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    • 1. 发明授权
    • Supersensitized color photographic material
    • 超强彩色摄影材料
    • US3840376A
    • 1974-10-08
    • US24869172
    • 1972-04-28
    • SHIBA KOISHI YHINATA MSATO AYOSHIDA Y
    • YOSHIDA YSATO AHINATA MOISHI YSHIBA K
    • G03C1/29G03C8/02G03C1/10G03C1/14
    • G03C8/02G03C1/29Y10S430/118
    • A green-sensitive silver halide photographic emulsion for use in photographic materials containing dye developers suitable for the diffusion transfer process containing, in combination, at least one of the sensitizing dyes represented by the formula I.

      wherein Y is selected from the group consisting of a sulfur atom and a selenium atom, Z represents a divalent group necessary to form a benzene ring, which may be substituted, Z1 represents a divalent group necessary to form a benzene ring, which may be substituted, R5 and R6 are each selected from the group consisting of an alkyl group, a substituted alkyl group which is conventionally present in cyanine dyes and an allyl group, at least one of R5 and R6 being an alkyl group or a substituted alkyl group containing a group selected from the group consisting of a carboxyl group and a sulfo group, X2 is an anion, p is an integer of from 1 to 2, said dye forming an intramolecular salt when p is 1, is disclosed.

      wherein R1, R2, R3 and R4 are each selected from the group consisting of an alkyl group which is conventionally used in cyanine dyes and an allyl group, at least one of R1 and R2 being an alkyl group or a substituted alkyl group containing a group selected from the group consisting of a carboxyl group and a sulfo group; Y1 and Y2 are each selected from the group consisting of a hydrogen atom and a halogen atom, Y2 and Y4 are each selected from the group consisting of a hydrogen atom, a halogen atom, an alkoxy group, an amino group, an acylamido group, an acyloxy group, an alkoxycarbonylamino group, a cyano group, a trifluoromethyl group, an alkylsulfonyl group, a sulfamyl group, an alkylaminosulfonyl group, a morpholinosulfonyl group, an alkoxycarbonyl group, and a piperidinosulfonyl group, X1 represents an anion and n is an integer of from 1 to 2, said dye forming an intramolecular salt when n is 1, and at least one of the sensitized dyes represented by the formula II