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    • 9. 发明申请
    • PROCESS FOR PREPARING C10 to C30 ALCOHOLS
    • 制备C10至C30醇的方法
    • WO2015013350A1
    • 2015-01-29
    • PCT/US2014/047719
    • 2014-07-23
    • SHELL OIL COMPANYSHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    • HAMILTON, JR., David MorrisNILEKAR, AnandNENU, Nicoleta CristinaEDULJI, SmitaNAIR, Nitish
    • C07C29/141C07C29/145C07C45/28E21B43/16
    • C07C45/28C07C29/141C07C29/145C07C47/02C07C49/04C07C31/02C07C31/125
    • The present invention provides a process for preparing C10 to C30 alcohols, comprising the following steps: (i) reacting aliphatic, non-cyclic C10 to C30 olefins with N 2 O to obtain an oxidation reaction product comprising C10 to C30 carbonyls; (ii) reducing at least part of the C10 to C30 carbonyls in the oxidation reaction product to the corresponding C10 to C30 alcohols, wherein the aliphatic, non-cyclic C10 to C30 olefins are reacted with the N 2 O in step (i) by: (i-a) providing a liquid olefin feed comprising aliphatic, non-cyclic C10 to C30 olefins; (i-b) providing an oxidant feed comprising at least 5% by volume of N 2 O, based on the total oxidant feed; and (i-c) contacting the liquid olefin feed and the oxidant feed with a porous material in a reactor at a temperature in the range of from 150 to 500º C and a pressure in the range of from 10 to 300 bar. In another aspect the invention provides a process or producing surfactant compounds and a method of treating a crude oil containing formation.
    • 本发明提供一种制备C10至C30醇的方法,包括以下步骤:(i)使脂族,非环状C 10至C 30烯烃与N 2 O反应,得到包含C10至C30羰基的氧化反应产物; (ii)将氧化反应产物中的至少部分C10至C30羰基还原成相应的C10至C30醇,其中在步骤(i)中使脂族非环状C 10至C 30烯烃与N 2 O反应:( ia)提供包含脂族,非环状C 10至C 30烯烃的液体烯烃进料; (i-b)基于总氧化剂进料提供包含至少5体积%N 2 O的氧化剂进料; 和(i-c)使液体烯烃进料和氧化剂进料与反应器中的多孔材料接触,温度范围为150-500℃,压力范围为10-300巴。 在另一方面,本发明提供了一种方法或生产表面活性剂化合物和一种处理含原油的地层的方法。