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    • 3. 发明申请
    • THERMOPLASTIC POLYIMIDES, METHOD FOR THE MANUFACTURE THEREOF, AND ARTICLES PREPARED THEREFROM
    • 热塑性聚酰亚胺及其制造方法和由其制备的制品
    • WO2017132656A1
    • 2017-08-03
    • PCT/US2017/015592
    • 2017-01-30
    • SABIC GLOBAL TECHNOLOGIES B.V.PATIL, Dadasaheb V.
    • PATIL, Dadasaheb V.CHELLAMUTHU, Manojkumar
    • C08G73/10C08L79/08
    • C08L79/08C08G73/1046C08G73/105
    • A polymer composition including a polyetherimide comprising repeating units of formula (1) and formula (2) [Formula should be inserted here] wherein the repeating units of formula (1) are present in an amount of at least 10 mole %, preferably 20 to 100 mole %, Z is independently at each occurrence derived from a biphenol; Z' is independently at each occurrence a group of formulas (3) to (13) as defined herein, preferably bisphenol A, 1,2-dihydroxybenzene, 1,1-bis(4-hydroxyphenyl)-1-phenyl-ethane, isophorone bisphenol (1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane), spirobiindane bisphenol, dimethylindanone bisphenol, 3,3'-dimethylbisphenol cyclohexane, or fluorenone bisphenol; and R is independently at each occurrence as a C 6-20 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C 2-20 alkylene group or a halogenated derivative thereof, a C 3-8 cycloalkylene group or halogenated derivative thereof; wherein the polyetherimide has a Tg of greater than 200°C.
    • 包含含有式(1)和式(2)的重复单元的聚醚酰亚胺的聚合物组合物[其中式(1)的重复单元以式 至少10摩尔%,优选20至100摩尔%,Z在每种情况下独立地衍生自联苯酚; Z'在每次出现时独立地为如本文所定义的式(3)至(13)的基团,优选双酚A,1,2-二羟基苯,1,1-双(4-羟基苯基)-1-苯基乙烷,异佛尔酮 双酚(1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷),螺二茚满双酚,二甲基茚满酮双酚,3,3'-二甲基双酚环己烷或芴酮双酚; 并且R在每次出现时独立地为C≡6-20芳族烃基或其卤代衍生物,直链或支链C 2-20亚烷基或卤代 其衍生物,C 3-8亚环烷基或其卤代衍生物; 其中聚醚酰亚胺的Tg大于200℃