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1. 发明专利

DE1168386B 未知
公开(公告)号：DE1168386B
公开(公告)日：1964-04-23
申请号：DES0074255
申请日：1961-06-08
申请人： SANDOZ AG
发明人： LERCH URS , MERIAN DR ERNEST , SENN DR OTTO
IPC分类号： C09B1/22 , C09B1/50 , C09B67/22 , C09B67/38 , D06P1/16 , D06P3/42 , D06P3/48
摘要： Monoazo dyes of formulae wherein A1 is chlorine or bromine, A2 and A3 are hydrogen, chlorine or bromine (A2 or A3 being hydrogen), X is chlorine hydrogen, methyl or ethyl, Y1 is a hydrogen or a C1-C6 alkyl, acetoxy, propionyloxy or cyano group, Y2 is an acetoxy, propionyloxy, methoxycarbonyl, ethoxycarbonyl or cyano group, Z1 is chlorine or bromine or a trifluoromethyl or cyano group and Z2 is hydrogen or, when Z1 is cyano, hydrogen, chlorine or bromine, are used in dyestuff compositions (see Division D1). In Example (1) 2,6-dichloro-4-nitroaniline is diazolized and coupled with N-cyanoethyl-N-hydroxyethyl aniline and the resultant dye acetylated with acetic anhydride. Many dyes of the above formulae are listed. Reference has been directed by the Comptroller to Specifications 813,906, 852,396, 855,488 and 872,481.ALSO:Dyestuff compositions used in dyeing polyester and cellulose acetate fibres in brown shades comprise dyes of formulae wherein A1 or chlorine or bromine, A2 and A3 are hydrogen, chlorine or bromine (A2 or A3 being hydrogen), X is methyl, ethyl, chlorine or hydrogen, Y1 is hydrogen or a C1-C6 alkyl acetoxy, propionyloxy or nitrile group, Y2 is an acetoxy, propionyloxy, methoxycarbonyl, ethoxycarbonyl or nitrile group, Z1 is chlorine or bromine or a trifluoromethyl or nitrile group, Z2 is hydrogen or, when Z1 is nitrile, hydrogen, chlorine or bromine, R1 and R2 are independently hydrogen or a C1-C6 alkyl radical and W is chlorine or bromine or an alkoxy, hydroxyaryl or alkoxyaryl radical. The compositions may contain dispersing agents. In examples the mixture of dyes is (1) ground with sodium dinaphthylmethane disulphonate sodium cetylsulphate and sodium sulphate; (2) ground with water and sulphitecellulose waste powder and the paste jet dried; (3) pasted with turkey red oil and water; (4) ground with sodium dinaphthylmethane disulphonate and water to form a colloidal solution which is mixed with the addition product of 2 mols of ethylene oxide and 1 mol of butanol and carboxymethylcellulose to form a printing paste; (99) pasted with sodium dinaphthyl methane disulphonate, butyl carbitol, crystal gum and water; (100) used together with sodium dinaphthylmethane disulphonate and sodium alginate in an aqueous padding liquor. Reference has been directed by the Comptroller to Specifications 813,906, 852,396, 855,488 and 872,481.

2. 发明专利

DE1087730B 未知
公开(公告)号：DE1087730B
公开(公告)日：1960-08-25
申请号：DES0058396
申请日：1958-05-28
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST
IPC分类号： C09B33/06

3. 发明专利

DE1083459B 未知
公开(公告)号：DE1083459B
公开(公告)日：1960-06-15
申请号：DES0050902
申请日：1956-10-17
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST
IPC分类号： C09B43/11 , C09B51/00 , C09B56/00

4. 发明专利

DE1261105B 未知
公开(公告)号：DE1261105B
公开(公告)日：1968-02-15
申请号：DES0092214
申请日：1964-07-23
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , WASEM HANS
IPC分类号： C09B25/00

5. 发明专利

DE1236461B 未知
公开(公告)号：DE1236461B
公开(公告)日：1967-03-16
申请号：DES0076839
申请日：1961-11-25
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , SENN DR OTTO
IPC分类号： D06P1/16

6. 发明专利

DE1219608B 未知
公开(公告)号：DE1219608B
公开(公告)日：1966-06-23
申请号：DES0074256
申请日：1961-06-08
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , SENN DR OTTO
IPC分类号： C09B43/20

7. 发明专利

DE1156912B 未知
公开(公告)号：DE1156912B
公开(公告)日：1963-11-07
申请号：DES0079760
申请日：1960-06-20
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , SENN DR OTTO
IPC分类号： C09B29/32

8. 发明专利

DE1113772B 未知
公开(公告)号：DE1113772B
公开(公告)日：1961-09-14
申请号：DES0061577
申请日：1959-01-31
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , NICOLAUS DR BRUNO
IPC分类号： C08K5/47 , C08L75/04 , C09B29/033 , C09B43/00 , C09B43/32 , D06P1/02

9. 发明专利

DE1061924B 未知
公开(公告)号：DE1061924B
公开(公告)日：1959-07-23
申请号：DES0047589
申请日：1956-02-21
申请人： SANDOZ AG
发明人： MERIAN DR ERNEST , NICOLAUS DR BRUNO J R , WEHRLI DR WALTER
IPC分类号： C09B43/124

10. 发明专利

DE1263680B 未知
公开(公告)号：DE1263680B
公开(公告)日：1968-03-21
申请号：DES0080824
申请日：1962-08-09
申请人： SANDOZ AG
发明人： CARBONELL DR JOSE , MERIAN DR ERNEST , NEIER DR REINHARD
IPC分类号： C09B45/14 , D06P3/79
摘要： Shaped articles of polyolefins, especially of polypropylene or polyisobutylene, are dyed at an elevated temperature with an aqueous preparation containing a dye of formula wherein X is alkyl, preferably C1-5, or Cl or Br. The polymer to be dyed contains e.g. Ni, Cr, Co or Al in the form of catalyst residues and/or stabilisers. The term "shaped articles" includes filaments, fibres, yarns, slubbing and tops, nonwoven and woven fabrics, knitted goods, films, foil and tubing.

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