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    • 4. 发明申请
    • WETTABILITY AND MATRIX IMBIBITION ANALYSIS
    • 湿度和矩阵影响分析
    • WO2012087902A3
    • 2012-08-09
    • PCT/US2011065776
    • 2011-12-19
    • SCHLUMBERGER CA LTDSCHLUMBERGER SERVICES PETROLSCHLUMBERGER HOLDINGSSCHLUMBERGER TECHNOLOGY BVPRAD RES & DEV LTDWILLBERG DEANPAGELS MARKUSHINKEL JERALD J
    • WILLBERG DEANPAGELS MARKUSHINKEL JERALD J
    • G01N13/00G01N1/30G01N33/24
    • G01N13/00G01N1/286
    • A method of determining wettability of a rock sample, such as from a core sample is described. The sample is preferably crushed or comminuted to a particulate size where micro fractures have been eliminated, but where the particles are still large enough to represent the native rock matrix and texture. The comminuted core sample is exposed to a test fluid for a given period of time. The rock sample can be split into many separate aliquots, and a series of tests is performed using a series of different fluids and/or the same fluid for different exposure times. The excess test fluid residing on the surfaces of sample particles is removed. The test fluid imbibed into the interior of the particulate sample is then measured. The test fluid can be, for example, water, a non-aqueous fluid, and/or a solution of miscible solvents. The technique used to measure the imbibed fluid depends on the solvent (imbibing fluid) being studied. In one example, this technique includes both gravimetric determination and quantitative chemical analysis. The detection of water can be via Karl Fischer titration.
    • 描述了一种确定岩样的润湿性的方法,例如来自核心样品。 样品优选被粉碎或粉碎成具有微裂纹的颗粒尺寸,其中颗粒仍然足够大以表示天然岩石基质和质地。 粉碎的芯样品暴露于测试流体一段给定的时间。 岩石样品可以分成许多单独的等分试样,并且使用一系列不同的流体和/或相同的流体进行不同曝光时间的一系列测试。 去除驻留在样品颗粒表面上的过量测试流体。 然后测量吸入颗粒样品内部的测试液。 测试流体可以是例如水,非水性流体和/或可混溶溶剂的溶液。 用于测量吸液的技术取决于正在研究的溶剂(吸液)。 在一个实例中,该技术包括重量测定和定量化学分析。 水的检测可以通过卡尔费休滴定。
    • 5. 发明申请
    • WELLBORE SERVICE FLUID AND METHODS OF USE
    • 井孔服务液和使用方法
    • WO2012024498A2
    • 2012-02-23
    • PCT/US2011048265
    • 2011-08-18
    • SCHLUMBERGER SERVICES PETROLSCHLUMBERGER CA LTDSCHLUMBERGER HOLDINGSSCHLUMBERGER TECHNOLOGY BVPRAD RES & DEV LTDWILLBERG DEAN
    • WILLBERG DEAN
    • E21B33/13C09K8/04E21B43/26
    • E21B43/26C09K8/665C09K8/76C09K8/882
    • A method is described to predict the composition of favorable bridging agents for a particular situation in which the solution thermodynamics of the chemicals used in the composition of the bridging material is carefully evaluated. Wellbore service fluids are also described that contain materials such as sodium bicarbonate, a material such as a salt containing water in a crystal structure, a material containing at least one boron-oxygen bond, or a non-polymer material having low solubility at low temperatures and high solubility at temperatures close to an expected long-term static bottom hole temperature. The material is provided in aqueous medium in sufficient concentration in the aqueous medium so as to act as a diverting agent during a hydraulic fracturing procedure using the fluid. The wellbore service fluid is pumped through the wellbore and the flow of the fluid is diverted using a plug that subsequently substantially dissolves due to changes in temperature and/or pressure.
    • 描述了一种方法来预测对于特定情况的有利桥接剂的组成,其中桥接材料的组成中使用的化学品的溶液热力学被仔细评估。 还描述了包含诸如碳酸氢钠的材料,诸如含有晶体结构中的水的盐,含有至少一个硼 - 氧键的材料或者在低温下具有低溶解度的非聚合物材料的材料的井筒服务流体 并且在接近预期的长期静态井底温度的温度下具有高溶解度。 该材料在含水介质中以足够的浓度提供在含水介质中,以便在使用该流体的水力压裂过程中用作分流剂。 井眼服务流体通过井筒泵送,并且使用随着温度和/或压力的变化而随后大体上溶解的塞的流体流动。