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    • 2. 发明专利
    • Method of manufacturing single crystal gallium nitride thick film
    • 制造单晶氮化镓厚膜的方法
    • JP2007137763A
    • 2007-06-07
    • JP2006315832
    • 2006-11-22
    • Samsung Corning Co Ltd三星コーニング株式会社
    • SHIN HYUN MINLEE CHANG HO
    • C30B29/38C23C16/34C30B25/10H01L21/205
    • C30B29/40C30B25/02
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a single crystal gallium nitride (GaN) thick film in which defects and cracks are reduced and which has excellent crystal quality by a hydride vapor phase epitaxy (HVPE) process. SOLUTION: The method of manufacturing the single crystal gallium nitride (GaN) thick film comprises loading a base substrate in an HVPE reactor, supplying gallium (Ga), hydrogen chloride (HCl) gas and ammonia (NH 3 ) gas, and growing the single crystal gallium nitride (GaN) thick film on the base substrate. The method includes: (1) a step of growing a first GaN film at a temperature area (surface kinetics regime), where the growth rate is determined by the reaction rate on a film surface; and (2) a step of growing a second GaN film on the first GaN film, grown in the step (1), at a temperature area (mass transport regime), where the growth rate is determined by material diffusion in the vapor phase. At this time, the growth temperature in the step (2) is higher than that in the step (1). COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供一种通过氢化物气相外延(HVPE)工艺制造其中缺陷和裂纹降低并且具有优异的晶体质量的单晶氮化镓(GaN)厚膜的方法。 解决方案:制造单晶氮化镓(GaN)厚膜的方法包括在HVPE反应器中加载基底,提供镓(Ga),氯化氢(HCl)气体和氨(NH 3 SB 3, / SB>)气体,并在基底衬底上生长单晶氮化镓(GaN)厚膜。 该方法包括:(1)在温度区域(表面动力学状态)生长第一GaN膜的步骤,其中生长速率由膜表面上的反应速率决定; 和(2)在步骤(1)中生长的第一GaN膜上生长第二GaN膜的温度区域(质量传输方式)的步骤,其中生长速率通过气相中的材料扩散来确定。 此时,步骤(2)中的生长温度高于步骤(1)中的生长温度。 版权所有(C)2007,JPO&INPIT