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    • 1. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JP2000294637A
    • 2000-10-20
    • JP10203099
    • 1999-04-09
    • SEIKO EPSON CORP
    • IWAMURA NAOYUKI
    • H01L21/302G03F7/40H01L21/3065H01L21/768
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a semiconductor device by which a semiconductor device having a plug can be manufactured and a liquid chemical which is used for removing such a matter as the polymer, etc., adhering to the side wall surface of a metallic wiring layer can be prevented from entering a recess around the plug and dissolving the wiring layer. SOLUTION: A plug 32 is formed in the opening of an insulating film 12 upon which a barrier metallic layer 14 is stacked. Then a metallic wiring layer 18 and a metallic wiring layer protective film 24 composed of silicon dioxide, etc., are successively stacked upon the wiring layer 18. After the protective film 24 is formed, a photoresist is applied to the film 24. Then the protective film 18 and wiring layer 18 are dry-etched and, successively, the polymer, etc., which adhere to the protective film 24 and wiring layer 18 at the dry etching is removed with an amine-based alkaline solution, etc. Finally, the barrier metallic layer 14 is dry-etched by using the protective film 24 as a mask.
    • 4. 发明专利
    • PLASMA REACTOR
    • JP2000100795A
    • 2000-04-07
    • JP27212498
    • 1998-09-25
    • SEIKO EPSON CORP
    • IWAMURA NAOYUKI
    • H01L21/302C23C16/50C23C16/505C23F4/00H01L21/205H01L21/3065H01L21/31H05H1/00H05H1/46
    • PROBLEM TO BE SOLVED: To detect partial abnormal discharges or a short spell of abnormal discharge, by installing a detector for detecting voltage or currents in a transmission line for supplying high-frequency power, and monitoring the third higher harmonic compounds and the fifth higher harmonic compounds. SOLUTION: Since impedance matching between supply side and load side is not taken at abnormal discharge, waves which are opposite in phase are produced, and odd higher harmonics increase. So, when introducing a gas between an upper electrode 1 and a lower electrode and applying higher harmonics by a higher harmonic power source 3 so as to etch a wafer 5, this reactor monitors third higher harmonic components and fifth higher harmonic components of applied high frequency with a detector 4, and when this compound becomes higher than the reference value, it is detected as abnormal discharges. This reactor can detect partial abnormal discharge or a short spell of abnormal discharge by detecting the abnormal discharge from the intensity of the third higher harmonic components and fifth higher harmonic compounds of the applied high frequency.