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    • 1. 发明申请
    • POLYESTER-POLACRYLATE DISPERSIONS FOR TWO-COMPONENT COATING COMPOSITIONS
    • 用于两种组分涂料组合物的聚酯 - 聚丙烯酸酯分散体
    • US20080214721A1
    • 2008-09-04
    • US12040972
    • 2008-03-03
    • Rolf GertzmannMartin MelchiorsSandra Hackbarth
    • Rolf GertzmannMartin MelchiorsSandra Hackbarth
    • C08L67/02
    • C09D175/04
    • The invention relates to aqueous polyester-polyacrylate dispersions based on copolymers, to a process for their preparation, and to aqueous coating compositions based thereon and the use thereof as lacquers. The dispersions are prepared from a polyester component A) that comprises the reaction product of A1) one or more saturated, aliphatic and/or aromatic di-, tri- or tetra-carboxylic acids or their anhydrides, and A2)one ore more diols and/or polyols, and a polyacrylate component B) that comprises the reaction product of B1) one or more OH-group-free (meth)acrylic acid esters and/or vinyl aromatic compounds, B2) one or more hydroxy-functional vinyl monomers or hydroxy-functional (meth)acrylic acid esters, and B3) one or more acid-group-containing monomers capable of free-radical copolymerisation, herein te polyester component A) has a hydroxyl number of from 180 to 300 mg KOH/g substance and an acid number of from 0.5 to 30 mg KOH/g, and the polyacrylate component B) has a hydroxyl number of from 10 to 180 mg KOH/g and an acid number of from 10 to 100 mg KOH/g, and the copolymer has an OH number smaller than that of the polyester component A) and greater than 27 mg KOH/g.
    • 本发明涉及基于共聚物的水性聚酯 - 聚丙烯酸酯分散体,其制备方法以及基于其的水性涂料组合物及其作为漆的用途。 分散体由包含A1)一种或多种饱和,脂族和/或芳族二 - ,三 - 或四 - 羧酸或其酸酐的反应产物的聚酯组分A)制备,和A2)一个或多个二醇和 /或多元醇,和聚丙烯酸酯组分B),其包含B1)一种或多种不含羟基的(甲基)丙烯酸酯和/或乙烯基芳族化合物的反应产物,B2)一种或多种羟基官能的乙烯基单体或 羟基官能(甲基)丙烯酸酯和B3)一种或多种能够自由基共聚的含酸基的单体,此处聚酯组分A)具有180至300mg KOH / g物质的羟值, 酸值为0.5至30mg KOH / g,聚丙烯酸酯组分B)的羟值为10至180mg KOH / g,酸值为10至100mg KOH / g,并且共聚物具有 OH数小于聚酯组分A)和大于27mg KOH / g。
    • 2. 发明申请
    • Polyester-polyacrylate dispersions with reactive diluents based on compounds containing lactone groups
    • 聚酯 - 聚丙烯酸酯分散体与基于含内酯化合物的反应性稀释剂
    • US20060100332A1
    • 2006-05-11
    • US11270218
    • 2005-11-09
    • Rolf GertzmannHeinz-Dietmar GewissThomas MunzmayMartin Melchiors
    • Rolf GertzmannHeinz-Dietmar GewissThomas MunzmayMartin Melchiors
    • C08K5/05
    • C08J3/03C08J2367/00C08L33/08C08L33/10C08L67/00C08L67/04C09D167/00C08L2666/02C08L2666/18
    • The present invention related to a process for preparing aqueous polyester-polyacrylate dispersions having a cosolvent content of 0 to 5% by weight, based on the weight of the dispersion, by preparing a polymer P) in a first step by polymerizing A) a mixture of vinyl monomers that are capable of free-radical copolymerization, in the presence of B) one or more oligoesters prepared from compounds containing lactone groups and having a hydroxyl number of 145 to 710 mg KOH/g, an acid number of ≦0.5 mg KOH/g solids and an average OH functionality of 2.5 to 5 mg KOH/g solids, and then mixing polymer P) in a second step with C) one or more polyester polyols having a hydroxyl number of 10 to 500 mg KOH/g solids and an acid number of >0.5 to ≦30 mg KOH/g solids and dispersing the resulting polymer mixture in water in a further step, before or after addition of a neutralizing agent. The present invention also relates to the aqueous polyester-polyacrylate polymer dispersions obtained in accordance with the process of the invention and to aqueous coating compositions containing the aqueous polyester-polyacrylate polymer dispersions of the invention.
    • 本发明涉及通过聚合A)混合物在第一步中制备共聚物含量为0-5重量%,基于分散体重量的聚酯 - 聚丙烯酸酯分散体的方法,通过制备聚合物P) 的乙烯基单体在B存在下存在下进行自由基共聚的乙烯基单体:一种或多种由含有内酯基团并且羟值为145至710mg KOH / g的化合物制备的低聚酯,酸值<= 0.5mg KOH / g固体,平均OH官能度为2.5至5mg KOH / g固体,然后在第二步中混合聚合物P)和C)一种或多种羟基数为10至500mg KOH / g固体的聚酯多元醇 并且酸值> 0.5至<= 30mg KOH / g固体,并且在加入中和剂之前或之后将所得聚合物混合物进一步分散在水中。 本发明还涉及根据本发明的方法获得的聚酯 - 聚丙烯酸酯聚合物水分散体和含有本发明的聚酯 - 聚丙烯酸酯聚合物水分散体的水性涂料组合物。
    • 6. 发明申请
    • Polyester-polyacrylate dispersions with reactive diluents based on hydroxy-functional esters
    • 具有基于羟基官能酯的反应性稀释剂的聚酯 - 聚丙烯酸酯分散体
    • US20060100348A1
    • 2006-05-11
    • US11270234
    • 2005-11-09
    • Rolf GertzmannHeinz-Dietmar GewissThomas MunzmayMartin Melchiors
    • Rolf GertzmannHeinz-Dietmar GewissThomas MunzmayMartin Melchiors
    • C09B67/00
    • C08J3/03C08J2367/00C08K5/11C08L33/08C08L33/10C08L67/00C08L2201/50C09D167/00C08L2666/04
    • The present invention relates to a process for preparing aqueous, hydroxy-functional polyester-polyacrylate dispersions having a cosolvent content of 0 to 5% by weight, based on the weight of the dispersion, by preparing a polymer P) in a first step by polymerizing A) a mixture of vinyl monomers that are capable of free-radical copolymerization, in the presence of B) one or more compound(s) of formula (I) wherein R1 is an aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms, R2 is H or CH3, R3 and R4 are identical or different aliphatic radicals having 1 to 7 carbon atoms, and n is 1 to 4, and then mixing polymer P) in a second step with C) one or more polyester polyols having a hydroxyl number of 10 to 500 mg KOH/g solids and an acid number of >0.5 to ≦30 mg KOH/g solids, and dispersing the resulting polymer mixture in water in a further step, before or after addition of a neutralizing agent. The present invention also relates to the aqueous polyester-polyacrylate polymer dispersions obtained in accordance with the process of the invention and to aqueous coating compositions containing the aqueous polyester-polyacrylate polymer dispersions of the invention.
    • 本发明涉及一种通过在第一步骤中通过聚合制备聚合物P而制备基于分散体重量的共溶剂含量为0-5重量%的水性羟基官能聚酯 - 聚丙烯酸酯分散体的方法 A)在B)一种或多种式(I)化合物的存在下能够进行自由基共聚的乙烯基单体的混合物,其中R 1是脂族,芳脂族或 具有1至18个碳原子的芳族基团,R 2是H或CH 3,R 3和R 4, 是具有1至7个碳原子的相同或不同的脂族基团,n为1至4,然后在第二步中将聚合物P)与C)羟基数为10至500mg KOH / g的一种或多种聚酯多元醇 固体,酸值> 0.5至<= 30mg KOH / g固体,并且在加入中和剂之前或之后将所得聚合物混合物进一步分散在水中。 本发明还涉及根据本发明的方法获得的聚酯 - 聚丙烯酸酯聚合物水分散体和含有本发明的聚酯 - 聚丙烯酸酯聚合物水分散体的水性涂料组合物。