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    • 5. 发明授权
    • Laminating method and products made thereby
    • 由此形成的层压方法和产品
    • US5455074A
    • 1995-10-03
    • US997799
    • 1992-12-29
    • Ronald S. NohrJohn G. MacDonald
    • Ronald S. NohrJohn G. MacDonald
    • B32B5/18B32B7/12B32B27/08B32B27/12B32B27/28B32B37/00B32B37/16C09J163/00B05D3/00B32B27/00
    • B32B37/12B29K2201/00B29K2223/00B32B2305/20B32B2310/0831B32B2310/0843B32B2327/06B32B2329/00B32B2363/00B32B37/1284Y10S428/934Y10T428/19Y10T428/192Y10T428/24041Y10T428/31504Y10T428/31573Y10T442/66Y10T442/668
    • A method of preparing a laminate having increased peel strength and solvent resistance which involves (A) applying an adhesive composition to a surface of a first sheet; (B) exposing the adhesive composition on the surface of the first sheet to incoherent, pulsed ultraviolet radiation from a dielectric barrier discharge excimer lamp; (C) bringing a surface of a second sheet in contact with the adhesive composition-bearing surface of the first article; and (D) allowing the adhesive composition to cure. The incoherent, pulsed ultraviolet radiation has a single narrow wavelength band within the range of from about 260 to about 360 nanometers. The adhesive composition includes from about 94 to about 60 percent by weight of a cycloaliphatic diepoxide, from about 1 to about 10 percent by weight of a cationic photoinitiator, and from about 5 to about 30 percent by weight of a vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, all based on the weight of adhesive composition. The sheets desirably are films and nonwoven webs composed of cellulosic fibers, polyolefin fibers, or a mixture of cellulosic fibers and polyolefin fibers. The method is particularly well suited for the preparation of such laminates as industrial wipers, workwear, medical fabrics, and the like.
    • 一种制备具有增加的剥离强度和耐溶剂性的层压体的方法,其包括(A)将粘合剂组合物施加到第一片的表面; (B)将第一片表面上的粘合剂组合物暴露于来自介电阻挡放电准分子灯的非相干的脉冲紫外线辐射; (C)使第二片材的表面与第一制品的粘合剂组合物承载表面接触; 和(D)使粘合剂组合物固化。 非相干脉冲紫外线辐射具有在约260至约360纳米范围内的单个窄波长带。 粘合剂组合物包含约94至约60重量%的脂环族二环氧化物,约1至约10重量%的阳离子光引发剂和约5至约30重量%的氯乙烯 - 乙酸乙烯酯 - 乙烯醇三元共聚物,均基于粘合剂组合物的重量。 片材期望地是由纤维素纤维,聚烯烃纤维或纤维素纤维和聚烯烃纤维的混合物组成的膜和非织造纤维网。 该方法特别适用于制备诸如工业擦拭器,工作服,医用织物等的这样的层压材料。
    • 8. 发明授权
    • Thermoplastic compositions and nonwoven webs prepared therefrom
    • 热塑性组合物和由其制备的非织造网
    • US5344862A
    • 1994-09-06
    • US783438
    • 1991-10-25
    • Ronald S. NohrJohn G. MacDonald
    • Ronald S. NohrJohn G. MacDonald
    • C08K3/34C08K3/36C08K5/5419C08L23/02C08L23/12C08L87/00D01D5/08D01F6/30D01F6/46D04H1/54C08K5/54
    • C08L23/12C08K3/36C08K5/5419D04H1/544C08L83/04Y10T156/1023
    • A melt-extrudable thermoplastic composition is provided which includes a thermoplastic polyolefin and an additive system made up of a first component and a second component, in which (A) the first component is a defined polysiloxane polyether having a molecular weight of from about 350 to about 18,000 and which is present in an amount of from about 0.1 to about 3 percent by weight, based on the amount of thermoplastic polyolefin; and (B) the second component is a hydrophobic fumed silica, in which the weight ratio of the first component to the second component is in the range of from about 20 to about 300. Such composition yields, upon melt-extrusion, either nonwoven webs having significantly increased tensile strengths when compared to nonwoven webs prepared from the thermoplastic polyolefin alone, or wettable webs requiring an amount of first component which is significantly less than that required in the absence of the second component.
    • 提供了一种可熔融挤出的热塑性组合物,其包括热塑性聚烯烃和由第一组分和第二组分组成的添加剂体系,其中(A)第一组分是限定的聚硅氧烷聚醚,其分子量为约350至 约18,000,其以基于热塑性聚烯烃的量计约0.1至约3重量%的量存在; 和(B)第二组分是疏水性热解二氧化硅,其中第一组分与第二组分的重量比在约20至约300的范围内。这种组合物在熔融挤出时产生无纺织物 与由单独的热塑性聚烯烃制备的非织造纤维网相比,具有显着增加的拉伸强度,或者可湿性纤维网需要显着小于在不存在第二组分时所需的第一组分的量。
    • 10. 发明授权
    • Stabilization of polyolefin nonwoven webs against actinic radiation
    • 聚烯烃非织造纤维网对光化辐射的稳定化
    • US5244947A
    • 1993-09-14
    • US815688
    • 1991-12-31
    • Ronald S. NohrJohn G. MacDonald
    • Ronald S. NohrJohn G. MacDonald
    • D01D5/098D01F1/10D01F6/04D04H1/42
    • D01F6/04D01D5/0985D01F1/10D04H1/4291Y10T442/637Y10T442/696
    • A method of stabilizing a polyolefin nonwoven web against actinic radiation which involves the steps of (a) melting a mixture of a thermoplastic polyolefin, a first additive, and a second additive; (b) forming fibers by extruding the resulting melt through a die at a shear rate of from about 50 to about 30,000 sec.sup.-1 and a throughput of no more than about 5.4 kg/cm/hour; (c) drawing the fibers; and (d) collecting the fibers on a moving foraminous surface as a web of entangled fibers. The first additive is a benzotriazolyl-containing polydialkylsiloxane having a molecular weight in the range of from about 500 to about 1,400 and a polydispersity of from about 1.3 to about 2.5. The second additive is a polyalkylpiperidyl-containing polydialkylsiloxane having a molecular weight in the range of from about 1,500 to about 30,400 and a polydispersity of from about 1.3 to about 3.0.
    • 一种使聚烯烃非织造纤维网抵抗光化辐射的方法,该方法涉及以下步骤:(a)熔化热塑性聚烯烃,第一添加剂和第二添加剂的混合物; (b)通过在约50至约30,000秒-1的剪切速率下将所得熔体挤压通过模头并且产量不超过约5.4kg / cm 2 /小时来形成纤维; (c)拉丝纤维; 和(d)将纤维收集在移动的多孔表面上作为缠结纤维网。 第一种添加剂是分子量为约500至约1400,多分散性为约1.3至约2.5的含苯并三唑基的聚二烷基硅氧烷。 第二种添加剂是分子量在约1500至约30,400范围内,多分散性为约1.3至约3.0的含聚烷基哌啶基的聚二烷基硅氧烷。