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    • 7. 发明授权
    • Polymer electrolyte composite for driving an electrolytic capacitor, an electrolytic capacitor using the same, and a method of making the electrolytic capacitor
    • 用于驱动电解电容器的聚合物电解质复合材料,使用该电解电容器的电解电容器以及制造该电解电容器的方法
    • US06765785B2
    • 2004-07-20
    • US10158131
    • 2002-05-31
    • Kazumitsu HondaNario NiiboYuichiro TsubakiJunji Ozaki
    • Kazumitsu HondaNario NiiboYuichiro TsubakiJunji Ozaki
    • H01G902
    • H01G9/025Y10T29/417
    • The polymer electrolyte composite, for driving an electrolytic capacitor, according to the present invention is a composite body including an electrolyte and an acrylic polymer containing a copolymer of acrylic derivative. The electrolyte includes a polar solvent and a solute including at least one of inorganic acids, organic acids and salts of such acids. The copolymer of acrylic derivative is a polymer of: a first monomer of at least one of a group of monofunctional monomers of acrylic derivatives each having at least one hydroxyl group at a terminal thereof and a polymerizable unsaturated double bond; and a second monomer of at least one of a group of multifunctional monomers of acrylic derivatives each having plural polymerizable unsaturated double bonds. The polymer electrolyte composite has a high ionic conductivity at room temperature together with a high heat resistance, and does not react with electrode foils such as aluminum, and moreover is superior in the easiness of manufacturing and long life. The present invention also provides an electrolytic capacitor using the polymer electrolyte composite.
    • 根据本发明的用于驱动电解电容器的聚合物电解质复合材料是包含电解质和含有丙烯酸衍生物的共聚物的丙烯酸类聚合物的复合体。 电解质包括极性溶剂和包含无机酸,有机酸和这些酸的盐中的至少一种的溶质。 丙烯酸衍生物的共聚物是以下的聚合物:第一单体,其至少一种单体的单官能单体的各自在其末端具有至少一个羟基和可聚合的不饱和双键; 和具有多个可聚合不饱和双键的丙烯酸衍生物的一组多官能单体中的至少一种的第二单体。 聚合物电解质复合材料在室温下具有高的离子电导率和高的耐热性,并且不与诸如铝的电极箔反应,而且制造的容易性和长寿命也优异。 本发明还提供一种使用聚合物电解质复合材料的电解电容器。
    • 8. 发明授权
    • Electrolytic capacitor and driving electrolyte thereof
    • 电解电容器及其驱动电解质
    • US06338806B1
    • 2002-01-15
    • US09386456
    • 1999-08-31
    • Nario NiiboKazumitsu Honda
    • Nario NiiboKazumitsu Honda
    • H01G9035
    • H01G9/022
    • Driving electrolytes for electrolytic capacitors of the present invention contain boric acid esters and/or their salts of the structural formulae: Rt—[(R1)1—O—B—(OH)—O]k—H;  (1) Rt—[(R1)1—O—B—(OH)—O—(R2)n]k—Rt; and  (2) In the foregoing formulae, Rt represents CH3 or H ; R1, R2 and R3 represent —CH2O, —C2H4O, —C3H6O, or —C4H8O; and K, l, and m indicate arbitrary natural numbers. Other electrolytes of the present invention further include inorganic acids and/or organic acids and have boric acid esters and/or their salts of the foregoing structural formulae dissolved in the solvent thereof. Using the above-mentioned electrolyte, an electrolytic capacitor which has high withstand voltage of not less than 500V even at the temperatures of 125° C. can be obtained.
    • 本发明的电解电容器的驱动电解液含有硼酸酯和/或其结构式的盐:在上式中,R t表示CH 3或H; R1,R2和R3表示-CH2O,-C2H4O,-C3H6O或-C4H8O; K,l,m表示任意的自然数。 本发明的其他电解质还包括无机酸和/或有机酸,并且具有溶解在其溶剂中的前述结构式的硼酸酯和/或其盐。 使用上述电解质,即使在125℃的温度下也能够获得耐压不低于500V的电解电容器。
    • 10. 发明授权
    • Polymer electrolyte composite for driving an electrolytic capacitor, an electrolytic capacitor using the same, and a method of making the electrolytic capacitor
    • 用于驱动电解电容器的聚合物电解质复合材料,使用该电解电容器的电解电容器以及制造该电解电容器的方法
    • US07004983B2
    • 2006-02-28
    • US10721105
    • 2003-11-26
    • Kazumitsu HondaNario NiiboYuichiro TsubakiJunji Ozaki
    • Kazumitsu HondaNario NiiboYuichiro TsubakiJunji Ozaki
    • H01G9/00B05D5/12
    • H01G9/025Y10T29/417
    • The polymer electrolyte composite, for driving an electrolytic capacitor, according to the present invention is a composite body comprising an electrolyte and an acrylic polymer containing a copolymer of acrylic derivative. The electrolyte comprises a polar solvent and a solute comprising at least one of inorganic acids, organic acids and salts of such acids. The copolymer of acrylic derivative is a polymer of: a first monomer of at least one of a group of monofunctional monomers of acrylic derivatives each having at least one hydroxyl group at a terminal thereof and a polymerizable unsaturated double bond; and a second monomer of at least one of a group of multifunctional monomers of acrylic derivatives each having plural polymerizable unsaturated double bonds.The polymer electrolyte composite has a high ionic conductivity at room temperature together with a high heat resistance, and does not react with electrode foils such as aluminum, and moreover is superior in the easiness of manufacturing and long life. The present invention also provides an electrolytic capacitor using the polymer electrolyte composite.
    • 根据本发明的用于驱动电解电容器的聚合物电解质复合材料是包含电解质和含有丙烯酸衍生物的共聚物的丙烯酸类聚合物的复合体。 电解质包含极性溶剂和包含无机酸,有机酸和这些酸的盐中的至少一种的溶质。 丙烯酸衍生物的共聚物是以下的聚合物:第一单体,其至少一种单体的单官能单体的各自在其末端具有至少一个羟基和可聚合的不饱和双键; 和具有多个可聚合不饱和双键的丙烯酸衍生物的一组多官能单体中的至少一种的第二单体。