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1. 发明申请

WO2010124030A1 METHODS OF PREPARING OIL COMPOSITIONS FOR FUEL REFINING 审中-公开
标题翻译：制备燃料精炼油组合物的方法
公开(公告)号：WO2010124030A1
公开(公告)日：2010-10-28
申请号：PCT/US2010/031952
申请日：2010-04-21
申请人： SAPPHIRE ENERGY, INC. , GOODALL, Brian , ARAVANIS, Alex , BEHNKE, Craig , CRANFORD, Richard , SAJKOWSKI, Daniel
发明人： GOODALL, Brian , ARAVANIS, Alex , BEHNKE, Craig , CRANFORD, Richard , SAJKOWSKI, Daniel
IPC分类号： C10G1/10 , C10G29/00
CPC分类号： C10L1/04 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G45/08 , C10G65/043 , C10G65/046 , C10G65/12 , C10G67/04 , C10G69/04 , C10G69/06 , C10G69/08 , C10G2300/1014 , C10G2300/202 , C10G2300/205 , C10G2300/30 , C10G2300/4018 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/06 , C10L1/08 , C11B3/02 , C11C3/12 , C11C3/14 , C12P7/6463 , Y02P30/20
摘要： Disclosed herein are methods and systems for upgrading (for example, removing heteroatoms, metals, or metalloids) an oil composition derived or extracted from a biomass. The upgraded oil composition can be used to make a desired product, for example, a fuel product.
摘要翻译：本文公开了用于升级（例如，去除杂原子，金属或准金属）从生物质衍生或提取的油组合物的方法和系统。改进的油组合物可用于制备所需产物，例如燃料产品。

2. 发明申请

WO2013006578A1 THERMAL TREATMENT OF CRUDE ALGAE OIL 审中-公开
标题翻译：原油油热处理
公开(公告)号：WO2013006578A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/045305
申请日：2012-07-02
申请人： SAPPHIRE ENERGY, INC. , ROUSSIS, Stilianos , SAJKOWSKI, Daniel , CRANFORD, Richard
发明人： ROUSSIS, Stilianos , SAJKOWSKI, Daniel , CRANFORD, Richard
IPC分类号： C11B3/00 , C11B1/02 , C11B1/04 , C11B1/10 , C12N1/06
CPC分类号： C11B3/00 , C10L1/00 , C10L2290/02 , C11C3/00
摘要： Crude algae oils are thermally-treated at temperature(s) in the range of 300 - 600 °C, without catalyst and/or the addition of hydrogen, to produce a higher grade, cleaner algae oil with, for example, reduced oxygen, boiling range, viscosity and/or density, and acid number, in addition, because the thermal treatment reduces metals in the oil and produces carbonaceous solids, it is expected that catalyst deactivation by algae oil feedstocks will be greatly reduced if the crude algae oil or fractions thereof are thermally-treated prior to catalytic upgrading. Oxy gen, fatty acids, metals, and metalloids are reduced/removed by the thermal treatment, so that RBI) processing of the crude bio-oil may be reduced or eliminated, and requirements for further deoxygenatiou and hydrotreating of the thermal products are reduced or eliminated.
摘要翻译：将粗藻油在300-600℃范围内的温度下进行热处理，无需催化剂和/或加入氢气，以产生更高级，更清洁的藻类油，例如还原氧，沸腾范围，粘度和/或密度以及酸值，此外，由于热处理降低了油中的金属并产生碳质固体，因此预计如果粗藻油或级分的话，藻油原料的催化剂失活将大大降低在催化升级之前进行热处理。通过热处理减少/除去氧基，脂肪酸，金属和准金属，从而可以减少或消除粗生物油的RBI）加工，并且降低热产物的进一步脱氧和加氢处理的要求淘汰。

3. 发明申请

WO2013063595A1 PROCESSES FOR UPGRADING ALGAE OILS AND PRODUCTS THEREOF 审中-公开
标题翻译：提高阿拉伯油及其制品的方法
公开(公告)号：WO2013063595A1
公开(公告)日：2013-05-02
申请号：PCT/US2012/062468
申请日：2012-10-29
申请人： SAPPHIRE ENERGY, INC. , SAJKOWSKI, Daniel , ROUSSIS, Stilianos , CRANFORD, Richard
发明人： SAJKOWSKI, Daniel , ROUSSIS, Stilianos , CRANFORD, Richard
IPC分类号： C10G45/00 , C10G3/00 , C11B1/10
CPC分类号： C07C5/02 , C07C1/2078 , C10G3/42 , C10G3/50 , C10G11/18 , C10G2300/1014 , C11B1/02 , C11B1/04 , C11B1/10 , C11C3/00 , C11C3/123 , C11C3/126 , Y02P30/20
摘要： Algae oil feeds comprise a wide range of molecular species forming a complex mixture of molecules having varying sizes and therefore varying boiling points, comprise high nitrogen, oxygen, and fatty acid content, but comprise low sulfur, saturated hydrocarbons, and triglycerides. The wide range of molecular species in the algae oil feeds, very unusual compared to conventional refinery feedstocks and vegetable oils, may be upgraded into fuels by conventional refining approaches such as thermal and/or catalytic-hydroprocessing. Hydrotreating at high pressure over large-pore catalyst, and optionally followed by FCC cracking, has shown a beneficial product slate including coke yield. Thermal treatment prior to hydrotreating may improve hydrotreating feedstock quality. Unusual behavior of the algae oils in thermal treatment and/or hydroprocessing, including cracking to lower boiling range compounds, may provide a high quality product slate with the flexibility to adjust the product slate due to the cracking behavior exhibited by these algae oils.
摘要翻译：藻类油料饲料包括广泛的分子种类，形成具有不同大小，因此变化沸点的分子的复杂混合物，包含高氮，氧和脂肪酸含量，但包含低硫，饱和烃和甘油三酯。与常规炼油原料和植物油相比，藻类油进料中广泛的分子种类可能通过常规的精炼方法如热和/或催化加氢处理而升级为燃料。在高压下在大孔催化剂上加氢处理，随后进行FCC裂解，已经显示出有益的产品，包括焦炭产率。在加氢处理之前的热处理可以提高加氢处理原料质量。藻类油在热处理和/或加氢处理（包括开裂至较低沸点化合物）中的不寻常行为可以提供高质量的产品板岩，具有由于这些藻油所显示的裂纹行为而调整产品板岩的灵活性。

4. 发明公开

EP2421934A1 METHODS OF PREPARING OIL COMPOSITIONS FOR FUEL REFINING 审中-公开
标题翻译：工艺生产油组合物用于燃料精炼
公开(公告)号：EP2421934A1
公开(公告)日：2012-02-29
申请号：EP10767732.0
申请日：2010-04-21
申请人： Sapphire Energy, Inc.
发明人： GOODALL, Brian , ARAVANIS, Alex , BEHNKE, Craig , CRANFORD, Richard , SAJKOWSKI, Daniel
IPC分类号： C10G1/10 , C10G29/00
CPC分类号： C10L1/04 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G45/08 , C10G65/043 , C10G65/046 , C10G65/12 , C10G67/04 , C10G69/04 , C10G69/06 , C10G69/08 , C10G2300/1014 , C10G2300/202 , C10G2300/205 , C10G2300/30 , C10G2300/4018 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/06 , C10L1/08 , C11B3/02 , C11C3/12 , C11C3/14 , C12P7/6463 , Y02P30/20
摘要： Disclosed herein are methods and systems for upgrading (for example, removing heteroatoms, metals, or metalloids) an oil composition derived or extracted from a biomass. The upgraded oil composition can be used to make a desired product, for example, a fuel product.

5. 发明授权

EP2771433B1 PROCESSES FOR UPGRADING ALGAE OILS AND PRODUCTS THEREOF 有权
标题翻译：一种用于处理藻油及其产品
公开(公告)号：EP2771433B1
公开(公告)日：2016-04-27
申请号：EP12843409.9
申请日：2012-10-29
申请人： Sapphire Energy, Inc.
发明人： SAJKOWSKI, Daniel , ROUSSIS, Stilianos , CRANFORD, Richard
IPC分类号： C10G45/00 , C10G3/00 , C11B1/10 , C11B1/02 , C11B1/04 , C07C1/207 , C07C5/02 , C11C3/00 , C10G11/18 , C11C3/12
CPC分类号： C07C5/02 , C07C1/2078 , C10G3/42 , C10G3/50 , C10G11/18 , C10G2300/1014 , C11B1/02 , C11B1/04 , C11B1/10 , C11C3/00 , C11C3/123 , C11C3/126 , Y02P30/20

6. 发明公开

EP2771433A1 PROCESSES FOR UPGRADING ALGAE OILS AND PRODUCTS THEREOF 有权
标题翻译：一种用于处理藻油及其产品
公开(公告)号：EP2771433A1
公开(公告)日：2014-09-03
申请号：EP12843409.9
申请日：2012-10-29
申请人： Sapphire Energy, Inc.
发明人： SAJKOWSKI, Daniel , ROUSSIS, Stilianos , CRANFORD, Richard
IPC分类号： C10G45/00 , C10G3/00 , C11B1/10
CPC分类号： C07C5/02 , C07C1/2078 , C10G3/42 , C10G3/50 , C10G11/18 , C10G2300/1014 , C11B1/02 , C11B1/04 , C11B1/10 , C11C3/00 , C11C3/123 , C11C3/126 , Y02P30/20
摘要： Algae oil feeds comprise a wide range of molecular species forming a complex mixture of molecules having varying sizes and therefore varying boiling points, comprise high nitrogen, oxygen, and fatty acid content, but comprise low sulfur, saturated hydrocarbons, and triglycerides. The wide range of molecular species in the algae oil feeds, very unusual compared to conventional refinery feedstocks and vegetable oils, may be upgraded into fuels by conventional refining approaches such as thermal and/or catalytic-hydroprocessing. Hydrotreating at high pressure over large-pore catalyst, and optionally followed by FCC cracking, has shown a beneficial product slate including coke yield. Thermal treatment prior to hydrotreating may improve hydrotreating feedstock quality. Unusual behavior of the algae oils in thermal treatment and/or hydroprocessing, including cracking to lower boiling range compounds, may provide a high quality product slate with the flexibility to adjust the product slate due to the cracking behavior exhibited by these algae oils.

7. 发明公开

EP2726587A1 THERMAL TREATMENT OF CRUDE ALGAE OIL 审中-公开
标题翻译：水藻原油热处理
公开(公告)号：EP2726587A1
公开(公告)日：2014-05-07
申请号：EP12807901.9
申请日：2012-07-02
申请人： Sapphire Energy, Inc.
发明人： ROUSSIS, Stilianos , SAJKOWSKI, Daniel , CRANFORD, Richard
IPC分类号： C11B3/00 , C11B1/02 , C11B1/04 , C11B1/10 , C12N1/06
CPC分类号： C11B3/00 , C10L1/00 , C10L2290/02 , C11C3/00
摘要： Crude algae oils are thermally-treated at temperature(s) in the range of 300 - 600 °C, without catalyst and/or the addition of hydrogen, to produce a higher grade, cleaner algae oil with, for example, reduced oxygen, boiling range, viscosity and/or density, and acid number, in addition, because the thermal treatment reduces metals in the oil and produces carbonaceous solids, it is expected that catalyst deactivation by algae oil feedstocks will be greatly reduced if the crude algae oil or fractions thereof are thermally-treated prior to catalytic upgrading. Oxy gen, fatty acids, metals, and metalloids are reduced/removed by the thermal treatment, so that RBI) processing of the crude bio-oil may be reduced or eliminated, and requirements for further deoxygenatiou and hydrotreating of the thermal products are reduced or eliminated.

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