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1. 发明授权

US06533911B1 Device for measuring combustible-gas concentration in an exhaust gas 有权
标题翻译：用于测量废气中的可燃气体浓度的装置
公开(公告)号：US06533911B1
公开(公告)日：2003-03-18
申请号：US09590189
申请日：2000-06-09
申请人： Hiroki Fujita , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Ryuji Inoue , Takafumi Oshima
发明人： Hiroki Fujita , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Ryuji Inoue , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/4075 , G01N27/4067
摘要： A device and method for measuring combustible-gas concentration and a device and method for measuring hydrocarbon-gas concentration, which exhibit low dependence on oxygen concentration variations as well as low temperature dependence. Paste is applied to the inner surface of a closed-bottom cylindrical solid electrolyte element, thereby forming a layer serving as a reference electrode. Plating with platinum is performed, so as to form a layer serving as a first detection electrode, on the outer surface of the solid electrolyte element only at a portion extending from an end portion of the solid electrolyte element to the vicinity of the interface between a heating resistor and a heating-resistor lead portion, which are formed within a heater element contained in the cylindrical solid electrolyte element. Paste which contains gold powder and 10 parts of indium oxide is applied onto the platinum-plating layer so as to form a layer serving as a second detection electrode, followed by firing. Subsequently, a diffusion layer containing spinel is formed by thermal spraying on the surface of a detection electrode. The heater element is disposed in the solid electrolyte element such that an end portion abuts an inner bottom portion of the solid electrolyte element. Lead wires for measuring internal resistance, which extend from the reference electrodes, and a lead wire extending from the detection electrode are connected to a temperature controller.
摘要翻译：用于测量可燃气体浓度的装置和方法以及测量烃 - 气体浓度的装置和方法，其对氧浓度变化的依赖性低以及低温依赖性。将糊状物施加到封闭底部的圆柱形固体电解质元件的内表面，从而形成用作参考电极的层。进行铂的电镀，以形成用作第一检测电极的层，仅在固体电解质元件的外表面上，仅在从固体电解质元件的端部延伸到位于固体电解质元件的界面附近的部分加热电阻器和加热电阻器引线部分，其形成在容纳在圆柱形固体电解质元件中的加热器元件内。将含有金粉末和10份氧化铟的浆料施加到铂镀层上，以形成用作第二检测电极的层，随后进行烧制。随后，通过热电喷涂在检测电极的表面上形成含有尖晶石的扩散层。加热器元件设置在固体电解质元件中，使得端部邻接固体电解质元件的内部底部。用于测量从参考电极延伸的内部电阻的引线和从检测电极延伸的引线连接到温度控制器。

2. 发明授权

US06303012B1 Gas sensor, gas sensor system using the same 失效
标题翻译：气体传感器，气体传感器系统使用相同
公开(公告)号：US06303012B1
公开(公告)日：2001-10-16
申请号：US09158147
申请日：1998-09-22
申请人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
发明人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/417
摘要： The gas sensor 1 has the following constituent features: (1) first processing space 9: a measurement gas is introduced thereinto via a first gas passage 11; (2) second processing space 10: a gas contained in the first processing space 9 is introduced thereinto via a second gas passage 13; (3) oxygen concentration detection element 4: adapted to measure the oxygen concentration of a gas contained in the first processing space 9; (4) oxygen pumping element 3: adapted to reduce the oxygen concentration of the measurement gas introduced into the first processing space 9 within a range such that water vapor contained in the measurement gas is not substantially decomposed; (5) oxidation catalyst section 16: adapted to accelerate combustion of a combustible gas component contained in a gas introduced into the second processing space 10; and (6) combustible gas component concentration detection element 5: a constant voltage is applied thereto, and element 5 has an output current which varies according to the amount of oxygen consumed by combustion of a combustible gas component contained in the gas introduced into the second processing space 10 from the first processing space, to thereby provide information regarding the concentration of the combustible gas component of the measurement gas based on the output current.
摘要翻译：气体传感器1具有以下构成特征：（1）第一处理空间9：经由第一气体通路11导入测定气体; （2）第二处理空间10：通过第二气体通道13将包含在第一处理空间9中的气体引入其中; （3）氧浓度检测元件4：适于测量包含在第一处理空间9中的气体的氧浓度; （4）氧气抽吸元件3：适于在测量气体中包含的水蒸气基本上不分解的范围内减少引入第一处理空间9的测量气体的氧浓度; （5）氧化催化剂部分16：适于加速包含在引入第二处理空间10的气体中的可燃气体组分的燃烧; 和（6）可燃气体成分浓度检测元件5：向其施加恒定电压，元件5具有输出电流，该输出电流根据包含在引入第二电极的气体中的可燃性气体成分的燃烧消耗的氧量而变化处理空间10，从而基于输出电流提供关于测量气体的可燃气体成分的浓度的信息。

3. 发明授权

US06554984B2 Method of manufacturing a gas sensor 失效
标题翻译：制造气体传感器的方法
公开(公告)号：US06554984B2
公开(公告)日：2003-04-29
申请号：US09883999
申请日：2001-06-20
申请人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
发明人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/417
摘要： A method of manufacturing a gas sensor, including a substrate electrode layer forming step, and a surface electrode layer forming step. The gas sensor includes first and second processing spaces, an oxygen concentration detection element, an oxygen pumping element, an oxidation catalyst and a combustible gas component concentration detection element.
摘要翻译：一种制造气体传感器的方法，包括基底电极层形成步骤和表面电极层形成步骤。气体传感器包括第一和第二处理空间，氧浓度检测元件，氧气抽吸元件，氧化催化剂和可燃气体成分浓度检测元件。

4. 发明授权

US06325906B1 Gas sensor and apparatus for measuring combustible gas component concentration using the same 有权
标题翻译：用于测量可燃气体组分浓度的气体传感器和装置
公开(公告)号：US06325906B1
公开(公告)日：2001-12-04
申请号：US09453540
申请日：1999-12-03
申请人： Shoji Kitanoya , Tomohiro Fuma , Kenji Kato , Ryuji Inoue , Takafumi Oshima
发明人： Shoji Kitanoya , Tomohiro Fuma , Kenji Kato , Ryuji Inoue , Takafumi Oshima
IPC分类号： G01N27407
摘要： A gas sensor includes a first processing chamber 3 into which a gas under measurement is introduced through a first gas passage 2; a second processing chamber 5 into which the gas is introduced from the first processing chamber 3 through a second gas passage 4 and in which combustible gas components burn; a third gas passage 15 for introducing O2 into the second processing chamber 5 under diffusion resistance; oxygen pump element 12 adapted to pump out O2 from or pump into the first processing chamber 3 on the basis of an output from an oxygen-concentration sensor 13, which senses the oxygen concentration of the gas introduced into the second processing chamber 5, to thereby control the oxygen concentration of the gas; and a second oxygen pump including a second inner electrode 10 and a second outer electrode 11 formed on an oxygen-ion conductor 1 in such a manner as to face the interior and exterior, respectively, of the second processing chamber 5, and adapted to pump out O2 which remains unconsumed in burning mentioned above in the second processing chamber 5, through application of a constant voltage between the second inner electrode 10 and the second outer electrode 11. The residual oxygen concentration of the second processing chamber 5 is determined on the basis of a second oxygen pump current flowing between the second inner and outer electrodes 10 and 11, whereby the concentration of combustible gas components contained in the gas under measurement is determined.
摘要翻译：气体传感器包括：第一处理室3，通过第一气体通道2引入测量气体; 第二处理室5，通过第二气体通道4从第一处理室3引入气体，其中可燃气体组分燃烧; 用于以扩散阻力将O 2引入第二处理室5的第三气体通道15; 氧气泵元件12适于根据来自氧浓度传感器13的输出来泵出O2或泵入第一处理室3，氧浓度传感器13检测引入第二处理室5的气体的氧气浓度，从而控制气体的氧气浓度; 以及第二氧气泵，其包括分别形成在氧离子导体1上的第二内部电极10和第二外部电极11，以分别面对第二处理室5的内部和外部，并且适于泵送在第二处理室5中通过在第二内部电极10和第二外部电极11之间施加恒定电压而在上述燃烧中保持未燃烧的O 2。第二处理室5的残余氧浓度基于在第二内电极10和第二电极11之间流动的第二氧泵电流，由此确定测量气体中所含的可燃气体组分的浓度。

5. 发明授权

US06338783B1 Gas sensor, method of manufacturing the same, and gas sensor system using the gas sensor 失效
标题翻译：气体传感器及其制造方法以及使用气体传感器的气体传感器系统
公开(公告)号：US06338783B1
公开(公告)日：2002-01-15
申请号：US09448441
申请日：1999-11-24
申请人： Ryuji Inoue , Shoji Kitanoya , Tomohiro Fuma , Kenji Kato , Takafumi Oshima
发明人： Ryuji Inoue , Shoji Kitanoya , Tomohiro Fuma , Kenji Kato , Takafumi Oshima
IPC分类号： G01N27407
CPC分类号： G01N27/417
摘要： A gas sensor which can detect the concentration of a combustible gas component in a measurement gas with high accuracy even when the oxygen concentration of the measurement gas or the element temperature changes and which has an excellent response in detecting the combustible gas component is disclosed. In a gas sensor 1, the oxygen concentration of a measurement gas is adjusted to a predetermined level within a first processing space 9 through operation of a first oxygen pump element 3. The measurement gas having an adjusted oxygen concentration is then introduced into a second processing space 10, where a combustible gas component is burned through the assistance of electrodes 16 and 17 functioning as oxidation catalyst sections. Constant voltage is applied to a combustible gas component concentration detection element 5. In this state, when the amount of oxygen changes due to the combustion of the combustible gas component, the output current of the combustible gas component concentration detection element 5 changes with change in the amount of oxygen. Therefore, information regarding the combustible gas component concentration of the original measurement gas can be obtained from the value of the output current. Further, oxygen required to burn the combustible gas component within the second processing space 10 is supplemented by a second oxygen pump element 6. Unlike conventional apparatuses, no feedback system is used, and a variation in the concentration of the combustible gas component appears directly as a variation in the current of the combustible gas component concentration detection element 5. Therefore, a high detection response is obtained.
摘要翻译：公开了一种气体传感器，其即使在测量气体或元件温度的氧浓度变化并且在检测可燃气体成分时具有优异的响应性的情况下也可以高精度地检测测量气体中的可燃气体成分的浓度。在气体传感器1中，测量气体的氧浓度通过第一氧气泵元件3的操作在第一处理空间9内被调节到预定水平。然后将具有调节氧浓度的测量气体引入第二处理空间10，其中通过用作氧化催化剂部分的电极16和17的帮助燃烧可燃气体组分。恒定电压被施加到可燃气体成分浓度检测元件5上。在这种状态下，当由于可燃性气体成分的燃烧而导致氧气的变化时，可燃性气体成分浓度检测元件5的输出电流随着氧气量。因此，可以从输出电流的值获得关于原始测量气体的可燃气体成分浓度的信息。此外，在第二处理空间10内燃烧可燃气体成分所需的氧被第二氧气泵元件6补充。与常规装置不同，不使用反馈系统，并且可燃气体组分的浓度的变化直接作为可燃性气体成分浓度检测元件5的电流的变化。因此，获得高检测响应。

6. 发明授权

US6153072A Gas sensor, gas sensor system using the same, and method of manufacturing a gas sensor 失效
标题翻译：气体传感器，使用其的气体传感器系统以及制造气体传感器的方法
公开(公告)号：US6153072A
公开(公告)日：2000-11-28
申请号：US150295
申请日：1998-09-09
申请人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
发明人： Ryuji Inoue , Shoji Kitanoya , Kenji Kato , Tomohiro Fuma , Takafumi Oshima
IPC分类号： G01N27/419 , G01N27/416 , G01N27/417 , G01N27/407
CPC分类号： G01N27/417
摘要： A gas sensor 1 including a first processing space 9; a first gas passage 11; a second processing space 10; a second gas passage 13; an oxygen concentration detection element 4; a first oxygen pumping element 3 adapted to reduce the oxygen concentration of exhaust gas introduced into the first processing space 9 within a range such that a water vapor contained in the measurement gas is not substantially decomposed; an oxygen catalyst section 16; and a combustible gas component concentration information generation/output section 5. Also disclosed is a gas sensor system including the above gas sensor and first oxygen pumping operation control means for adjusting the oxygen concentration of the measurement gas introduced into the first processing space within a range such that water vapor contained in the measuring gas is not substantially decomposed.
摘要翻译：一种气体传感器1，包括第一处理空间9; 第一气体通道11; 第二处理空间10; 第二气体通道13; 氧浓度检测元件4; 第一氧气抽吸元件3，其适于在被包含在测量气体中的水蒸气基本上不分解的范围内减少引入到第一处理空间9中的废气的氧浓度; 氧催化剂部分16; 以及可燃气体成分浓度信息生成/输出部5.还公开了一种气体传感器系统，其包括上述气体传感器和第一氧气抽运运转控制装置，用于将导入到第一处理空间的测量气体的氧浓度调整到一定范围内使得包含在测量气体中的水蒸气基本上不分解。

7. 发明授权

US6136170A Exhaust gas sensor and system thereof 失效
标题翻译：废气传感器及其系统
公开(公告)号：US6136170A
公开(公告)日：2000-10-24
申请号：US997738
申请日：1997-12-24
申请人： Ryuji Inoue , Tomohiro Fuma , Shoji Kitanoya , Yumi Mizutani , Masahito Kida , Takafumi Oshima , Takashi Hibino
发明人： Ryuji Inoue , Tomohiro Fuma , Shoji Kitanoya , Yumi Mizutani , Masahito Kida , Takafumi Oshima , Takashi Hibino
IPC分类号： G01N27/406 , G01N27/407 , G01N27/417 , G01N27/419 , G01N33/00 , G01N27/26
CPC分类号： G01N27/417 , G01N27/4065 , G01N27/4075 , G01N27/419 , G01N33/0047
摘要： The present invention provides an apparatus for measuring the concentration of a constituent to be detected in exhaust gas, which apparatus is capable of detecting with a high accuracy the concentration of the constituent to be detected in exhaust gas even though oxygen concentration in the exhaust gas varies. In an exhaust gas sensor 1 for use in the measuring apparatus, exhaust gas is introduced into spaces 15, 16 on both sides of an oxygen concentration cell element 4, and the oxidation catalyst activities of first to third electrodes 11 to 13 are adjusted so that there occurs a difference between the space 15 and the space 16 in consumption of the constituent to be detected, which consumption is caused by the oxidation of the constituent. Thus a concentration cell electromotive force is generated in the oxygen concentration cell element 4, and an oxygen pump element 3 pumps oxygen into or out of the space 15 so that the electromotive force is held at an target value EC not more than 10 mV. The pump current at this time is taken as the detection output on the constituent to be detected. The strengths of the oxygen concentration cell element 4 and of the oxygen pump element 3 can be increased by the provision of an integrated sintered body in which the elements 4 and 3 are laminated together with the space 15 formed between the first electrode 11 and the second electrode 12. Besides, the accuracy of detecting the constituent to be detected can be improved by the control over the temperature of the oxygen concentration cell element 4 and by the temperature compensation to the pump current.
摘要翻译：本发明提供了一种用于测量排气中要检测的成分浓度的装置，该装置能够高精度地检测排气中的待检测物质的浓度，即使废气中的氧浓度变化。在用于测定装置的废气传感器1中，将废气引入到氧浓度电池元件4的两侧的空间15,16中，调整第一〜第三电极11〜13的氧化催化剂活性，在被检测成分消耗的空间15和空间16之间存在差异，该消耗是由成分的氧化引起的。因此，在氧浓度电池元件4中产生浓度电池电动势，并且氧气泵元件3将氧气输入到空间15中或从空间15排出，使得电动势保持在不大于10mV的目标值EC。此时的泵电流被作为要检测的成分的检测输出。可以通过提供一体的烧结体来增加氧浓度电池元件4和氧气泵元件3的强度，其中元件4和3与形成在第一电极11和第二电极11之间的空间15层叠在一起电极12.此外，通过控制氧浓度电池元件4的温度以及对泵电流的温度补偿，可以提高检测成分的检测精度。

8. 发明授权

US5993625A Exhaust gas sensor 失效
标题翻译：废气传感器
公开(公告)号：US5993625A
公开(公告)日：1999-11-30
申请号：US820522
申请日：1997-03-19
申请人： Ryuji Inoue , Yumi Kuroki , Tomohiro Fuma , Shoji Kitanoya , Satoshi Sugaya , Takafumi Oshima
发明人： Ryuji Inoue , Yumi Kuroki , Tomohiro Fuma , Shoji Kitanoya , Satoshi Sugaya , Takafumi Oshima
IPC分类号： G01N27/41 , G01N27/12 , G01N27/407 , G01N27/416 , G01N27/419
CPC分类号： G01N27/4074 , G01N27/419
摘要： In accordance with the present invention, there is provided an exhaust gas sensor which comprises an oxygen pump cell made of solid electrolyte having an oxygen ion conductivity, an oxygen sensor cell made of solid electrolyte having an oxygen ion conductivity and disposed in opposition to the pump cell in such a manner as to define therebetween a detection space, and a semiconductor detection element made of oxide semiconductor and disposed in the detection space for detecting a predetermined detected substance in the exhaust gas introduced to the detection space. The concentration of oxygen in the detection space is regulated so as to be included within a predetermined range through control of charge or discharge of oxygen into or from the detection space by means of the oxygen pump cell on the basis of the concentration of oxygen in the exhaust gas, which is detected by the oxygen sensor cell.
摘要翻译：根据本发明，提供了一种废气传感器，其包括由具有氧离子传导性的固体电解质制成的氧气泵电池，由具有氧离子传导性的固体电解质制成的氧传感器电池并且与泵以在其间限定检测空间的方式，以及由氧化物半导体制成的半导体检测元件，并设置在检测空间中，用于检测引入检测空间的排气中的预定检测物质。调节检测空间中的氧浓度以便通过基于氧泵的浓度通过氧泵电池的控制将氧气进入或从检测空间排出来进入到预定范围内废气，其由氧传感器单元检测。

9. 发明授权

US07963145B2 Apparatus and method for detecting combustible gas within atmosphere to be detected 有权
标题翻译：用于检测大气中可燃气体的检测装置和方法
公开(公告)号：US07963145B2
公开(公告)日：2011-06-21
申请号：US12015699
申请日：2008-01-17
申请人： Shogo Hamatani , Shoji Kitanoya , Ryuji Inoue
发明人： Shogo Hamatani , Shoji Kitanoya , Ryuji Inoue
IPC分类号： G01N25/00 , G01N27/18
CPC分类号： G01N27/16
摘要： In apparatus and method for detecting a combustible gas within an atmosphere to be detected, a calculated humidity deviation corresponding to a past gas concentration stored in a memory unit of a microcomputer is calculated on the basis of a correlation between a preset gas concentration of the combustible gas and the calculated humidity deviation, a calculated humidity of the atmosphere to be detected is corrected using the calculated humidity deviation to calculate a corrected humidity, and, when a concentration of the combustible gas is calculated on the basis of a terminal voltage, a temperature of the atmosphere to be detected, and a humidity of the atmosphere to be detected, the calculated corrected humidity is used for the humidity of the atmosphere to be detected calculated on the basis of terminal voltages across first and second heating resistors and the temperature of the detected temperature.
摘要翻译：在检测到的气氛中的可燃气体的检测装置和方法中，根据存储在微型计算机的存储单元中的过去气体浓度的计算出的湿度偏差，根据可燃气体的预设气体浓度气体和计算出的湿度偏差，使用计算出的湿度偏差校正要检测的气氛的计算湿度，以计算校正湿度，并且当基于端电压计算可燃气体的浓度时，要检测的气氛和要检测的气氛的湿度，根据第一和第二加热电阻器上的端子电压计算出的计算出的校正湿度用于要检测的大气的湿度，并且根据检测温度。

10. 发明申请

US20080282771A1 APPARATUS AND METHOD FOR DETECTING COMBUSTIBLE GAS WITHIN ATMOSPHERE TO BE DETECTED 有权
标题翻译：检测大气中可燃气体的装置和方法
公开(公告)号：US20080282771A1
公开(公告)日：2008-11-20
申请号：US12015699
申请日：2008-01-17
申请人： Shogo Hamatani , Shoji Kitanoya , Ryuji Inoue
发明人： Shogo Hamatani , Shoji Kitanoya , Ryuji Inoue
IPC分类号： G01N33/00 , G01N25/00
CPC分类号： G01N27/16
摘要： In apparatus and method for detecting a combustible gas within an atmosphere to be detected, a calculated humidity deviation corresponding to a past gas concentration stored in a memory unit of a microcomputer is calculated on the basis of a correlation between a preset gas concentration of the combustible gas and the calculated humidity deviation, a calculated humidity of the atmosphere to be detected is corrected using the calculated humidity deviation to calculate a corrected humidity, and, when a concentration of the combustible gas is calculated on the basis of a terminal voltage, a temperature of the atmosphere to be detected, and a humidity of the atmosphere to be detected, the calculated corrected humidity is used for the humidity of the atmosphere to be detected calculated on the basis of terminal voltages across first and second heating resistors and the temperature of the detected temperature.
摘要翻译：在检测到的气氛中的可燃气体的检测装置和方法中，根据存储在微型计算机的存储单元中的过去气体浓度的计算出的湿度偏差，根据可燃气体的预设气体浓度气体和计算出的湿度偏差，使用计算出的湿度偏差校正要检测的气氛的计算湿度，以计算校正湿度，并且当基于端电压计算可燃气体的浓度时，要检测的气氛和要检测的气氛的湿度，根据第一和第二加热电阻器上的端子电压计算出的计算出的校正湿度用于要检测的大气的湿度，并且根据检测温度。

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