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1. 发明申请

WO0247805A3 CATALYTIC PARTIAL OXIDATION PROCESS USING A CATALYST SYSTEM HAVING AN UPSTREAM AND A DOWNSTREAM PART 审中-公开
标题翻译：使用具有上游和下游部分的催化剂系统的催化部分氧化方法
公开(公告)号：WO0247805A3
公开(公告)日：2002-11-28
申请号：PCT/EP0114753
申请日：2001-12-13
申请人： SHELL INT RESEARCH , KRAMER GERT JAN , LEENHOUTS WILLEM PIETER , SCHOONEBEEK RONALD JAN , WIJNBELT JOHANNES
发明人： KRAMER GERT JAN , LEENHOUTS WILLEM PIETER , SCHOONEBEEK RONALD JAN , WIJNBELT JOHANNES
IPC分类号： B01J8/04 , B01J12/00 , B01J19/24 , B01J23/40 , B01J23/46 , B01J32/00 , B01J35/00 , B01J35/02 , B01J35/04 , B01J35/06 , B01J37/02 , C01B3/38 , C01B3/48 , C01B32/40 , H01M8/00 , H01M8/06 , C01B3/16
CPC分类号： B01J35/06 , B01J8/0446 , B01J12/007 , B01J23/40 , B01J35/0006 , B01J37/0225 , B01J37/0242 , C01B3/386 , C01B3/48 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/085 , C01B2203/1011 , C01B2203/1023 , C01B2203/1029 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1205 , C01B2203/1217 , C01B2203/1235 , C01B2203/1276 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , C01B2203/82 , Y02P20/52
摘要： The invention relates to a process for the catalytic partial oxidation of a hydrocarbonaceous feedstock, wherein a feed mixture comprising the hydrocarbonaceous feedstock and a molecular-oxygen containing gas is contacted with a catalyst system having an upstream part (3) and a downstream part (2), the downstream part (2) being in the form of a porous catalyst bed, wherein the catalyst system is retained in a reactor, the reactor comprising an upstream part (5) that contains the upstream part (3) of the catalyst system and a downstream part (6) that contains the downstream part (2) of the catalyst system, wherein the upstream part (3) of the catalyst system only partly fills the cross-sectional area of the fluid flow path of the upstream part of the reactor and the downstream part (3) of the catalyst system completely fills the cross-sectional area of the fluid flow path of the downstream part of the reactor. The invention further relates to a reactor comprising such a catalyst system and a catalytic reaction zone for the water-gas shift conversion of the effluent of the catalyst system, to a fuel cell system comprising such a reactor and a fuel cell, and to a vehicle provided with such a fuel cell system.
摘要翻译：本发明涉及烃类原料的催化部分氧化方法，其中包含烃类原料和含分子氧的气体的原料混合物与具有上游部分（3）和下游部分（2）的催化剂体系接触，），所述下游部分（2）为多孔催化剂床的形式，其中所述催化剂体系保留在反应器中，所述反应器包含含有所述催化剂体系的上游部分（3）的上游部分（5）和包含催化剂体系的下游部分（2）的下游部分（6），其中催化剂体系的上游部分（3）仅部分填充反应器上游部分的流体流动路径的横截面积并且催化剂系统的下游部分（3）完全填充反应器下游部分的流体流动路径的横截面积。本发明进一步涉及包含这种催化剂体系和用于催化剂体系流出物的水煤气变换转化的催化反应区的反应器，以及包含这种反应器和燃料电池的燃料电池系统，提供有这种燃料电池系统。

2. 发明申请

WO2011101406A3 PROCESS FOR SELECTIVE OXIDATION OF HYDROGEN SULPHIDE 审中-公开
标题翻译：硫化氢的选择性氧化方法
公开(公告)号：WO2011101406A3
公开(公告)日：2011-12-01
申请号：PCT/EP2011052341
申请日：2011-02-17
申请人： SHELL INT RESEARCH , SCHOONEBEEK RONALD JAN , WADMAN SIPKE HIDDE
发明人： SCHOONEBEEK RONALD JAN , WADMAN SIPKE HIDDE
IPC分类号： C01B17/04 , C10K1/26 , C10K1/34
CPC分类号： C10K1/004 , C01B17/0439 , C10K1/26 , C10K1/34
摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide-containing hydrocarbon and/or hydrogen feed gas to elemental sulphur in a reaction zone containing a Claus catalyst, comprising the steps of : i) reacting in the reaction zone the hydrogen sulphide in the hydrogen sulphide-containing hydrocarbon and/or hydrogen feed gas with sulphur dioxide at a pressure in the range of from 4 to 200 bar (absolute) and a temperature in the range of from 120 and 160 °C, such that the elemental sulphur formed is essentially in liquid form; ii) contacting the catalyst with a reducing atmosphere at elevated temperatures.
摘要翻译：本发明提供了一种在含有硫化氢的烃和/或氢气原料气中将硫化氢选择性氧化成含有克劳斯催化剂的反应区中的元素硫的方法，该方法包括以下步骤：i）在反应区所述含硫化氢的烃和/或氢气原料气中的硫化氢与二氧化硫在4-200巴（绝对）的压力和120-160℃的温度范围内，使得所形成的元素硫基本上呈液体形式; ii）在升高的温度下使催化剂与还原性气氛接触。

3. 发明申请

WO2011080198A2 COATING METHOD FOR STRUCTURED CATALYSTS 审中-公开
标题翻译：结构催化剂的涂覆方法
公开(公告)号：WO2011080198A2
公开(公告)日：2011-07-07
申请号：PCT/EP2010070593
申请日：2010-12-22
申请人： SHELL INT RESEARCH , BOUMENDJEL NARIMAN , BUGLASS JOHN GRAHAM , JENKINS YVETTE LOUISE , NIESEN GERARDUS PETRUS LAMBERTUS , SCHADDENHORST DAVID , SCHOONEBEEK RONALD JAN , VAN KLEI THIJMEN SIMON
发明人： BOUMENDJEL NARIMAN , BUGLASS JOHN GRAHAM , JENKINS YVETTE LOUISE , NIESEN GERARDUS PETRUS LAMBERTUS , SCHADDENHORST DAVID , SCHOONEBEEK RONALD JAN , VAN KLEI THIJMEN SIMON
IPC分类号： C10G2/00 , B01J37/02
CPC分类号： B01J37/0215 , B01J21/063 , B01J23/462 , B01J23/745 , B01J23/75 , B01J35/023 , B01J37/0221 , B01J37/0223 , B01J37/0225 , B01J37/0234 , B01J37/0242 , B01J37/0244 , C10G2/33 , C10G2/331
摘要： The invention relates to a method for applying a layer comprising a carrier material to a highly porous support, said method comprising the following steps: (a) applying a mixture comprising a liquid and a carrier material to a highly porous support having a size of at least 1 mm and a porosity within the range of between 50 and 98 volume%; (b) centrifuging and spinning the support; (c) drying and/or calcining the support.
摘要翻译：本发明涉及一种将包含载体材料的层施加到高度多孔载体上的方法，所述方法包括以下步骤：（a）将包含液体和载体材料的混合物施加到具有大小为至少1mm，孔隙率在50和98体积％之间的范围内; （b）离心并旋转载体; （c）干燥和/或煅烧载体。

4. 发明申请

WO2005029629A3 SOLID OXIDE FUEL CELL-BASED AUXILIARY POWER UNIT 审中-公开
标题翻译：固体氧化物燃料电池辅助电源
公开(公告)号：WO2005029629A3
公开(公告)日：2006-05-18
申请号：PCT/EP2004052306
申请日：2004-09-24
申请人： SHELL INT RESEARCH , BUGLASS JOHN GRAHAM , GOES MARINUS FRANCISCUS , SCHOONEBEEK RONALD JAN
发明人： BUGLASS JOHN GRAHAM , GOES MARINUS FRANCISCUS , SCHOONEBEEK RONALD JAN
IPC分类号： C01B3/38 , H01M8/04 , H01M8/06 , H01M8/12
CPC分类号： H01M8/0612 , C01B3/386 , C01B2203/0261 , C01B2203/066 , C01B2203/1247 , C01B2203/1288 , H01M8/04089 , H01M8/0618 , H01M8/12 , H01M2008/1293 , H01M2250/20 , H01M2250/407 , Y02E60/525 , Y02E60/563 , Y02T90/32
摘要： The invention relates to an auxiliary power unit (APU) for electricity generation in combination with an internal combustion engine having an outlet for engine exhaust gas, the APU comprising 1) a solid oxide fuel cell (SOFC, 9) comprising an inlet (6b) for fuel, an inlet for air and/or engine exhaust gas, and an outlet for off-gas, and 2) a catalytic partial oxidation reformer (CPOx, 5) having an outlet (6a) which is connected to the inlet (6b) for fuel of the SOFC (9) and an inlet (4b) for reactants, characterized in that the inlet for reactants (4b) is connected to the outlet for engine exhaust gas of the internal combustion engine through an evaporator (3) having an inlet (1) for fuel and an inlet (2) for engine exhaust gas and an outlet (4a) which is connected to the inlet (4b) of the CPOx. The invention further relates to a process for the generation of electricity from a hydrocarbonaceous fuel using such an APU.
摘要翻译：本发明涉及一种用于发电的辅助动力单元（APU），其具有用于发动机排气出口的内燃机，该APU包括1）包括入口（6b）的固体氧化物燃料电池（SOFC，9）用于燃料，用于空气和/或发动机废气的入口和用于废气的出口;以及2）具有连接到入口（6b）的出口（6a）的催化部分氧化重整器（CPOx，5）用于SOFC（9）的燃料和用于反应物的入口（4b），其特征在于反应物（4b）的入口通过具有入口（3）的蒸发器（3）连接到内燃机的发动机废气出口（1）和用于发动机排气的入口（2）和连接到CPOx的入口（4b）的出口（4a）。本发明还涉及使用这种APU从含烃燃料产生电的方法。

5. 发明专利

AR122768A1 PROCESO DE DESHIDROGENACIÓN OXIDATIVA DE ETANOS 未知
公开(公告)号：AR122768A1
公开(公告)日：2022-10-05
申请号：ARP210101784
申请日：2021-06-28
申请人： SHELL INT RESEARCH
发明人： SCHOONEBEEK RONALD JAN , VAN ROSSUM GUUS , BOS ALOUISIUS NICOLAAS RENE , ESPOSITO CASSIBBA IVANA DANIELA , CHRISTIANSEN MATTHEW ADAM
IPC分类号： C07C11/04 , B01J23/00 , B01J23/28 , B01J27/057 , B01J37/02 , B01J37/03 , C07C5/48
摘要： Reivindicación 1: Un proceso para la producción de etileno mediante la deshidrogenación oxidativa de etano, que comprende: a) suministrar etano y oxígeno a una primera zona de deshidrogenación oxidativa que está formada por múltiples tubos de reactor que contienen un lecho de catalizador que contiene un catalizador de deshidrogenación oxidativa que es un catalizador de óxido de metal mixto; b) poner en contacto el etano y el oxígeno con el catalizador en los múltiples tubos de reactor en la primera zona de deshidrogenación oxidativa lo que genera múltiples corrientes efluentes, en donde los múltiples tubos de reactor se enfrían con un refrigerante; c) mezclar al menos una porción de las múltiples corrientes efluentes de la etapa b) dando como resultado una mezcla que comprende etileno, etano sin convertir y oxígeno sin convertir; d) suministrar al menos una porción de la mezcla de la etapa c) a una segunda zona de deshidrogenación oxidativa que contiene un lecho de catalizador que contiene un catalizador de deshidrogenación oxidativa que es un catalizador de óxido de metal mixto; e) poner en contacto al menos una porción de la mezcla de la etapa c) con el catalizador en la segunda zona de deshidrogenación oxidativa dando como resultado una corriente que comprende etileno y etano sin convertir.

6. 发明专利

CA2953195C ALKANE OXIDATIVE DEHYDROGENATION AND/OR ALKENE OXIDATION 未知
公开(公告)号：CA2953195C
公开(公告)日：2022-08-30
申请号：CA2953195
申请日：2015-06-29
申请人： SHELL INT RESEARCH
发明人： BOS ALOUISIUS NICOLAAS RENEE , SCHOONEBEEK RONALD JAN , SPIES FRANK , VERHAAK MICHIEL JOHANNES FRANCISCUS MARIA
IPC分类号： C07C2/84 , B01J23/20 , B01J23/22 , B01J23/28 , B01J27/057 , C07C5/48 , C07C9/04 , C07C9/06 , C07C9/08 , C07C11/04 , C07C11/06
摘要： The invention relates to a process of the oxidative dehydrogenation of an alkane containing 2 to 6 carbon atoms and/or the oxidation of an alkene containing 2 to 6 carbon atoms, comprising contacting a first gas stream comprising oxygen and the alkane containing 2 to 6 carbon atoms and/or the alkene containing 2 to 6 carbon atoms with a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium; followed by contacting a second gas stream comprising methane, an inert gas or oxygen or any combination of two or more of these with the catalyst, wherein the second gas stream comprises 0 to 25 vol.% of the alkane containing 2 to 6 carbon atoms and/or alkene containing 2 to 6 carbon atoms.

7. 发明专利

PE20212191A1 DESHIDROGENACION OXIDATIVA DE ALCANOS Y/U OXIDACION DE ALQUENOS 未知
公开(公告)号：PE20212191A1
公开(公告)日：2021-11-15
申请号：PE2021000841
申请日：2019-12-06
申请人： SHELL INT RESEARCH
发明人： SCHOONEBEEK RONALD JAN , VAN ROSSUM GUUS
IPC分类号： C07C5/48 , C07C11/04 , C07C11/06 , C07C51/215 , C07C51/25
摘要： Se refiere a un proceso de la deshidrogenacion oxidativa de un alcano que contiene de 2 a 6 atomos de carbono y/o la oxidacion de un alqueno que contiene de 2 a 6 atomos de carbono, en donde el alcano y/o el alqueno se ponen en contacto con el oxigeno en presencia de un catalizador que comprende un oxido de metal mixto y uno o mas diluyentes que se seleccionan del grupo que consiste en dioxido de carbono, monoxido de carbono y vapor, y en donde la conversion del alcano y/o el alqueno es al menos del 40 %.

8. 发明专利

CA2928898C ALKANE OXIDATIVE DEHYDROGENATION AND/OR ALKENE OXIDATION 未知
公开(公告)号：CA2928898C
公开(公告)日：2020-10-20
申请号：CA2928898
申请日：2014-12-04
申请人： SHELL INT RESEARCH
发明人： BOS ALOUISIUS NICOLAAS RENEE , SCHOONEBEEK RONALD JAN , VERHAAK MICHIEL JOHANNES FRANCISCUS MARIA
IPC分类号： C07C5/48 , C07C11/04 , C07C11/06 , C07C51/25 , C07C53/08 , C07C57/04
摘要： The invention relates to a process of the oxidative dehydrogenation of an alkane containing 2 to 6 carbon atoms and/or the oxidation of an alkene containing 2 to 6 carbon atoms, wherein a gas stream comprising oxygen and the alkane and/or alkene is contacted with a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium, and wherein the linear velocity of said gas stream is at least 10 cm/sec.

9. 发明专利

CA2928795C ALKANE OXIDATIVE DEHYDROGENATION AND/OR ALKENE OXIDATION 未知
公开(公告)号：CA2928795C
公开(公告)日：2020-10-20
申请号：CA2928795
申请日：2014-12-04
申请人： SHELL INT RESEARCH
发明人： BOS ALOUISIUS NICOLAAS RENEE , SCHOONEBEEK RONALD JAN , SPIES FRANK , VERHAAK MICHIEL JOHANNES FRANCISCUS MARIA
IPC分类号： C07C5/48 , C07C11/04 , C07C11/06 , C07C51/25 , C07C53/08 , C07C57/04
摘要： The invention relates to a process of the oxidative dehydrogenation of an alkane containing 2 to 6 carbon atoms and/or the oxidation of an alkene containing 2 to 6 carbon atoms, wherein a gas stream comprising oxygen and the alkane and/or alkene is contacted with a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium, and wherein the weight hourly space velocity is of from 2.1 to 25.0 hr-1 and the temperature is of from 300 to 500 °C.

10. 发明专利

RU2725646C2 ОКИСЛИТЕЛЬНОЕ ДЕГИДРИРОВАНИЕ ЭТАНА И ИЗВЛЕЧЕНИЕ УКСУСНОЙ КИСЛОТЫ 未知
公开(公告)号：RU2725646C2
公开(公告)日：2020-07-03
申请号：RU2018114471
申请日：2016-10-25
申请人： SHELL INT RESEARCH
发明人： MITKIDIS GEORGIOS , SAN ROMAN MACIA MARIA , ROSSUM VAN GUUS , SCHOONEBEEK RONALD JAN
IPC分类号： C07C5/48 , C07C7/04 , C07C7/11 , C07C9/06 , C07C11/04 , C07C51/215 , C07C51/48 , C07C53/08
摘要： Изобретениеотноситсяк усовершенствованномуспособуокислительногодегидрированияэтана. Способокислительногодегидрированияэтанавключаетстадии, вкоторыхподаютгазовыйпоток, содержащийэтани пропан, вперегоннуюколоннудляполученияпотока, содержащегопропан, ипотока, содержащегоэтан; подаютпоменьшеймеречастьгазовогопотока, содержащегоэтан, полученногонастадии (a), вреактор; вреактореприводяткислороди этани необязательноэтиленв контактс катализатором, содержащимсмешанныйоксидметаллов; охлаждаютвыходящийизреакторапотоки одновременнои/илинаследующейстадиидобавляютводук выходящемуизреакторапотокудляполученияжидкогопотока, содержащеговодуи уксуснуюкислоту, игазовогопотока, содержащегоэтилен; извлекаютуксунуюкислотуизжидкогопотока, полученногонастадии (d), спомощьюэкстракциирастворителем; причемпоменьшеймере 50% мас. смешанногооксидаметалловв катализаторе, используемомнастадии (c), находитсяв орторомбическойкристаллическойфазе M1; иприэтомсмешанныйоксидметалловв катализаторе, используемомнастадии (c), содержит: молибден, ванадийи сурьмуилимолибден, ванадий, ниобийи необязательнотеллурилисурьму. Цельюявляетсядостижениеотносительновысокойактивностии/илиотносительновысокойселективностипревращенияэтанав этилен. Другойцельюявляетсяполучениеотносительночистогоэтилена. Дополнительнойцельюявляетсяизвлечениеотносительночистойуксуснойкислоты. 14 з.п. ф-лы, 5 пр.

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