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1. 发明公开

EP0465263A3 Polysilethylenesiloxane 失效
公开(公告)号：EP0465263A3
公开(公告)日：1992-09-09
申请号：EP91306117.2
申请日：1991-07-05
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Takago, Toshio , Kishita, Hirofumi , Kinami, Hitoshi , Fukuda, Kenichi , Sato, Shinichi , Yamaguchi, Koichi , Suganuma, Shuji
IPC分类号： C08G77/50
CPC分类号： C08G77/485 , C08G77/50
摘要： The present polysilethylenesiloxane is a liquid polymer represented by the following general formula:

wherein R¹ and R² each represent a lower alkyl group and R³ and R⁴ each represent a perfluoroalkylethyl group, and n is an integer of 10 to 1,000. This polymer is quite useful as a major component of elastomer compositions having chemical resistance, electrical properties, and high strength.
摘要翻译：本聚二乙烯硅氧烷是由下列通式表示的液体聚合物：其中R 1和R 2各代表低级烷基，R 3和R 4各代表全氟烷基乙基，n是10-1,000的整数。该聚合物作为具有耐化学性，电特性和高强度的弹性体组合物的主要组分是非常有用的。

2. 发明公开

EP0393984A3 Curable silicone composition 失效
标题翻译：可固化硅胶组合物
公开(公告)号：EP0393984A3
公开(公告)日：1991-07-03
申请号：EP90304100.2
申请日：1990-04-17
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Kishita, Hirofumi, Iryu-apartment 402, 3-19-1 , Yamaguchi, Koichi , Suganuma, Shuji
IPC分类号： C08L83/07 , C08L83/08
CPC分类号： C08L83/08 , C08G77/24 , C09D183/08 , C08L83/00
摘要： A curable silicone composition comprising as a basic component an organopolysiloxane having at least two silicon-bonded alkenyl groups, a silicon-bonded fluorine-containing substituent of the formula (I):
wherein m is an integer of from 1 to 4, and n is an integer of from 1 to 6, and /or the formula (II):
wherein m and n are as defined above, and at least one silicon-bonded fluorine-containing substituent of the formula (III):
C l F 2l+1 (CH₂) k - (III)
wherein k is an integer of from 1 to 4, and l is an integer of from 1 to 10, and/or the formula (IV):
C l F 2l+1 -(-CH₂-) k -O-(-CH₂-) m - (IV)
wherein k, l and m are as defined above, and further comprising an organohydrogenpolysiloxane, and a platinum family metal catalyst. This composition can form a coating film having a low surface energy and therefore having good release properties, etc.

3. 发明授权

EP0538061B1 Fluorine-containing organosilicon compound and process of producing the same 失效
标题翻译：它们的制备方法的有机硅化合物和工艺含氟
公开(公告)号：EP0538061B1
公开(公告)日：1998-03-18
申请号：EP92309483.3
申请日：1992-10-16
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Kishita, Hirofumi , Yamaguchi, Kouichi , Suganuma, Shuji
IPC分类号： C07F7/12 , C07F7/14
CPC分类号： C07F7/12 , C07F7/14

4. 发明公开

EP0469928A2 Curable silicone composition and its cured product 失效
标题翻译： äare Si ung ung ung。。。。。。。
公开(公告)号：EP0469928A2
公开(公告)日：1992-02-05
申请号：EP91307128.8
申请日：1991-08-02
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Kishita, Hirofumi , Yamaguchi, Kouichi , Takano, Kouji , Suganuma, Shuji
IPC分类号： C08L83/08 , C09D183/08
CPC分类号： C08L83/08 , C09D183/08 , C08L83/00
摘要： A curable silicone composition comprising:

(A) an alkenyl group-containing organopolysiloxane containing silicon-bonded alkenyl groups and a silicon-bonded fluorine-containing substituent having the general formula (1):

Rf-O-Y- (1)

wherein Rf is a perfluoroalkenyl group having 5 to 10 carbon atoms, and Y represents a divalent organic group,
(B) an organohydrogenpolysiloxane, and
(C) a catalyst for addition reaction between components (A) and (B). This composition can form a cured coating which adheres firmly to various substrates and has good release properties, stability in the release properties, water- and oil-repellency, and solvent resistance. The coating exhibits good release properties even against pressure sensitive adhesives comprising a dimetylpolysiloxane.
摘要翻译：一种可固化有机硅组合物，其包含：（A）含有烯基的含硅键合的烯基的有机聚硅氧烷和具有通式（1）的与硅键合的含氟取代基：Rf-OY-（1）其中Rf是全氟链烯基具有5〜10个碳原子的基团，Y表示二价有机基团，（B）有机氢聚硅氧烷，（C）成分（A）和（B）之间的加成反应用催化剂。该组合物可以形成固化的涂层，其牢固地粘附到各种基材上并且具有良好的剥离性能，脱模性能的稳定性，拒水拒油性和耐溶剂性。即使对于包含二甲基聚硅氧烷的压敏粘合剂，该涂层表现出良好的剥离性能。升

5. 发明公开

EP0465177A1 Fluorine-containing organic silicon compounds 失效
标题翻译：氟化合物Siliziumverbindungen。
公开(公告)号：EP0465177A1
公开(公告)日：1992-01-08
申请号：EP91305915.0
申请日：1991-06-28
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Kishita. Hirofumi , Yamaguchi, Kouichi , Fujii, Hideki , Suganuma, Shuji , Saito, Yoshikazu , Sato, Shinichi , Fukuda, Kenichi , Kobayashi, Nobuyuki
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： The synthesis and use of a fluorine-containing organic silicon compound represented by:

wherein each R¹ independently represents a monovalent hydrocarbon group having 1-10 carbon atoms, and each R² independently represents a monovalent hydrocarbon group having 1-10 carbon atoms or a CH₂CH₂Rf group, such that at least one R² is CH₂CH₂Rf, wherein Rf is a perfluoroalkyl group having 1-10 carbon atoms; the compounds of formula (I) are useful in the preparation of fluorine-containing polysylethylenesiloxanes having excellent solvent-resisting and surface-lubricating properties.
摘要翻译：由表示的含氟有机硅化合物的合成和使用，其中每个R 1独立地表示具有1-10个碳原子的一价烃基，并且每个R 2独立地表示具有 1-10个碳原子或CH 2 CH 2 R f基团，使得至少一个R 2是CH 2 CH 2 R f，其中Rf是具有1-10个碳原子的全氟烷基; 式（I）化合物可用于制备具有优异的耐溶剂性和表面润滑性的含氟聚乙烯基硅氧烷。

6. 发明授权

EP0465263B1 Polysilethylenesiloxane 失效
公开(公告)号：EP0465263B1
公开(公告)日：1996-10-09
申请号：EP91306117.2
申请日：1991-07-05
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Takago, Toshio , Kishita, Hirofumi , Kinami, Hitoshi , Fukuda, Kenichi , Sato, Shinichi , Yamaguchi, Koichi , Suganuma, Shuji
IPC分类号： C08G77/50
CPC分类号： C08G77/485 , C08G77/50

7. 发明公开

EP0538061A3 Fluorine-containing organosilicon compound and process of producing the same 失效
标题翻译：含氟有机硅化合物及其制造方法
公开(公告)号：EP0538061A3
公开(公告)日：1994-02-16
申请号：EP92309483.3
申请日：1992-10-16
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Kishita, Hirofumi , Yamaguchi, Kouichi , Suganuma, Shuji
IPC分类号： C07F7/12 , C07F7/14
CPC分类号： C07F7/12 , C07F7/14
摘要： A fluorine-containing organosilicon compound represented by the following general formula:

wherein R represents an alkyl group or an aryl group, a is an integer of 1 to 7, b is an integer of 2 to 8, and c is an integer of 1 to 3. This compound is useful as a surface treating agent for silicas, an adhesive improver for resists, an oil- or water-repellent treating agent, and a raw material for synthesis of various silicone compounds.
摘要翻译：由下列通式表示的含氟有机硅化合物：其中R表示烷基或芳基，a是1至7的整数，b是2至8的整数，并且c是1至1的整数 3.该化合物可用作二氧化硅的表面处理剂，抗蚀剂用粘合改进剂，防油或防水处理剂和用于合成各种硅氧烷化合物的原料。

8. 发明公开

EP0465263A2 Polysilethylenesiloxane 失效
标题翻译： Polysilethylensiloxan。
公开(公告)号：EP0465263A2
公开(公告)日：1992-01-08
申请号：EP91306117.2
申请日：1991-07-05
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Takago, Toshio , Kishita, Hirofumi , Kinami, Hitoshi , Fukuda, Kenichi , Sato, Shinichi , Yamaguchi, Koichi , Suganuma, Shuji
IPC分类号： C08G77/50
CPC分类号： C08G77/485 , C08G77/50
摘要： The present polysilethylenesiloxane is a liquid polymer represented by the following general formula:

wherein R¹ and R² each represent a lower alkyl group and R³ and R⁴ each represent a perfluoroalkylethyl group, and n is an integer of 10 to 1,000. This polymer is quite useful as a major component of elastomer compositions having chemical resistance, electrical properties, and high strength.
摘要翻译：本发明的聚硅氧烷是由以下通式表示的液体聚合物：其中R 1和R 2各自表示低级烷基，R 3和R 4各自表示全氟烷基乙基， n为10〜1000的整数。该聚合物作为具有耐化学性，电性能和高强度的弹性体组合物的主要成分是非常有用的。

9. 发明授权

EP0469928B1 Curable silicone composition and its cured product 失效
标题翻译：可固化硅氧烷成分和固化物。
公开(公告)号：EP0469928B1
公开(公告)日：1995-10-18
申请号：EP91307128.8
申请日：1991-08-02
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Kishita, Hirofumi , Yamaguchi, Kouichi , Takano, Kouji , Suganuma, Shuji
IPC分类号： C08L83/08 , C09D183/08
CPC分类号： C08L83/08 , C09D183/08 , C08L83/00

10. 发明公开

EP0465129A1 Fluorine-containing organosilicon compound 失效
标题翻译：氟内酯有机硅氧烷。
公开(公告)号：EP0465129A1
公开(公告)日：1992-01-08
申请号：EP91305830.1
申请日：1991-06-27
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Takago, Toshio , Kishita, Hirofumi , Sato, Shinichi , Kinami, Hitoshi , Suganuma, Shuji , Yamaguchi, Koichi , Fukuda, Kenichi , Yamada, Hirokazu
IPC分类号： C07F7/08
CPC分类号： C07F7/0841
摘要： The fluorine-containing organosilicon compound of the present invention is represented by the following formula:

wherein Rf is a perfluoroalkyl group. This compound is quite useful as a raw material for the production of polysilethylenesiloxanes excellent in solvent resistance.
摘要翻译：本发明的含氟有机硅化合物由下式表示：＆lt; CHEM＆gt; CHEM，其中Rf是全氟烷基。该化合物作为生产耐溶剂性优异的聚硅氧烷硅氧烷的原料是非常有用的。

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