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    • 4. 发明授权
    • Use of salts of layered double hydroxides as charge control agents
    • 使用分层双氢氧化物的盐作为电荷控制剂
    • US07611812B2
    • 2009-11-03
    • US10523536
    • 2003-07-09
    • Eduard MichelRuediger BaurHans-Tobias Macholdt
    • Eduard MichelRuediger BaurHans-Tobias Macholdt
    • G03G9/08
    • C08K5/098C01F7/005C01P2002/22C01P2002/88C01P2004/51C01P2004/61C01P2006/12C01P2006/40C08K5/0091C08K5/41C09C1/40C09C1/407C09D5/034G03G9/09708G03G9/09716
    • Layered double hydroxide salts as charge control agents in electrophotographic toners and developers, in powder coating materials, electret materials and in electrostatic separation processes of chargeable materials, such as polymers, wherein the double hydroxide salt contains monovalent and/or divalent, and also trivalent, metal cations, and also contains one or more organic anions A of the formula (I) X—R—Y  (1) wherein X is hydroxyl, carboxyl, sulfato or sulfo; Y is carboxyl, sulfato or sulfo, and R is an aliphatic, cycloaliphatic, heterocycloaliphatic, olefinic, cycloolefinic. heterocycloolefinic, aromatic, heteroaromatic, araliphatic or heteroaraliphatic radical having a total of at least 8 carbon atoms which can be substituted by one or several substituents from the group hydroxyl, amino, halogen, C1-C22-alkyl, C1-C22-alkoxy, —C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-alkyl,—C1-C22-alkylene-(CO)—O—(CH2H2O)0-50-haloalkyl, carboxy, sulfo, nitro or cyano.
    • 分层双氢氧化物盐作为电子照相调色剂和显影剂中的电荷控制剂,粉末涂料,驻极体材料和可带电材料如聚合物的静电分离方法,其中双氢氧化物盐含有一价和/或二价,以及三价, 金属阳离子,还含有一种或多种式(I)XRY(1)的有机阴离子A,其中X是羟基,羧基,硫酸根或磺基; Y是羧基,硫酸根或磺基,R是脂族,脂环族,杂脂族,烯烃,环烯烃。 具有总共至少8个碳原子的杂环烯烃,芳族,杂芳族,芳脂族或杂脂族基团,其可以被羟基,氨基,卤素,C 1 -C 22 - 烷基,C 1 -C 22 - 烷氧基 - , - C 1 -C 22 - 亚烷基 - (CO)-O-(CH 2 CH 2 O)0-50-烷基,-C 1 -C 22 - 亚烷基 - (CO)-O-(CH 2 H 2 O)0-50-卤代烷基,羧基,磺基,硝基或氰基 。