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1. 发明申请

WO2010106404A2 DERIVATISATION OF CARBON 审中-公开
标题翻译：碳的衍生物
公开(公告)号：WO2010106404A2
公开(公告)日：2010-09-23
申请号：PCT/IB2010/000293
申请日：2010-02-12
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED A British Virgin Islands Company , SCHLUMBERGER SEACO, INC. , ZOU, Fenglou , LAWRENCE, Nathan , JONES, Timothy
发明人： ZOU, Fenglou , LAWRENCE, Nathan , JONES, Timothy
IPC分类号： C01B31/02 , C01B31/04 , B82B3/00
CPC分类号： C07C201/12 , B82Y30/00 , B82Y40/00 , C01B32/156 , C01B32/174 , C01B32/194 , C01B32/20 , C01B32/21 , C01B32/28 , C01B32/354 , G01N27/308
摘要： A molecular species is covalently attached to elemental carbon by exposing the carbon to a reaction mixture containing a strong base and a compound of the formula (I) or (II) in which X denotes a covalently attached atom or group capable of forming an X - anion and each Z is a moiety comprising a plurality of atoms, but which does not have a hydrogen atom directly attached to the atom which itself is directly attached to the -CH 2 X or -CHX group. The carbon substrate may be graphite or carbon nanotubes.
摘要翻译：通过将碳暴露于含有强碱和式（I）或（II）的化合物的反应混合物中，分子物质共价连接到元素碳上，其中X表示共价连接的原子或能够形成X- 阴离子，每个Z是包含多个原子的部分，但不具有与本身直接连接到-CH 2 X或-CHX基团的原子直接相连的氢原子。碳衬底可以是石墨或碳纳米管。

2. 发明申请

WO2012017306A2 ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2012017306A2
公开(公告)日：2012-02-09
申请号：PCT/IB2011/001820
申请日：2011-08-04
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED (SHL) , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER (SPS) , PRAD RESEARCH AND DEVELOPMENT LIMITED A British Virgin Islands Company , SCHLUMBERGER SEACO, INC. , LAWRENCE, Nathan , MEREDITH, Andrew
发明人： LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/30
CPC分类号： G01N27/302 , G01N27/4167
摘要： An electrochemical sensor for measuring an analyte in a fluid, the electrochemical sensor having a first working electrode that includes a redox species sensitive to the analyte to be measured and a second working electrode made from a conducting substrate absent the redox species. The electrochemical sensor being capable of operation so that electrochemical effects of active contaminants in the fluid can be removed/attenuated from electrochemical signals produced by the reduction/oxidation of the redox species in the presence of the analyte.
摘要翻译：一种用于测量流体中的分析物的电化学传感器，所述电化学传感器具有第一工作电极，所述第一工作电极包括对待测量的分析物敏感的氧化还原物质，以及由不含氧化还原物质的导电基材制成的第二工作电极。电化学传感器能够进行操作，从而可以通过在分析物存在下由氧化还原物质的还原/氧化产生的电化学信号去除/减弱活性污染物在流体中的电化学效应。

3. 发明申请

WO2005066618A1 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2005066618A1
公开(公告)日：2005-07-21
申请号：PCT/GB2004/005397
申请日：2004-12-22
申请人： SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT N.V. , SCHLUMBERGER CANADA LIMITED , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER OILFIELD ASSISTANCE LIMITED , SCHLUMBERGER OVERSEAS S.A. , SCHLUMBERGER SEACO INC. , SCHLUMBERGER SURENCO S.A. , SERVICES PETROLIERS SCHLUMBERGER , JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
发明人： JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
IPC分类号： G01N27/416
CPC分类号： G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要： An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译：描述了一种电化学传感器，其具有对相同物质敏感的两个分子氧化还原系统，并且具有检测器以检测两个氧化还原体系的伏安图的相对位移。

4. 发明公开

EP2601518A2 ELECTROCHEMICAL SENSOR 审中-公开
标题翻译： ELEKTROCHEMISCHER传感器
公开(公告)号：EP2601518A2
公开(公告)日：2013-06-12
申请号：EP11814172.0
申请日：2011-08-04
申请人： Schlumberger Technology B.V. , Schlumberger Holdings Limited (SHL) , Services Petroliers Schlumberger (SPS) , Prad Research And Development Limited A British Virgin Islands Company
发明人： LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/30
CPC分类号： G01N27/302 , G01N27/4167
摘要： An electrochemical sensor for measuring an analyte in a fluid, the electrochemical sensor having a first working electrode that includes a redox species sensitive to the analyte to be measured and a second working electrode made from a conducting substrate absent the redox species. The electrochemical sensor being capable of operation so that electrochemical effects of active contaminants in the fluid can be removed/attenuated from electrochemical signals produced by the reduction/oxidation of the redox species in the presence of the analyte.
摘要翻译：一种用于测量流体中的分析物的电化学传感器，所述电化学传感器具有第一工作电极，所述第一工作电极包括对待测量的分析物敏感的氧化还原物质和由不含所述氧化还原物质的导电基底制成的第二工作电极。电化学传感器能够操作，使得流体中活性污染物的电化学效应可以通过在分析物存在下由氧化还原物质的还原/氧化产生的电化学信号去除/减弱。

5. 发明申请

WO2011064632A2 PREPARATION OF SETTING SLURRIES 审中-公开
标题翻译：准备条件的准备
公开(公告)号：WO2011064632A2
公开(公告)日：2011-06-03
申请号：PCT/IB2010/002658
申请日：2010-10-15
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , VIDICK, Benoit , HARTSHORNE, Robert, Seth , LAWRENCE, Nathan , JOHNSON, Carl , MONTEIRO, Glen , WOODROW, Jonathan
发明人： VIDICK, Benoit , HARTSHORNE, Robert, Seth , LAWRENCE, Nathan , JOHNSON, Carl , MONTEIRO, Glen , WOODROW, Jonathan
CPC分类号： E21B33/14 , C04B40/0032 , C09K8/467 , C04B28/02 , C04B40/0039 , C04B2103/22
摘要： When preparing a settable slurry such as a cement slurry for cementing an oil well, cement or other solid powder is mixed with water and a set retarder. In order to be able to run a convenient and rapid check on the concentration of retarder after dilution at the site of use, a tracer material is mixed with the retarder in known amount during manufacture. The tracer is chosen to enable its concentration to be determined analytically after dilution at the site of use, thereby providing a way to determine the concentration of set retarder after such dilution. The tracer may be a redox-active material and its concentration may be determined by voltammetry. Tracer may likewise be mixed with additives other than set retarder.
摘要翻译：在制备用于固井的水泥浆等可固化浆料时，将水泥或其它固体粉末与水和缓凝剂混合。为了能够在使用地点稀释后对缓凝剂的浓度进行方便快速的检查，在制造过程中将示踪剂材料与缓凝剂以已知量混合。选择示踪剂以使其浓度在使用位置稀释后分析测定，由此提供确定这种稀释后缓凝剂浓度的方法。示踪剂可以是氧化还原活性物质，其浓度可以通过伏安法测定。示踪剂也可以与除缓凝剂之外的添加剂混合。

6. 发明申请

WO2011070408A2 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2011070408A2
公开(公告)日：2011-06-16
申请号：PCT/IB2010/002641
申请日：2010-10-14
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , LAFITTE, Valerie , LAWRENCE, Nathan
发明人： LAFITTE, Valerie , LAWRENCE, Nathan
IPC分类号： G01N27/30 , G01N33/18 , E21B47/00
CPC分类号： G01N27/3335 , G01N33/18
摘要： An electrochemical sensor for the presence or concentration of an analyte has at least one electrode and at least one electrochemically active species able to undergo electrochemical reaction in response to electrical potential applied to the electrode, where the said reaction is modified by the presence of the analyte. This sensor has the novel characteristic that at least one said electrochemically active species is encapsulated within polymer particles. These particles are preferably formed from an amorphous polymer with a glass transition temperature above the temperature of the fluid to which the sensor is exposed. The encapsulating polymer protects the analyte species from degradation, but a small analyte such as a hydrogen or bisulfide ion can pass through the polymer and undergo reaction at the active species.
摘要翻译：用于分析物的存在或浓度的电化学传感器具有至少一个电极和至少一个电化学活性物质，其能够响应于施加到电极的电势而经历电化学反应，其中所述反应通过分析物的存在而被修饰。该传感器具有将至少一种所述电化学活性物质包封在聚合物颗粒内的新颖特征。这些颗粒优选由玻璃化转变温度高于传感器所暴露的流体的温度的无定形聚合物形成。封装聚合物保护分析物物质免于降解，但是小分析物例如氢或二硫化物离子可以通过聚合物并在活性物质上进行反应。

7. 发明申请

WO2012156875A2 ALTERING A COMPOSITION AT A LOCATION ACCESSED THROUGH AN ELONGATE CONDUIT 审中-公开
标题翻译：通过一个最近的连接在一个位置改变一个组成
公开(公告)号：WO2012156875A2
公开(公告)日：2012-11-22
申请号：PCT/IB2012/052334
申请日：2012-05-10
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC , HARTSHORNE, Robert Seth , MEREDITH, Andrew , LAWRENCE, Nathan
发明人： HARTSHORNE, Robert Seth , MEREDITH, Andrew , LAWRENCE, Nathan
CPC分类号： C09K8/58 , C09K8/685 , C09K8/805 , E21B41/00
摘要： A composition flowing along an elongate conduit to a location accessed by that conduit contains a precursor substance which, arriving at the location, is converted electrochemically to chemically reactive intermediate. This intermediate reacts with another constituent of the composition, thereby bringing about a change in the composition. The reactive intermediate may be a cross-linking agent for a polymeric constituent of the composition so that the electrochemical reaction and subsequent cross-linking increases the viscosity of the composition as it arrives at the location where it is required.
摘要翻译：沿着细长管道流动到由该管道接近的位置的组合物含有前体物质，其到达该位置时被电化学转化为化学反应中间体。该中间体与组合物的另一成分反应，从而导致组合物的变化。反应性中间体可以是用于组合物的聚合物组分的交联剂，使得当组合物到达需要的位置时，电化学反应和随后的交联增加了组合物的粘度。

8. 发明申请

WO2011073746A2 CALIBRATION OF ELECTROCHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器校准
公开(公告)号：WO2011073746A2
公开(公告)日：2011-06-23
申请号：PCT/IB2010/002747
申请日：2010-10-25
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , LAWRENCE, Nathan
发明人： LAWRENCE, Nathan
IPC分类号： G01N27/26 , G01N33/18 , G01V3/18 , E21B47/00
CPC分类号： G01N27/4163 , G01N27/308
摘要： This invention is concerned with electrochemical methods of analysing a fluid for an analyte. It utilises a sensor comprising electrodes and a mediator compound capable of undergoing a cycle of oxidation and reduction in response to varying potential applied to the electrodes, where the compound is also able to undergo a portion of the cycle through chemical reaction with the analyte. As is already known, the sensor is used in a method in which the sensor and the fluid are brought into contact sufficiently for the analyte to react chemically with the mediator, and in a voltammetry procedure, potential is applied to the electrodes while observing current flow with sufficient time for reaction between the mediator compound and the analyte, for thereby observing the concentration of the analyte. The novel characteristic of this invention is a step of calibrating the sensor by applying a rapidly changing potential to the electrodes and observing current flow, the change of this potential and observation of current being sufficiently fast to allow and observe electrochemical oxidation and reduction of the mediator taking place independently of the concentration of analyte, thereby observing the concentration of the mediator compound. The rapid change of potential maybe provided by pulse voltammetry or square wave voltammetry.
摘要翻译：本发明涉及分析用于分析物的流体的电化学方法。它利用包含电极和介质化合物的传感器，其能够响应于施加到电极的变化的电位而经历氧化和还原循环，其中化合物还能够经受与分析物的化学反应的一部分循环。如已知的那样，传感器用于传感器和流体被充分接触以使分析物与介体发生化学反应的方法中，并且在伏安程序中，电势被施加到电极，同时观察电流具有足够的时间用于介体化合物和分析物之间的反应，从而观察分析物的浓度。本发明的新颖特征是通过向电极施加快速变化的电位并观察电流，该电位的变化和电流的观察足够快以允许和观察电化学氧化和还原介体来校准传感器的步骤独立于分析物的浓度进行，从而观察介体化合物的浓度。电位的快速变化可以通过脉冲伏安法或方波伏安法来提供。

9. 发明申请

WO2010026456A3 ELECTRO-CHEMICAL SENSOR 审中-公开
公开(公告)号：WO2010026456A3
公开(公告)日：2010-03-11
申请号：PCT/IB2009/006637
申请日：2009-08-26
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER SEACO, INC. , ROBINSON, Kay , LAWRENCE, Nathan , MEREDITH, Andrew
发明人： ROBINSON, Kay , LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/26 , G01N27/74
摘要： The present invention provides an electrochemical sensor having a solid electrically conductive substrate and a compound immobilized thereon which has binding affinity for an analyte species to be detected and also displays electrochemical behaviour which is modified upon binding of that analyte species, so that binding of an analyte species can be detected by measuring electrochemical properties, such as by voltammetry. Desirably the immobilised compound contains both a first moiety with binding affinity for the analyte and a separate second moiety which is a redox system whose electrochemical oxidation/reduction properties become modified when the first moiety binds the analyte. The analyte binding moiety may be a diol or polyol and preferably is a sugar. The electrochemical sensor finds use in methods of analysing reservoir and process fluids, particularly at a subterranean location. The electrochemical sensor may be a component of a downhole tool, adapted for deployment downhole.

10. 发明申请

WO2008015435A1 AN EROSION AND WEAR RESISTANT SONOELECTROCHEMICAL PROBE 审中-公开
标题翻译：耐腐蚀和耐磨耗的电化学探针
公开(公告)号：WO2008015435A1
公开(公告)日：2008-02-07
申请号：PCT/GB2007/002933
申请日：2007-08-01
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT N.V. , HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
发明人： HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
IPC分类号： G01N27/30 , G01N27/38
CPC分类号： G01N27/308 , G01N27/26 , G01N27/38
摘要： The present invention provides methods and systems incorporating conducting diamond electrodes into a high power acoustic resonator. More specifically in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn.
摘要翻译：本发明提供了将导电金刚石电极结合到高功率声谐振器中的方法和系统。更具体地，在本发明的某些实施例中，金刚石电极可以集成到高功率声谐振器中，以提供鲁棒的感测装置，其可以提供对电极的声学清洁并且提高质量传输到金刚石电极的速率。金刚石电极可以用作工作电极，参考电极或对电极，或两个或多个这样的电极的组合。在某些方面，高功率声谐振器可以包括用于聚焦声能的声喇叭，并且金刚石电极可以与声喇叭耦合。

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