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1. 发明申请

WO2012083258A3 ELECTROCHEMICAL SENSORS 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2012083258A3
公开(公告)日：2013-01-10
申请号：PCT/US2011065652
申请日：2011-12-16
申请人： SENSOR INNOVATIONS INC , KAHN CAROLYN R , WONG ELICIA , WILKINS JAMES A , MANSOUR DEAN , NORVIEL VERN , SIDHU ROBBIE SINGH
发明人： KAHN CAROLYN R , WONG ELICIA , WILKINS JAMES A , MANSOUR DEAN , NORVIEL VERN , SIDHU ROBBIE SINGH
IPC分类号： G01N27/30 , G01N33/00
CPC分类号： G01N27/302 , G01N27/3335 , G01N27/4167 , Y10T428/24421
摘要： Systems and methods are provided for detecting the presence of an analyte in a sample. A solid state electrochemical sensor can include a redox active moiety having an oxidation and/or reduction potential that is sensitive to the presence of an analyte immobilized over a surface of a working electrode. A redox active moiety having an oxidation and/or reduction potential that is insensitive to the presence of the analyte can be used for reference. Voltammetric measurements made using such systems can accurately determine the presence and/or concentration of the analyte in the sample. The solid state electrochemical sensor can be robust and not require calibration or re-calibration.
摘要翻译：提供了用于检测样品中分析物的存在的系统和方法。固态电化学传感器可以包括具有氧化和/或还原电位的氧化还原活性部分，其对固定在工作电极的表面上的分析物的存在敏感。具有对分析物的存在不敏感的氧化还原电位的氧化还原活性部分可以用作参考。使用这种系统进行的伏安测量可以准确地确定样品中分析物的存在和/或浓度。固态电化学传感器可以是鲁棒的，不需要校准或重新校准。

2. 发明专利

GB2450002B Semiconductor electrochemical sensors 未知
公开(公告)号：GB2450002B
公开(公告)日：2009-04-15
申请号：GB0810556
申请日：2008-06-09
申请人： SENSOR INNOVATIONS INC
发明人： KAHN CAROLYN R , WONG ELICIA , NORVIEL VERN
IPC分类号： G01N27/333 , G01N27/49 , G01N33/00
摘要： Described herein are substrates, sensors and systems related to measuring the concentration of an analyte such as hydrogen ion in a sample. Redox active moieties whose reduction and/or oxidation potentials are sensitive to the presence of an analyte are immobilized onto a surface of an electrode. Immobilized redox active moieties whose reduction and/or oxidation potential are insensitive to the analyte can be used for reference. Voltammetric measurements made using such modified surfaces can accurately determine the presence and/or concentrations of analytes in a sample of interest. The electrochemical sensors of the invention are robust and can be made so as not to require calibration or re-calibration.

3. 发明专利

GB2451596A Semiconductor electrochemical sensors 未知
公开(公告)号：GB2451596A
公开(公告)日：2009-02-04
申请号：GB0820528
申请日：2008-06-09
申请人： SENSOR INNOVATIONS INC
发明人： KAHN CAROLYN R , WONG ELICIA , NORVIEL VERN
IPC分类号： G01N27/30 , G01N33/00 , H01L29/40
摘要： Described herein are substrates, sensors and systems related to measuring the concentration of an analyte such as hydrogen ion (i.e. pH) in a sample. Redox active moieties whose reduction and/or oxidation potentials are sensitive to the presence of an analyte are immobilized onto a doped semiconductor surface. Examples of such redox-active moieties include anthracenes, quinines, anthroquinones, phenanthroquinones. phenyl diamines. catechols, phenothiazinium dyes, monoquaternized N-alkyl-4,4'-bipyridium, RuOx or Ni(OH)2. Immobilized redox active moieties whose reduction and/or oxidation potential are insensitive to the analyte can be used for reference (for example ferrocene, polyvinylferrocene, viologen, polyviologen or polythiophene). Voltammetric measurements made using such modified semiconductor surfaces can accurately determine the presence and/or concentrations of analytes in a sample of interest. The described semiconductor electrochemical sensors are robust and can be made so as not to require calibration or re-calibration.

4. 发明专利

GB2451596B Semiconductor electrochemical sensors 未知
公开(公告)号：GB2451596B
公开(公告)日：2009-09-23
申请号：GB0820528
申请日：2008-06-09
申请人： SENSOR INNOVATIONS INC
发明人： KAHN CAROLYN R , WONG ELICIA , NORVIEL VERN
IPC分类号： G01N27/333 , G01N27/49 , G01N33/00
摘要： Described herein are substrates, sensors and systems related to measuring the concentration of an analyte such as hydrogen ion in a sample. Redox active moieties whose reduction and/or oxidation potentials are sensitive to the presence of an analyte are immobilized onto a surface of an electrode. Immobilized redox active moieties whose reduction and/or oxidation potential are insensitive to the analyte can be used for reference. Voltammetric measurements made using such modified surfaces can accurately determine the presence and/or concentrations of analytes in a sample of interest. The electrochemical sensors of the invention are robust and can be made so as not to require calibration or re-calibration.

5. 发明专利

GB2500550A Electrochemical sensors 未知
公开(公告)号：GB2500550A
公开(公告)日：2013-09-25
申请号：GB201312655
申请日：2011-12-16
申请人： SENSOR INNOVATIONS INC
发明人： KAHN CAROLYN R , WONG ELICIA , WILKINS JAMES A , MANSOUR DEAN , NORVIEL VERN , SIDHU ROBBIE SINGH
IPC分类号： G01N27/416 , G01N27/333
摘要： Systems and methods are provided for detecting the presence of an analyte in a sample. A solid state electrochemical sensor can include a redox active moiety having an oxidation and/or reduction potential that is sensitive to the presence of an analyte immobilized over a surface of a working electrode. A redox active moiety having an oxidation and/or reduction potential that is insensitive to the presence of the analyte can be used for reference. Voltammetric measurements made using such systems can accurately determine the presence and/or concentration of the analyte in the sample. The solid state electrochemical sensor can be robust and not require calibration or re-calibration.

6. 发明专利

CA2687752A1 SEMICONDUCTOR ELECTROCHEMICAL SENSORS 未知
公开(公告)号：CA2687752A1
公开(公告)日：2008-12-18
申请号：CA2687752
申请日：2008-06-06
申请人： SENSOR INNOVATIONS INC
发明人： WONG ELICIA , NORVIEL VERN , KAHN CAROLYN R
IPC分类号： G01N27/403
摘要： Described herein are substrates, sensors and systems related to measuring the concentration of an analyte such as hydrogen ion in a sample. Redox act ive moieties whose reduction and/or oxidation potentials are sensitive to th e presence of an analyte are immobilized onto a semiconductor surface. Immob ilized redox active moieties whose reduction and/or oxidation potential are insensitive to the analyte can be used for reference. Voltammetric measureme nts made using such modified semiconductor surfaces can accurately determine the presence and/or concentrations of analytes in a sample of interest. The semiconductor electrochemical sensors of the invention are robust and can b e made so as not to require calibration or re-calibration.

7. 发明专利

GB2450002A Semiconductor electrochemical sensors 未知
公开(公告)号：GB2450002A
公开(公告)日：2008-12-10
申请号：GB0810556
申请日：2008-06-09
申请人： SENSOR INNOVATIONS INC
发明人： KAHN CAROLYN R , WONG ELICIA , NORVIEL VERN
IPC分类号： G01N27/30 , G01N33/00
摘要： Described herein are substrates, sensors and systems related to measuring the concentration of an analyte such as hydrogen ion in a sample for determining the samples pH. Redox active moieties whose reduction and/or oxidation potentials are sensitive to the presence of an analyte (such as H ion) are immobilized onto a semiconductor surface. Immobilized redox active moieties whose reduction and/or oxidation potential are insensitive to the analyte can also be used for reference or can be used to detect a second analyte (such as ammonia, oxygen or carbon dioxide). Voltammetric measurements made using such modified semiconductor surfaces can accurately determine the presence and/or concentrations of analytes in a sample of interest. The semiconductor electrochemical sensors of the invention are accurate and robust and can be made so as not to require calibration or re-calibration. Figure 5 shows one embodiment wherein a silicon semiconducting electrode is modified with ferrocene moieties, vinyl-ferrocene (VFc) and ferrocene carboxaldehyde (FcA) by covalent attachment. A method of forming the derivatized semiconductor surface is also disclosed. Further embodiments relate to voltammetric measuring of a pH value in a waste or water treatment process or from a biopharmaceutical process.

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