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1. 发明公开

EP3030635A4 CONVERSION OF ALKANES TO ORGANOSELENIUMS AND ORGANOTELLURIUMS 失效
标题翻译：转化有机硅和有机物中的烷烃
公开(公告)号：EP3030635A4
公开(公告)日：2016-07-27
申请号：EP14833997
申请日：2014-08-06
申请人： SCRIPPS RESEARCH INST , PERIANA ROY A , KONNICK MICHAEL M , HASHIGUCHI BRIAN G
发明人： PERIANA ROY A , KONNICK MICHAEL M , HASHIGUCHI BRIAN G
IPC分类号： C07C391/00 , C07C1/32 , C07C11/02 , C07C17/093 , C07C319/02 , C07C319/14 , C07C321/04 , C07C321/14 , C07C395/00
CPC分类号： C07C395/00 , C07B39/00 , C07B41/06 , C07B43/04 , C07B45/00 , C07B47/00 , C07C1/321 , C07C17/093 , C07C45/00 , C07C209/22 , C07C231/10 , C07C319/02 , C07C319/14 , C07C391/00 , C07F7/2208 , C07F9/5004 , C07C321/04 , C07C321/14 , C07C11/02
摘要： The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.

2. 发明专利

AU2014306055B2 Conversion of alkanes to organoseleniums and organotelluriums 未知
公开(公告)号：AU2014306055B2
公开(公告)日：2018-03-08
申请号：AU2014306055
申请日：2014-08-06
申请人： HASHIGUCHI BRIAN G , KONNICK MICHAEL M , PERIANA ROY A , SCRIPPS RESEARCH INST
发明人： PERIANA ROY A , KONNICK MICHAEL M , HASHIGUCHI BRIAN G
IPC分类号： C07B47/00 , C10L1/24
摘要： The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.

3. 发明申请

WO2014130987A8 OXIDATION OF ALKANES TO ALCOHOLS 审中-公开
标题翻译：烷烃氧化成酒精
公开(公告)号：WO2014130987A8
公开(公告)日：2015-09-24
申请号：PCT/US2014018175
申请日：2014-02-25
申请人： SCRIPPS RESEARCH INST
发明人： PERIANA ROY , HASHIGUCHI BRIAN G , KONNICK MICHAEL M , BISCHOF STEVEN M
IPC分类号： C07C9/02 , C07C27/10 , C07C29/50
CPC分类号： C07C67/035 , C07C69/63
摘要： The invention provides processes and materials for the efficient and cost- effective functionalization of alkanes, such as methane from natural gas, to provide esters, alcohols, and other compounds. The method can be used to produce liquid fuels such as methanol from a natural gas methane-containing feedstock. The soft oxidizing electrophile, a compound of a main group, post- transitional element such as Tl, Pb, Bi, and I, that reacts to activate the alkane C- H bond can be regenerated using inexpensive regenerants such as hydrogen peroxide, oxygen, halogens, nitric acid, etc. Main group compounds useful for carrying out this reaction includes haloacetate salts of metals having a pair of available oxidation states, such as Tl, Pb, Bi, and I. The inventors herein believe that a unifying feature of many of the MXn electrophiles useful in carrying out this reaction, such as Tl, Pb, and Bi species, is their isoelectronic configuration in the alkane -reactive oxidation state; the electrons having the configuation [Xe]4f145d10, with an empty 6s orbital. However, the iodine reagents have a different electronic configuration.
摘要翻译：本发明提供了用于有效和成本有效地官能化烷烃（例如天然气的甲烷）的方法和材料，以提供酯，醇和其它化合物。该方法可用于从含天然气甲烷的原料中生产液体燃料如甲醇。可以使用廉价的再生剂例如过氧化氢，氧气，氧气，氢氧化钠等，再生使用软氧化亲电体，即主要化合物，后处理元素如Tl，Pb，Bi和I，卤素，硝酸等。可用于进行该反应的主要化合物包括具有一对可用氧化态的金属的卤代乙酸盐，例如Tl，Pb，Bi和I.本发明人认为，许多的用于进行这种反应的MXn亲电子试剂，如Tl，Pb和Bi物质，是它们在烷烃反应氧化态下的等电子构型; 具有配置[Xe] 4f145d10的电子，具有空的6s轨道。然而，碘试剂具有不同的电子结构。

4. 发明公开

EP2958878A4 OXIDATION OF ALKANES TO ALCOHOLS 有权
标题翻译：烷烃转化成醇的氧化
公开(公告)号：EP2958878A4
公开(公告)日：2016-03-23
申请号：EP14753994
申请日：2014-02-25
申请人： SCRIPPS RESEARCH INST
发明人： PERIANA ROY , HASHIGUCHI BRIAN G , KONNICK MICHAEL M , BISCHOF STEVEN M
IPC分类号： C07C9/02 , C07C27/10 , C07C29/50
CPC分类号： C07C67/035 , C07C69/63
摘要： The invention provides processes and materials for the efficient and cost-effective functionalization of alkanes, such as methane from natural gas, to provide esters, alcohols, and other compounds. The method can be used to produce liquid fuels such as methanol from a natural gas methane-containing feedstock. The soft oxidizing electrophile, a compound of a main group, post-transitional element such as Tl, Pb, Bi, and I, that reacts to activate the alkane C—H bond can be regenerated using inexpensive regenerants such as hydrogen peroxide, oxygen, halogens, nitric acid, etc. Main group compounds useful for carrying out this reaction includes haloacetate salts of metals having a pair of available oxidation states, such as Tl, Pb, Bi, and I. The inventors herein believe that a unifying feature of many of the MXn electrophiles useful in carrying out this reaction, such as Tl, Pb, and Bi species, is their isoelectronic configuration in the alkane-reactive oxidation state; the electrons having the configuration [Xe]4f145d10, with an empty 6s orbital. However, the iodine reagents have a different electronic configuration.

5. 发明专利

AU2018272065A1 Direct oxidation of olefins to oxygenated species 未知
公开(公告)号：AU2018272065A1
公开(公告)日：2020-01-16
申请号：AU2018272065
申请日：2018-05-25
申请人： HYCONIX INC , SCRIPPS RESEARCH INST
发明人： PERIANA ROY A , HASHIGUCHI BRIAN G , KONNICK MICHAEL M
IPC分类号： C07C5/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46
摘要： Provided is a process for oxidizing an alkene. The process comprises contacting an alkene, and either an oxidizing electrophile comprising a main group element in oxidized form or an oxidant and a reduced form of the oxidizing electrophile, in a liquid medium comprising an oxygen acid and optionally one or more additives selected from a non-oxidizable liquid, a salt additive, a Lewis acid, and water, to provide an oxygenate and a reduced form of the oxidizing electrophile. The process optionally further comprises separating the oxygenate and the reduced form of the oxidizing electrophile. The oxygenate can be further hydrolyzed to form an alcohol, diol, or polyol.

6. 发明专利

AU2018272065B2 Direct oxidation of olefins to oxygenated species 未知
公开(公告)号：AU2018272065B2
公开(公告)日：2020-08-13
申请号：AU2018272065
申请日：2018-05-25
申请人： HYCONIX INC , SCRIPPS RESEARCH INST
发明人： PERIANA ROY A , HASHIGUCHI BRIAN G , KONNICK MICHAEL M
IPC分类号： C07C5/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46
摘要： Provided is a process for oxidizing an alkene. The process comprises contacting an alkene, and either an oxidizing electrophile comprising a main group element in oxidized form or an oxidant and a reduced form of the oxidizing electrophile, in a liquid medium comprising an oxygen acid and optionally one or more additives selected from a non-oxidizable liquid, a salt additive, a Lewis acid, and water, to provide an oxygenate and a reduced form of the oxidizing electrophile. The process optionally further comprises separating the oxygenate and the reduced form of the oxidizing electrophile. The oxygenate can be further hydrolyzed to form an alcohol, diol, or polyol.

7. 发明专利

AU2018272055A1 Oxidizing liquid media for chemical transformations 未知
公开(公告)号：AU2018272055A1
公开(公告)日：2020-01-16
申请号：AU2018272055
申请日：2018-05-25
申请人： HYCONIX INC , SCRIPPS RESEARCH INST
发明人： PERIANA ROY A , HASHIGUCHI BRIAN G , KONNICK MICHAEL M
IPC分类号： C07C5/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46
摘要： Provided is an oxidizing composition, in which a liquid medium is substantially inert in the presence of an oxidizing electrophile contained in the liquid medium. The composition comprises (a) an oxidizing electrophile comprising a main group element in oxidized form and at least one conjugate anion of an oxygen acid; (b) a non-oxidizable liquid selected from a fluorinated hydrocarbon, a sulfone, a deactivated arene, a deactivated aliphatic, a deactivated heteroarene, a deactivated heteroaliphatic, and a combination thereof; and (c) optionally one or more salt additives. Further provided are a method of using the oxidizing composition to oxidize a substrate and a method of generating and/or regenerating an oxidizing electrophile comprising a main group element.

8. 发明专利

EA032269B1 ПРЕВРАЩЕНИЕ АЛКАНОВ В СЕЛЕНООРГАНИЧЕСКИЕ И ТЕЛЛУРООРГАНИЧЕСКИЕ СОЕДИНЕНИЯ 未知
公开(公告)号：EA032269B1
公开(公告)日：2019-05-31
申请号：EA201690344
申请日：2014-08-06
申请人： SCRIPPS RESEARCH INST
发明人： PERIANA ROY A , KONNICK MICHAEL M , HASHIGUCHI BRIAN G
IPC分类号： C10L1/24
摘要： Настоящееизобретениепредлагаетспособыи материалыдляэффективнойи экономичнойфункционализацииалканови гетероалканов, котораяможетосуществлятьсяпритемпературе, составляющейменеечем 300°C, ивключаетвведениев контакталканаилигетероалкана, содержащегопоменьшеймереодин sp-гибридизованныйатомуглерода, несущийпоменьшеймереодинатомводорода, имягкогоэлектрофильногоокислителя, содержащего Se (VI) илиТе (VI), вкислойсреде, необязательнодополнительновключающейапротоннуюсреду, споследующимотделениемсоответствующегоалкилселеновогоилиалкилтеллуровогопродукта. Выделениепромежуточногоалкилселеновогоилиалкилтеллуровогосоединенияпозволяетосуществитьегопоследующиепревращениев продукты, необязательносовместимыес начальнымиусловиямиреакции, такиекакамины, станнаны, сероорганическиесоединения, ацильныесоединения, галогенуглеродныесоединенияи олефины.

9. 发明专利

CA3064326A1 OXIDIZING LIQUID MEDIA FOR CHEMICAL TRANSFORMATIONS 未知
公开(公告)号：CA3064326A1
公开(公告)日：2018-11-29
申请号：CA3064326
申请日：2018-05-25
申请人： SCRIPPS RESEARCH INST , HYCONIX INC
发明人： PERIANA ROY A , HASHIGUCHI BRIAN G , KONNICK MICHAEL M
IPC分类号： C07B33/00 , C07B41/00
摘要： Provided is an oxidizing composition, in which a liquid medium is substantially inert in the presence of an oxidizing electrophile contained in the liquid medium. The composition comprises (a) an oxidizing electrophile comprising a main group element in oxidized form and at least one conjugate anion of an oxygen acid; (b) a non-oxidizable liquid selected from a fluorinated hydrocarbon, a sulfone, a deactivated arene, a deactivated aliphatic, a deactivated heteroarene, a deactivated heteroaliphatic, and a combination thereof; and (c) optionally one or more salt additives. Further provided are a method of using the oxidizing composition to oxidize a substrate and a method of generating and/or regenerating an oxidizing electrophile comprising a main group element.

10. 发明专利

CA2902326C DIRECT, SELECTIVE PROCESSES FOR OXIDATION OF NATURAL GAS ALKANES TO ALCOHOLS 未知
公开(公告)号：CA2902326C
公开(公告)日：2021-07-27
申请号：CA2902326
申请日：2014-02-25
申请人： SCRIPPS RESEARCH INST
发明人： BISCHOF STEVEN M , PERIANA ROY A , HASHIGUCHI BRIAN G , KONNICK MICHAEL M
IPC分类号： C07C27/10 , C07C29/48
摘要： The invention provides processes and materials for the efficient and cost- effective functionalization of alkanes, such as methane from natural gas, to provide esters, alcohols, and other compounds. The method can be used to produce liquid fuels such as methanol from a natural gas methane-containing feedstock. The soft oxidizing electrophile, a compound of a main group, post- transitional element such as Tl, Pb, Bi, and I, that reacts to activate the alkane C- H bond can be regenerated using inexpensive regenerants such as hydrogen peroxide, oxygen, halogens, nitric acid, etc. Main group compounds useful for carrying out this reaction includes haloacetate salts of metals having a pair of available oxidation states, such as Tl, Pb, Bi, and I. The inventors herein believe that a unifying feature of many of the MXn electrophiles useful in carrying out this reaction, such as Tl, Pb, and Bi species, is their isoelectronic configuration in the alkane -reactive oxidation state; the electrons having the configuation [Xe]4f145d10, with an empty 6s orbital. However, the iodine reagents have a different electronic configuration.

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