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    • 1. 发明授权
      US06180637B2 1,2,5-trisubstituted 1,2-dihydroindazol-3-ones having anti-asthmatic, anti-allergic, anti-inflammatory, immunomodulating and neuroprotective action, process for their preparation and their use as medicaments 失效
    • 1,2,5-trisubstituted 1,2-dihydroindazol-3-ones having anti-asthmatic, anti-allergic, anti-inflammatory, immunomodulating and neuroprotective action, process for their preparation and their use as medicaments
    • US06180637B2
    • 2001-01-30
    • US09305602
    • 1999-05-05
    • Rudolf Schindler , Norbert Höfgen , Hildegard Poppe , Kay Brune
    • Rudolf Schindler , Norbert Höfgen , Hildegard Poppe , Kay Brune
    • A61K31513
    • C07D231/56 , C07D403/06 , C07D417/06
    • The invention relates to 1,2,5-trisubstituted 1,2-dihydroindazol-3-ones of formula (I) wherein X is —SO2—, —SO—, —(CH2)p—, —(CH2)p—O—, —(CH2)p—(C═O)—, —(CH2)p—(C═O)—NH—, —(CH2)p—CHOH—, —CHOH—(CH2)p—, —(CH2)p—CH═CH—, —CH═CH—(CH2)p—, Y is —(C═O)—, —(C═O)—NH—, —(C═O)—NH—(CH2)p—, —C═O)—(CH2)p—, —(CH2)p—, —(CH2)p—O—, —(CH2)p—(C═O)—, —(CH2)p—(C═O)—NH—, —(CH2)p—(C═O)—NH—(CH2)p—, —(CH2)p—CHOH—, —CHOH—(CH2)p—, —(CH2)p—CH═CH—, —CH═CH—(CH2)p—, Z is —O—, —O—(CH2)p—, —NH—, —NH—(C═O)—, —NH—(C═O)—NH—, —NH—(C═O)—O—, —NH—CH2—(C═O)— and —NH—(C═O)—CH2—, P is a cardinal number from 1 to 4, R1, R2 and R3 can be the same or different and are: mono-, bi- or tricyclic saturated or mono- or polyunsaturated carbocycles having from 5 to 14 ring members; or mono-, bi- or tricyclic saturated or mono- or polyunsaturated heterocycles having from 5 to 15 ring members and from 1 to 6 heteroatoms, in which the carbocycles and the heterocycles can be mono- or polysubstituted by: C1-6-alkyl, —O—C1-6-alkyl, —O—C3-7-cycloalkyl, mono-, bi- or tricyclic saturated or mono- or polyunsaturated carbocycles having from 3 to 14 ring members, mono-, bi- or tricyclic saturated or mono- or polyunsaturated heterocycles having from 5 to 15 ring members and from 1 to 6 heteroatoms, R1 is also H, provided that when X is CH2, then R1 is not H, R3—Z is also NO2, and their pharmaceutically acceptable salts, but excluding compounds of formula (I) in which if Z is —NH—(C═O)—, —NH—(C═O)—NH—, —NH—(C═O)—O—, —NH—(C═O)—CH2 and at the same time R1 is phenyl, monosubstituted or polysubstituted by —COOH, —COOC1-6-alkyl, —(CH2)p—COOH, —(CH2)p—COOC1-6-alkyl —CONHC1-6-alkyl, —CONHC6-14-aryl, —CONHSO2C1-6-alkyl, —CONHSO2C6-4-aryl, 1H-tetrazol-5-yl, then R2 is not phenyl, monosubstituted or polysubstituted by CN, halogen, C1-4-alkyl, C1-4-alkyloxy, CF3; and if R3—Z is NO2, then R1—X is not benzyl or 4-methoxybenzyl, and R2—Y is not benzyl or 2-picolyl at the same time; and to pharmaceutical treatment processes, and processes for making.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 10. 发明授权
      US4190996A Corners of structural members 失效
    • Corners of structural members
    • 结构构件的角落
    • US4190996A
    • 1980-03-04
    • US860180
    • 1977-12-13
    • Rudolf Schindler , Werner Hartmann
    • Rudolf Schindler , Werner Hartmann
    • B32B1/04 , B29C70/00 , B32B5/00 , B64C1/06 , B65D59/00 , E04C2/22
    • B64C1/06 , B29C70/00 , B29K2309/08 , B64C2001/0072 , Y02T50/433 , Y10S428/902 , Y10T428/24124
    • The corner of a structural member has first, second, third and fourth surfaces which converge to form the corner with first, second and third layers of fiber reinforced material successively applied to the corner surfaces to form the walls of the corner. The first layer of fiber reinforced material completely covers the first and second surfaces and partially covers the third and fourth surfaces. The second layer completely covers the second and fourth surfaces and that part of the third surface which remained uncovered by the first layer, and the third layer completely covers the first and third surfaces and that part of the fourth surface which remained uncovered by the first layer. The three layers arranged in this manner therefore produces corner walls having a thickness corresponding to two of the layers. The fibers in the two layers forming the walls extend in directions transverse to each other and form patterns different from each other.
    • 结构件的角部具有第一，第二，第三和第四表面，该第一表面，第二表面，第三表面和第四表面会聚成角部，其中第一，第二和第三层纤维增强材料连续地施加到角部表面以形成角部的壁。 第一层纤维增强材料完全覆盖第一和第二表面，并部分覆盖第三和第四表面。 第二层完全覆盖第二表面和第四表面以及第三表面的未被第一层覆盖的部分，第三层完全覆盖第一和第三表面，并且第四表面的第一表面的未被第一层覆盖的部分 。 因此，以这种方式布置的三层产生具有对应于两层的厚度的角壁。 形成壁的两层中的纤维沿彼此横向的方向延伸并形成彼此不同的图案。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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