CHEMICAL CO
发明人： MATSUDA TAKASHI , SATO SHINICHI , KOIKE NORIYUKI
IPC分类号： C07C231/02 , C07C231/24 , C07C235/06 , C07C235/16
摘要： Provided is a method of producing a highly pure amide compound in a high yield, wherein a silazane compound or/and a silane compound having at least one silicon-nitrogen bond are added to a reaction mixture obtained by reacting an acylfluoride group-containing compound with an amino compound, wherein the amide compound is present together with hydrogen fluoride and/or the amine hydrofluoride, thereby removing the hydrogen fluoride and/or the amine hydrofluoride from the reaction mixture.

10. 发明专利

DE4000661C2 未知
公开(公告)号：DE4000661C2
公开(公告)日：1997-03-20
申请号：DE4000661
申请日：1990-01-11
申请人： SHINETSU CHEMICAL CO
发明人： TAKAOKA AKIO , KOIKE NORIYUKI , FUJII HIDEKI
IPC分类号： C07C43/17 , C08F16/14 , C08F214/26 , C08F216/14 , C08F290/00 , C08F299/00 , C08G77/38 , C08G77/385
摘要： An oligohexafluoropropylene oxide compound having the general formula (I): (I) wherein n represents an integer of 2 to 5. The compound is useful for preparing a polymer having good thermal resistance, chemical stability, non-adhesion properties, water and oil repellencies, and flexibility, when copolymerized if other monomers.

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