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1. 发明申请

WO2008023338A1 PRODUCTION OF ESTERS 审中-公开
标题翻译：产ESESs
公开(公告)号：WO2008023338A1
公开(公告)日：2008-02-28
申请号：PCT/IB2007/053354
申请日：2007-08-22
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED , FOSTER, Douglas Francis , VAN RENSBURG, Hendrik , TOOZE, Robert Paul
发明人： FOSTER, Douglas Francis , VAN RENSBURG, Hendrik , TOOZE, Robert Paul
IPC分类号： C07C67/38 , C07C69/24 , C07C69/28 , C07C69/30 , C07C69/34
CPC分类号： C07C67/38 , C07C69/34 , C07C69/24 , C07C69/30 , C07C69/28
摘要： This invention relates to a process for the hydroesterification of olefins in which a hydrocarbon stream containing olefins is reacted with CO and an alcohol in the presence of a catalyst to form a hydrocarbon stream containing esters, wherein the alcohol has more than one carbon atom. The hydroesterification reaction is typically carried out in the presence of a catalyst comprising cobalt and a nitrogen-containing additive such as pyridine and the olefins may be branched. The invention also relates to a process for preparing an alkoxylated ester suitable for use as a surfactant molecule in detergent formulations.
摘要翻译：本发明涉及烯烃的加氢酯化方法，其中含有烯烃的烃物流在催化剂存在下与CO和醇反应形成含有酯的烃物流，其中醇具有多于一个碳原子。加氢酯化反应通常在包含钴和含氮添加剂如吡啶的催化剂存在下进行，烯烃可以是支链的。本发明还涉及一种制备适合用作洗涤剂配方中的表面活性剂分子的烷氧基化酯的方法。

2. 发明申请

WO2013041997A1 PROCESS FOR PREPARING A COBALT - CONTAINING FISCHER TROPSCH CATALYST 审中-公开
标题翻译：制备钴 - 含有螯合催化剂的方法
公开(公告)号：WO2013041997A1
公开(公告)日：2013-03-28
申请号：PCT/IB2012/054493
申请日：2012-08-31
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED , VAN RENSBURG, Hendrik
发明人： VAN RENSBURG, Hendrik
IPC分类号： B01J23/75 , B01J37/08 , B01J37/18 , B01J21/12 , B01J37/02 , B01J37/14 , C10G2/332
CPC分类号： B01J23/8913 , B01J21/12 , B01J23/75 , B01J37/0205 , B01J37/0213 , B01J37/024 , B01J37/088 , B01J37/14 , B01J37/18 , C07C1/043 , C10G2/332
摘要： A process for preparing a cobalt-containing hydrocarbon synthesis catalyst includes calcining an initial catalyst precursor comprising a catalyst support supporting a cobalt compound, by heat treating the initial catalyst precursor under non-reducing conditions in order to decompose the cobalt compound and/or to cause the cobalt compound to react with oxygen, thereby to obtain a calcined initial catalyst precursor. A cobalt compound is introduced onto and/or into the calcined initial catalyst precursor so that the calcined initial catalyst precursor supports this cobalt compound thereby obtaining a subsequent catalyst precursor. The subsequent catalyst precursor is directly subjected to reduction conditions to activate the subsequent catalyst precursor, thereby to obtain a cobalt-containing hydrocarbon synthesis catalyst.
摘要翻译：一种制备含钴烃合成催化剂的方法包括通过在非还原条件下热处理初始催化剂前体以煅烧含有钴化合物的催化剂载体的初始催化剂前体，以分解钴化合物和/或引起钴化合物与氧反应，从而获得煅烧的初始催化剂前体。将钴化合物引入煅烧的初始催化剂前体和/或进入煅烧的初始催化剂前体，使得煅烧的初始催化剂前体支持该钴化合物，从而获得随后的催化剂前体。随后的催化剂前体直接进行还原条件以活化随后的催化剂前体，从而获得含钴烃合成催化剂。

3. 发明申请

WO2003068719A3 PRODUCTION OF OXYGENATED PRODUCTS 审中-公开
公开(公告)号：WO2003068719A3
公开(公告)日：2003-08-21
申请号：PCT/IB2003/000472
申请日：2003-02-13
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED , STEYNBERG, Petrus, Johannes , VAN RENSBURG, Hendrik , GROVÉ, Jacobus, Johannes, Cronjé , OTTO, Stefanus , CRAUSE, Chantelle
发明人： STEYNBERG, Petrus, Johannes , VAN RENSBURG, Hendrik , GROVÉ, Jacobus, Johannes, Cronjé , OTTO, Stefanus , CRAUSE, Chantelle
IPC分类号： C07C29/16
摘要： A process for producing oxygenated products includes reacting an olefin feedstock with carbon monoxide and hydrogen at an elevated reaction temperature and at a superatmospheric reaction pressure in the presence of a hydroformylation catalyst, to produce oxygenated products. The catalyst comprises a mixture of a metal, M, where M is cobalt (Co), rhodium (Rh), ruthenium (Ru) or palladium (Pd); carbon monoxide; hydrogen; and a bicyclic tertiary phosphine. The phosphine has two cyclic structures and a ligating phosphorus atom, with the ligating phosphorus forming part of the largest ring structure of the molecule, and with fewer than two hydrocarbon substituents being present on the carbon atoms of the cyclic structures of the molecule.

4. 发明申请

WO2012153218A1 PROCESS FOR PREPARING A COBALT - CONTAINING HYDROCARBON SYNTHESIS CATALYST PRECURSOR 审中-公开
标题翻译：制备含钴混合催化剂前体的方法
公开(公告)号：WO2012153218A1
公开(公告)日：2012-11-15
申请号：PCT/IB2012/052070
申请日：2012-04-25
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED , ELOFF, Cornelia, Carolina , VAN DE LOOSDRECHT, Jan , VISAGIE, Jacobus, Lucas , VAN RENSBURG, Hendrik
发明人： ELOFF, Cornelia, Carolina , VAN DE LOOSDRECHT, Jan , VISAGIE, Jacobus, Lucas , VAN RENSBURG, Hendrik
IPC分类号： B01J23/75 , B01J23/889 , B01J23/89 , B01J37/08 , C07C1/04 , B01J35/00
CPC分类号： B01J23/75 , B01J21/04 , B01J21/12 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J35/1038 , B01J37/0201 , B01J37/0207 , B01J37/0244 , B01J37/08 , B01J37/088 , B01J37/16 , B01J37/18 , C01G45/00 , C10G2/332 , C10G3/50 , C10G45/00 , Y02P30/20
摘要： A process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor includes calcining a loaded catalyst support comprising a catalyst support supporting a cobalt compound. The calcination includes subjecting the loaded catalyst support to heat treatment by heating the loaded catalyst support to a temperature, T, of at least 220°C at a heating rate below 10°C/minute, and effecting gas flow at a space velocity of at least 9m 3 n/kg cobalt compound/hour over the loaded catalyst support during at least part of the heating. The cobalt-containing hydrocarbon synthesis catalyst precursor is thereby produced.
摘要翻译：制备含钴烃合成催化剂前体的方法包括煅烧负载的催化剂载体，其包含负载钴化合物的催化剂载体。煅烧包括使负载的催化剂载体进行热处理，通过将加载的催化剂载体加热到至少220℃的温度T，加热速率低于10℃/分钟，并且以空气速度在至少部分加热期间，在负载的催化剂载体上至少有9m 3 / kg钴化合物/小时。由此生产含钴烃合成催化剂前体。

5. 发明申请

WO2003068719A2 PRODUCTION OF OXYGENATED PRODUCTS 审中-公开
标题翻译：生产氧化产品
公开(公告)号：WO2003068719A2
公开(公告)日：2003-08-21
申请号：PCT/IB2003/000472
申请日：2003-02-13
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED , STEYNBERG, Petrus, Johannes , VAN RENSBURG, Hendrik , GROVÉ, Jacobus, Johannes, Cronjé , OTTO, Stefanus , CRAUSE, Chantelle
发明人： STEYNBERG, Petrus, Johannes , VAN RENSBURG, Hendrik , GROVÉ, Jacobus, Johannes, Cronjé , OTTO, Stefanus , CRAUSE, Chantelle
IPC分类号： C07C29/00
CPC分类号： B01J31/248 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/845 , C07B41/00 , C07C27/22 , C07C29/16 , C07C45/50 , C07F9/5059 , C07F9/65683 , C07C31/125 , C07C47/02
摘要： A process for producing oxygenated products includes reacting an olefin feedstock with carbon monoxide and hydrogen at an elevated reaction temperature and at a superatmospheric reaction pressure in the presence of a hydroformylation catalyst, to produce oxygenated products. The catalyst comprises a mixture of a metal, M, where M is cobalt (Co), rhodium (Rh), ruthenium (Ru) or palladium (Pd); carbon monoxide; hydrogen; and a bicyclic tertiary phosphine. The phosphine has two cyclic structures and a ligating phosphorus atom, with the ligating phosphorus forming part of the largest ring structure of the molecule, and with fewer than two hydrocarbon substituents being present on the carbon atoms of the cyclic structures of the molecule.
摘要翻译：生产氧化产物的方法包括在加氢甲酰化催化剂存在下，在升高的反应温度和超大气压的反应压力下使烯烃原料与一氧化碳和氢气反应以产生氧化产物。所述催化剂包含金属M（其中M为钴（Co），铑（Rh），钌（Ru）或钯（Pd）的混合物; 一氧化碳; 氢; 和双环叔膦。膦具有两个环状结构和连接的磷原子，连接的磷形成分子的最大环结构的一部分，并且在分子的环状结构的碳原子上存在少于两个烃取代基。 p>

6. 发明申请

WO2014064563A1 PROCESS FOR PREPARING A FISCHER-TROPSCH CATALYST 审中-公开
标题翻译：制备FISCHER-TROPSCH催化剂的方法
公开(公告)号：WO2014064563A1
公开(公告)日：2014-05-01
申请号：PCT/IB2013/059167
申请日：2013-10-07
申请人： SASOL TECHNOLOGY (PROPRIETARY) LIMITED
发明人： VAN RENSBURG, Hendrik
IPC分类号： B01J37/08 , B01J37/00 , B01J37/18 , B01J23/75 , B01J23/89 , C07C1/04 , C10G2/00
CPC分类号： B01J23/8913 , B01J23/75 , B01J37/00 , B01J37/08 , B01J37/18 , C10G2/332 , C10G2/333
摘要： A process for preparing a cobalt-containing hydrocarbon synthesis catalyst includes, in a carbide formation step, treating an initial catalyst precursor comprising a catalyst support supporting cobalt and/or a cobalt compound, with a CO containing gas at a temperature T. T is from 200°C to 280°C. The cobalt or cobalt compound is converted to cobalt carbide thereby obtaining a cobalt carbide containing catalyst precursor. The CO containing gas (when it contains H 2 ) does not have a CO to H 2 molar ratio equal to or less than 33:1. The carbide formation step is carried out under non-oxidative conditions. In a subsequent activation step, the cobalt carbide containing catalyst precursor is subjected to treatment with a hydrogen containing gas at a temperature T 2. T 2 is at least 300°C. The cobalt carbide is converted to cobalt metal thereby activating the cobalt carbide containing catalyst precursor and obtaining a cobalt-containing hydrocarbon synthesis catalyst.
摘要翻译：制备含钴烃合成催化剂的方法包括在碳化物形成步骤中，在温度T T下用含CO的气体处理包含负载钴和/或钴化合物的催化剂载体的初始催化剂前体来自 200℃至280℃。将钴或钴化合物转化为碳化钴，从而得到含有碳化钴的催化剂前体。含CO的气体（当含有H 2时）的CO / H 2摩尔比不等于或小于33:1。碳化物形成步骤在非氧化条件下进行。在随后的活化步骤中，将含碳酸钴的催化剂前体在温度T 2下用含氢气体进行处理.T 2至少为300℃。将钴碳化物转化为钴金属，由此活化含钴碳化物的催化剂前体并获得含钴烃合成催化剂。

7. 发明申请

WO2003068786A1 PHOSPHINE COMPOUNDS 审中-公开
标题翻译：磷化合物
公开(公告)号：WO2003068786A1
公开(公告)日：2003-08-21
申请号：PCT/IB2003/000461
申请日：2003-02-13
申请人： CYTEC TECHNOLOGY CORP , JANSE VAN RENSBURG, Werner , VAN RENSBURG, Hendrik , ROBERTSON, Allan, James
发明人： JANSE VAN RENSBURG, Werner , VAN RENSBURG, Hendrik , ROBERTSON, Allan, James
IPC分类号： C07F9/6568
CPC分类号： B01J31/248 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/845 , C07B41/00 , C07C27/22 , C07C29/16 , C07C45/50 , C07F9/5059 , C07F9/65683 , C07C31/125 , C07C47/02
摘要： A bicyclic tertiary phosphine compound in accordance with the invention has two cyclic structures and a ligating phosphorus atom. The ligating phosphorus atom forms part of the largest ring structure of the molecule, and fewer than two hydrocarbon substituents are present on the carbon atoms of the cyclic structures of the molecule.
摘要翻译：根据本发明的双环叔膦化合物具有两个环状结构和连接的磷原子。连接的磷原子构成分子的最大环结构的一部分，并且在分子的环状结构的碳原子上存在少于两个的烃取代基。

8. 发明公开

EP2704828A1 PROCESS FOR PREPARING A COBALT - CONTAINING HYDROCARBON SYNTHESIS CATALYST PRECURSOR 有权
标题翻译：用于生产钴含烃合成催化剂FORERUNNER
公开(公告)号：EP2704828A1
公开(公告)日：2014-03-12
申请号：EP12721934.3
申请日：2012-04-25
申请人： Sasol Technology (Proprietary) Limited
发明人： ELOFF, Cornelia, Carolina , VAN DE LOOSDRECHT, Jan , VISAGIE, Jacobus, Lucas , VAN RENSBURG, Hendrik
IPC分类号： B01J23/75 , B01J23/889 , B01J23/89 , B01J37/08 , C07C1/04 , B01J35/00
CPC分类号： B01J23/75 , B01J21/04 , B01J21/12 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J35/1038 , B01J37/0201 , B01J37/0207 , B01J37/0244 , B01J37/08 , B01J37/088 , B01J37/16 , B01J37/18 , C01G45/00 , C10G2/332 , C10G3/50 , C10G45/00 , Y02P30/20
摘要： A process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor includes calcining a loaded catalyst support comprising a catalyst support supporting a cobalt compound. The calcination includes subjecting the loaded catalyst support to heat treatment by heating the loaded catalyst support to a temperature, T, of at least 220° C. at a heating rate below 10° C./minute, and effecting gas flow at a space velocity of at least 9 m3n/kg cobalt compound/hour over the loaded catalyst support during at least part of the heating. The cobalt-containing hydrocarbon synthesis catalyst precursor is thereby produced.

9. 发明授权

EP2758170B1 PROCESS FOR PREPARING A COBALT - CONTAINING FISCHER TROPSCH CATALYST 有权
标题翻译：用于生产含钴费 - 托催化剂
公开(公告)号：EP2758170B1
公开(公告)日：2015-10-07
申请号：EP12772489.6
申请日：2012-08-31
申请人： Sasol Technology (Proprietary) Limited
发明人： VAN RENSBURG, Hendrik
IPC分类号： B01J23/89 , B01J37/02 , B01J37/08 , B01J37/14 , B01J37/18 , B01J21/12 , B01J23/75 , C07C1/04 , C10G2/00
CPC分类号： B01J23/8913 , B01J21/12 , B01J23/75 , B01J37/0205 , B01J37/0213 , B01J37/024 , B01J37/088 , B01J37/14 , B01J37/18 , C07C1/043 , C10G2/332

10. 发明授权

EP2911785B1 PROCESS FOR PREPARING A FISCHER-TROPSCH CATALYST 有权
公开(公告)号：EP2911785B1
公开(公告)日：2020-02-12
申请号：EP13808225.0
申请日：2013-10-07
申请人： Sasol Technology (Proprietary) Limited
发明人： VAN RENSBURG, Hendrik
IPC分类号： B01J37/08 , B01J37/00 , B01J37/18 , B01J23/75 , B01J23/89 , C07C1/04 , C10G2/00

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