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1. 发明授权

US5147845A Triazolopyridine dyes and thermal transfer of methine dyes 失效
标题翻译：三唑并吡啶染料和甲基染料的热转移
公开(公告)号：US5147845A
公开(公告)日：1992-09-15
申请号：US743191
申请日：1991-08-09
申请人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
发明人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
IPC分类号： C09B26/02 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C07D471/04 , C09B23/00 , C09B23/04 , C09B23/16 , C09B53/00 , C09B55/00 , C09B57/00 , D06P5/00 , D06P5/13
CPC分类号： B41M5/3856 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Triazolopyridine dyes useful for thermal transfer of methine dyes have the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl, which may be substituted and interrupted by one or more oxygen atoms, or is substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a 5- or 6-membered carbocyclic or heterocyclic ring which may be substituted and benzofused,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is oxygen or a radical of the formula ##STR2## where L.sup.1 is in each case C.sub.1 -C.sub.8 -alkyl which may be interrupted by 1 or 2 oxygen atoms, andX is CH or nitrogen.

2. 发明授权

US5079365A Triazolopyridine dyes and thermal transfer of methine dyes 失效
标题翻译：三唑并吡啶染料和甲基染料的热转移
公开(公告)号：US5079365A
公开(公告)日：1992-01-07
申请号：US569914
申请日：1990-08-20
申请人： Rudiger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
发明人： Rudiger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
IPC分类号： C09B26/02 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C07D471/04 , C09B23/00 , C09B23/04 , C09B23/16 , C09B53/00 , C09B55/00 , C09B57/00 , D06P5/00 , D06P5/13
CPC分类号： B41M5/3856 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Triazolopyridine dyes useful for thermal transfer of methine dyes have the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl, which may be substituted and interrupted by one or more oxygen atoms, or is substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a 5- or 6-membered carbocyclic or heterocyclic ring which may be substituted and benzofused,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is oxygen or a radical of the formula ##STR2## where L.sup.1 is in each case C.sub.1 -C.sub.6 -alkyl which may be interrupted by 1 or 2 oxygen atoms, andX is CH or nitrogen.
摘要翻译：可用于次甲基染料的热转移的三唑并吡啶染料具有式（I）其中R 1是可以被一个或多个氧原子取代和间隔的C 1 -C 20烷基，或者是取代或未取代的苯基或羟基，R 2 是可以被取代和苯并稠合的5-或6-元碳环或杂环，R 3是氰基，氨基甲酰基，羧基或C 1 -C 4 - 烷氧基羰基，R 4是氧或下式的基团：可能被1或2个氧原子中断的C 1 -C 6 - 烷基，X是CH或氮。

3. 发明授权

US5654122A N-aminopyridone dyes 失效
标题翻译： N-氨基吡啶酮染料
公开(公告)号：US5654122A
公开(公告)日：1997-08-05
申请号：US470480
申请日：1995-06-06
申请人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
发明人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C07B57/00 , C07D213/89 , C07D265/36 , C09B23/00 , C09B23/02 , C09B23/04 , C09B53/00 , C09B55/00 , C09B57/00 , C07D215/38 , C07D277/38
CPC分类号： B41M5/3856 , C09B23/02 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39
摘要： Pyridone dyes useful for thermal transfer have the formula ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 - alkyl,R.sup.2 and R.sup.3 are identical or different and each is, independently of the other, hydrogen, substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted pyridyl, substituted or unsubstituted C.sub.1 -C.sub.12 -alkanoyl, C.sub.1 -C.sub.12 -alkoxycarbonyl, substituted or unsubstituted C.sub.1 -C.sub.12 -alkylsulfonyl, C.sub.5 -C.sub.7 -cycloalkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted pyridylsulfonyl, substituted or unsubstituted benzoyl, pyridylcarbonyl or thienylcarbonyl or are together with the nitrogen atom to which they are bonded unsubstituted or C.sub.1 -C.sub.4 - alkyl-substituted succinimido, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted phthalimido or a five- or six-membered saturated heterocyclic radical which may contain further hetero atoms,X is CH or nitrogen,Y is cyano or a radical of the formula CO--W, CO--OW or CO--NHW where W is hydrogen, C.sub.1 -C.sub.8 -alkyl which may be substituted and which may be interrupted by one or two oxygen atoms in ether function, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or tolyl, andZ is an aromatic carbocyclic or heterocyclic radical.
摘要翻译：可用于热转移的吡啶酮染料具有式（I）其中R 1是氢或C 1 -C 4 - 烷基，R 2和R 3相同或不同，并且各自独立地是氢，取代或未取代的C 1 -C 12 - 烷基，C 5 -C 7 - 环烷基，取代或未取代的苯基，取代或未取代的吡啶基，取代或未取代的C 1 -C 12烷酰基，C 1 -C 12烷氧基羰基，取代或未取代的C 1 -C 12烷基磺酰基，C 5 -C 7环烷基磺酰基，未取代的苯基磺酰基，取代或未取代的吡啶基磺酰基，取代或未取代的苯甲酰基，吡啶基羰基或噻吩基羰基，或与它们所键合的氮原子一起未取代或C 1 -C 4烷基取代的琥珀酰亚胺基，未取代的或C 1 -C 4烷基取代的苯二甲酰亚氨基或可以含有其它杂原子的五元或六元饱和杂环基，X是CH或氮，Y是氰基或式CO-W，CO-OW或CO-NHW的基团，其中 W是氢，可以被取代的C1-C8-烷基，其可以被醚官能团中的一个或两个氧原子中断，C 5 -C 7环烷基，苯基或甲苯基，Z是芳族碳环或杂环基。

4. 发明授权

US5580980A N-aminopyridone dyes 失效
标题翻译： N-氨基吡啶酮染料
公开(公告)号：US5580980A
公开(公告)日：1996-12-03
申请号：US140021
申请日：1993-11-01
申请人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
发明人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C07B57/00 , C07D213/89 , C07D265/36 , C09B23/00 , C09B23/02 , C09B23/04 , C09B53/00 , C09B55/00 , C09B57/00 , C07D215/38 , C07D277/38
CPC分类号： B41M5/3856 , C09B23/02 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39
摘要： Pyridone dyes useful for thermal transfer have the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, Y, X and Z are defined in the specification.
摘要翻译： PCT No.PCT / EP92 / 00505 Sec。 371日期：1993年11月1日 102（e）1993年11月1日PCT PCT。出版物WO92 / 19684 日期：1992年11月12日可用于热转移的吡啶酮染料具有式（I）其中R1，R2，R3，Y，X和Z在本说明书中定义。

5. 发明授权

US5612465A Phenylazotriazolopyridine dyestuffs 失效
标题翻译：苯偶氮三唑并吡啶染料
公开(公告)号：US5612465A
公开(公告)日：1997-03-18
申请号：US592310
申请日：1996-02-12
申请人： Ernst Schefczik , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Clemens Grund
发明人： Ernst Schefczik , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Clemens Grund
IPC分类号： B41M5/388 , C07D471/04 , C09B29/36 , C09B29/42 , D06P1/18
CPC分类号： B41M5/388 , C07D471/04 , C09B29/3617
摘要： Azo dyestuffs of the formula ##STR1## where R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.20 -alkyl, unsubstituted or substituted phenyl, or unsubstituted or substituted mercapto,R.sup.2 is hydroxyl or mercapto andD is the radical of a diazo component which is selected from the group consisting of the radicals of the formulae ##STR2## where L.sup.1 is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, one of the two radicals L.sup.2 and L.sup.3 is hydrogen and the other is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, L.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl, L.sup.5 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio and L.sup.6 is unsubstituted or substituted C.sub.8 -C.sub.13 -alkyl or phenoxy,their use for dyeing or printing textile materials and novel mercaptotriazolopyridines are described.
摘要翻译： PCT No.PCT / EP94 / 02634。 371日期：1996年2月12日 102（e）日期1996年2月12日PCT 1994年8月9日PCT公布。公开号WO95 / 05420 日期2月23日，1995年2月23日的偶氮染料，其中R1是未取代或取代的C1-C20烷基，未取代或取代的苯基，或未取代或取代的巯基，R2是羟基或巯基，D是重氮组分的基团其选自由式为“IMAGE”的基团，其中L 1为C 1 -C 4 - 烷基，未取代或取代的C 1 -C 4 - 烷氧基或未取代或取代的氨基，两个基团L2和L3之一为氢，另一个是C 1 -C 4 - 烷基，未取代或取代的C 1 -C 4 - 烷氧基或未取代或取代的氨基，L 4是氢或C 1 -C 4 - 烷基，L 5是未取代的或取代的C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基， L6是未取代的或取代的C 8 -C 13 - 烷基或苯氧基，它们用于染色或印刷纺织材料和新型巯基三唑并吡啶类的用途。

6. 发明授权

US4994564A Azo dyes with a diazo component of the 3-amino thiophene series and a coupling component of the pyridine, pyridone or pyrazole series 失效
标题翻译：具有3-氨基噻吩系列的重氮组分的偶氮染料和吡啶，吡啶酮或吡唑系的偶联组分
公开(公告)号：US4994564A
公开(公告)日：1991-02-19
申请号：US269646
申请日：1988-11-10
申请人： Karl-Heinz Etzbach , Helmut Reichelt , Guenter Hansen , Ernst Schefczik , Helmut Hagen , Gunther Lamm
发明人： Karl-Heinz Etzbach , Helmut Reichelt , Guenter Hansen , Ernst Schefczik , Helmut Hagen , Gunther Lamm
IPC分类号： C09B29/09 , C09B29/00 , C09B29/42 , C09B29/48
CPC分类号： C09B29/0059 , C09B29/3621 , C09B29/3634 , C09B29/3656
摘要： Thien-3-ylazo dyes of the formula: ##STR1## where X is cyano, nitro, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are identical or different and each is independently of each other substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl, substituted or unsubstituted phenyl or together with the nitrogen atom linking them a 5- or 6-membered saturated heterocyclic radical, and R.sup.2 may additionally be hydrogen, Y is hydrogen, cyano, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are each as defined above, Z is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylthio, substituted or unsubstituted phenylthio, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylsulfonyl or phenylsulfonyl or together with the radical Y a fused benzo ring which may be substituted, and K is the radical of a coupling component of the 2,6-diaminopyridine, 6-hydroxypyrid-2-one or 5-aminopyrazole series, are used for dyeing synthetic fiber materials, in particular synthetic polyesters, in yellow to red shades and are notable for good light fastness, fastness to dry heat setting and pleating and for good affinity.
摘要翻译：噻吩-3-基偶氮染料，其结构式如下：其中X为氰基，硝基，C 1 -C 6烷酰基，取代或未取代的苯甲酰基，取代或未取代的苯基或基团COOR1或CONR1R2，其中R 1和R 2相同或不同，各自独立地为取代或未取代的C 1 -C 8 - 烷基，C 5 -C 7 - 环烷基，C 3 -C 4 - 烯基，取代或未取代的苯基或与连接它们的氮原子一起形成5-或6-元饱和杂环基， R 2可另外为氢，Y为氢，氰基，C 1 -C 6烷酰基，取代或未取代的苯甲酰基，C 1 -C 4 - 烷基磺酰基，取代或未取代的苯基磺酰基，取代或未取代的苯基或基团COOR1或CONR1R2，其中R1和R2为 Z是氢，取代或未取代的C 1 -C 8 - 烷基，取代或未取代的苯基，取代或未取代的C 1 -C 6 - 烷硫基，取代或未取代的苯硫基，取代或未取代的C 1 -C 6 - 烷基磺酰基或与苯基磺酰基或与基团Y一起可以被取代的稠合苯并环，K是2,6-二氨基吡啶，6-羟基吡啶-2-酮或5-氨基吡唑系列的偶联组分的基团用于将合成纤维材料，特别是合成聚酯染色为黄色至红色，并且具有良好的耐光性，耐干燥定型和打褶的牢度以及良好的亲和力。

7. 发明授权

US5283326A Dyes containing thiophene radicals 失效
标题翻译：染料含有噻吩基
公开(公告)号：US5283326A
公开(公告)日：1994-02-01
申请号：US884472
申请日：1992-05-13
申请人： Guenter Hansen , Ernst Schefczik , Karl-Heinz Etzbach , Helmut Reichelt , Hermann Loeffler
发明人： Guenter Hansen , Ernst Schefczik , Karl-Heinz Etzbach , Helmut Reichelt , Hermann Loeffler
IPC分类号： C09B29/00 , C09B29/033 , C09B29/06 , C09B29/36 , D06P1/18
CPC分类号： C09B29/0059
摘要： The compounds of the general formula ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are very useful for dyeing synthetic fibers or plastics.
摘要翻译：其中X为氟，氯，溴，SO 2 E或未取代或取代的羟基或巯基的通式为“IMAGE”的化合物，E为烷基，烯基，环烷基，芳烷基，芳基，氯或未取代或取代的羟基或氨基，Y为氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C 1 -C 4烷基，可以通过亲电取代引入的基团或式 - CH = B，其中B是亚甲基活性化合物或胺的基团，K是偶合组分的基团，对于合成纤维或塑料的染色非常有用。

8. 发明授权

US4837269A 2-aminothiophene radical substituted by an electron withdrawing group 失效
标题翻译：由吸电子基团取代的2-氨基噻吩基团
公开(公告)号：US4837269A
公开(公告)日：1989-06-06
申请号：US68168
申请日：1987-06-30
申请人： Karl-Heinz Etzbach , Guenter Hansen , Ernst Schefczik , Helmut Reichelt
发明人： Karl-Heinz Etzbach , Guenter Hansen , Ernst Schefczik , Helmut Reichelt
IPC分类号： C09B31/02 , C09B31/04 , C09B31/14
CPC分类号： C09B31/04 , C09B31/14
摘要： Disazothiphene dyes of the formula ##STR1## where X is an electron withdrawing group, Z is an electron withdrawing group, D is the radical of a diazo component and K is the radical of a coupling component, are highly suitable for dyeing synthetic fibers, in particular polyesters.
摘要翻译：其中X是吸电子基团，Z是吸电子基团，D是重氮组分的基团，K是偶合组分的基团，非常适合于染色合成纤维，其中X是吸电子基团，特定的聚酯。

9. 发明授权

US5616710A Triazolopyridine dyes 失效
标题翻译：三唑并吡啶染料
公开(公告)号：US5616710A
公开(公告)日：1997-04-01
申请号：US687453
申请日：1996-08-19
申请人： Rudiger Sens , Ernst Schefczik , Helmut Reichelt , Karl-Heinz Etzbach
发明人： Rudiger Sens , Ernst Schefczik , Helmut Reichelt , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/30 , B41M5/388 , B41M5/39 , C07D471/04 , C07D487/04 , C09B23/00 , C09B23/04 , C09B23/10 , C09B55/00 , C09B57/00 , D06P5/13 , B41M5/38
CPC分类号： B41M5/3856 , C09B23/04 , C09B23/105 , C09B55/009 , B41M5/3854 , B41M5/39 , Y10S430/165
摘要： Triazolopyridine dyes of the formula ##STR1## where one of the two radicals A and E is nitrogen and the other is a radical of the formula C-R.sup.1, where R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.20 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted mercapto,Q is a radical of the formula ##STR2## where R.sup.2 is a carbocyclic or heterocyclic radical,R.sup.3 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or unsubstituted or substituted phenyl,R.sup.4 is cyano, carbamoyl, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or benzothiazolyl or R.sup.3 and R.sup.4 together are the remainder of a fused-on benzene ring andX is CH or nitrogen, andR.sup.5 is oxygen or a radical of a compound with an acidic CH, and a process for the thermal transfer of these dyes.
摘要翻译： PCT No.PCT / EP95 / 00564 Sec。 371日期：1996年8月19日 102（e）日期1996年8月19日PCT提交1995年2月15日PCT公布。第WO95 / 22581号公报日期1995年8月24日具有式（IMAGE）的三唑并吡啶染料，其中两个基团A和E中的一个是氮，另一个是式C-R 1的基团，其中R 1是未取代的或取代的C 1 -C 20 - 烷基，或取代的苯基或未取代的或取代的巯基，Q是下式的基团，其中R 2是碳环或杂环基，R 3是未取代的或取代的C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基羰基或未取代的或未取代的取代的苯基，R 4是氰基，氨基甲酰基，羧基，C 1 -C 4 - 烷氧基羰基或苯并噻唑基，或者R 3和R 4一起是稠合的苯环的其余部分，X是CH或氮，R 5是氧或化合物具有酸性CH，以及这些染料的热转移过程。

10. 发明授权

US5270456A Azo dyes with A2-aminothiophene dye azo component and a coupling component and coupling component of the diphenylamine series 失效
标题翻译：偶氮染料与A 2-氨基噻吩染料偶氮组分和偶联组分和二苯胺系列的偶联组分
公开(公告)号：US5270456A
公开(公告)日：1993-12-14
申请号：US727881
申请日：1991-07-10
申请人： Erwin Hahn , Guenter Hansen , Karl-Heinz Etzbach , Helmut Reichelt , Ernst Schefczik , Sabine Greuttner , Helmut Degen
发明人： Erwin Hahn , Guenter Hansen , Karl-Heinz Etzbach , Helmut Reichelt , Ernst Schefczik , Sabine Greuttner , Helmut Degen
IPC分类号： C09B29/09 , C09B29/00 , C09B29/08 , C09B43/32 , C09B43/40 , C09B29/033 , D06P1/18 , D06P3/54
CPC分类号： C09B29/081 , C09B29/0059 , C09B29/0811 , C09B43/325 , C09B43/40 , Y10S8/922
摘要： Thiopheneazo dye I which are chiefly useful as disperse dyes for dyeing textile material, in particular polyesters, have the formula ##STR1## where the substituents are as defined in the description.
摘要翻译：主要用作染色纺织材料，特别是聚酯的分散染料的噻吩偶氮染料I具有式（I），其中取代基如说明书中所定义。

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