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1. 发明申请

US20150159000A1 AQUEOUS COMPOSITIONS OF POLYALDEHYDES FROM THE OXIDATION OF POLYSACCHARIDES AND THEIR THERMOSETS 审中-公开
标题翻译：聚氧乙烯醚及其热稳定剂氧化聚氨酯的水性组合物
公开(公告)号：US20150159000A1
公开(公告)日：2015-06-11
申请号：US14563069
申请日：2014-12-08
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： Charles J. Rand , William C. Finch , Thomas P. Clark
IPC分类号： C08L5/00
CPC分类号： C08B30/18 , C08L3/02 , C09D103/02 , C09J103/02
摘要： The present invention provides thermosetting aqueous binder compositions comprising a diprimary amine or poly(primary amine) and one or more water soluble oxidized dextrin made by oxidizing a dextrin having a DE value of from 2 to 25 and having from 2 to 10 millieq CHO/g of dry oxidized dextrin or a larger oxidized dextrin or an oxidized dextrin made by oxidizing a dextrin having a DE value of below 2 and having from 0.25 to 5 millieq CHO/g of dry oxidized dextrin. The aqueous biobased binders provide hot wet tensile strength when heat cured.
摘要翻译：本发明提供了包含二原子胺或聚（伯胺）和一种或多种水溶性氧化糊精的热固性水性粘合剂组合物，其通过氧化DE值为2至25的糊精和具有2至10毫克CHO / g 的干氧化糊精或通过氧化DE值低于2的糊精和0.25至5毫克CHO / g干氧化糊精制成的较大氧化糊精或氧化糊精。水性生物基粘合剂在热固化时提供热湿拉伸强度。

2. 发明申请

US20180327310A1 Emulsion Polymer Two-Component Compositions For Fast Curing, Flexible Cementitious Waterproofing Membranes 审中-公开
公开(公告)号：US20180327310A1
公开(公告)日：2018-11-15
申请号：US15770980
申请日：2016-10-24
申请人： Dow Global Technologies LLC , Rohm and Haas Company
发明人： Ann E. Evans , William C. Finch , Miroslav Janco , Sudhir M. Mulik , Margarita Perello , Marc Schmitz
IPC分类号： C04B24/26 , C04B24/06 , C04B28/06 , C04B40/02
CPC分类号： C04B24/2652 , C04B7/02 , C04B14/06 , C04B24/06 , C04B24/2641 , C04B24/2676 , C04B24/2688 , C04B28/06 , C04B40/029 , C04B2103/0062 , C04B2103/12 , C04B2111/00801 , C04B2111/27 , C04B20/0076 , C04B22/143 , C04B24/383 , C04B40/065
摘要： The present invention provides two-component compositions for making a waterproofing membrane comprising as component A) one or more acrylic aqueous emulsion copolymerization product (copolymer) of (i) from 60 to 89.9 wt. % of one or more nonionic (meth)acrylic monomers, preferably, butyl acrylate, methyl acrylate or ethylhexyl (meth)acrylate, (ii) from 10 to 40 wt. % of one or more vinyl aromatic monomers, (iii) from 0.1 to 2.0 wt. % of one or more amide functional acrylic monomer, and mixtures thereof with itaconic acid or methacrylic acid, wherein the emulsion copolymer has at least one residue of an ascorbic acid reducing agent and of t-butyl hydroperoxide and has less than 40 ppm or, preferably, less than 20 ppm, or more preferably, less than 10 ppm, of residual (meth)acrylamide.

3. 发明申请

US20180298534A1 CURABLE AQUEOUS COMPOSITIONS HAVING IMPROVED WET TENSILE STRENGTH AND USES THEREOF 审中-公开
公开(公告)号：US20180298534A1
公开(公告)日：2018-10-18
申请号：US15762581
申请日：2016-10-24
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： Silvia Isabel Endres , William C. Finch , Drew E. Williams
IPC分类号： D04H1/587 , C08L3/02 , C08L5/00 , C08L5/02 , D04H1/64
摘要： According to the present invention, curable aqueous compositions provide excellent wet tensile strength and comprise (i) one or more polyacid, (ii) a mixture of two or more polyols including pentaerythritol, (iii) a carbohydrate, such as a starch, and (iv) from 0.5 to 12 wt. %, based on total solids, of one or more azetidinium group containing polyamidoamine resins. The compositions are useful in providing fibrous articles, such as heat resistant nonwovens.

4. 发明授权

US09574079B2 Aqueous binder compositions of aliphatic or cycloaliphatic dicarboxaldehydes and resorcinol 有权
标题翻译：脂肪族或脂环族二羧酸和间苯二酚的水性粘合剂组合物
公开(公告)号：US09574079B2
公开(公告)日：2017-02-21
申请号：US14552889
申请日：2014-11-25
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： William C. Finch , Sudhir M. Mulik , Manesh Nadupparambil Sekharan
IPC分类号： C08L61/12 , C08G8/04 , C08G14/08 , C09J161/12 , C09J161/34 , C08L61/34
CPC分类号： C08L61/12 , C08G8/04 , C08G14/08 , C08L61/34 , C08L63/00 , C08L2201/54 , C09J161/12 , C09J161/34 , C08K5/5435
摘要： The present invention provides substantially formaldehyde free aqueous thermosetting binder resins from resorcinol and cycloaliphatic dialdehydes, glutaraldehyde or their mixtures and urea which may be excluded or included up to amounts which deter hot wet tensile strength in the cured binder. The compositions provide binders that on a performance cost basis are equivalent to phenol formaldehyde resins but without the formaldehyde.
摘要翻译：本发明提供了基本上不含甲醛的水性热固性粘合剂树脂，其中间苯二酚和脂环族二醛，戊二醛或它们的混合物和尿素可被排除或包括在内，该量可以阻止固化的粘合剂中的热湿拉伸强度。组合物提供在性能成本基础上相当于苯酚甲醛树脂但不含甲醛的粘合剂。

5. 发明申请

US20150148484A1 AQUEOUS BINDER COMPOSITIONS OF ALIPHATIC OR CYCLOALIPHATIC DICARBOXALDEHYDES AND RESORCINOL 有权
标题翻译：脂肪酸或环己烷二羧酸和环己烯酮的水性粘合剂组合物
公开(公告)号：US20150148484A1
公开(公告)日：2015-05-28
申请号：US14552889
申请日：2014-11-25
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： William C. Finch , Sudhir M. Mulik , Manesh Nadupparambil Sekharan
IPC分类号： C08L61/12
CPC分类号： C08L61/12 , C08G8/04 , C08G14/08 , C08L61/34 , C08L63/00 , C08L2201/54 , C09J161/12 , C09J161/34 , C08K5/5435
摘要： The present invention provides substantially formaldehyde free aqueous thermosetting binder resins from resorcinol and cycloaliphatic dialdehydes, glutaraldehyde or their mixtures and urea which may be excluded or included up to amounts which deter hot wet tensile strength in the cured binder. The compositions provide binders that on a performance cost basis are equivalent to phenol formaldehyde resins but without the formaldehyde.
摘要翻译：本发明提供了基本上不含甲醛的水性热固性粘合剂树脂，其中间苯二酚和脂环族二醛，戊二醛或它们的混合物和尿素可被排除或包括在内，该量可以阻止固化的粘合剂中的热湿拉伸强度。组合物提供在性能成本基础上相当于苯酚甲醛树脂但不含甲醛的粘合剂。

6. 发明授权

US09175121B2 Resins of B-hydroxy propyl gamma-polyoxyalkylene ethers and polymers thereof 有权
标题翻译： B-羟基丙基γ-聚氧化烯醚的树脂及其聚合物
公开(公告)号：US09175121B2
公开(公告)日：2015-11-03
申请号：US14353821
申请日：2012-10-25
申请人： Rohm and Haas Company
发明人： William C. Finch , Sudhir M. Mulik , C. Damien Rodowski , Barry Weinstein
IPC分类号： C08F220/28 , C08F8/14 , C08F8/44 , C08F120/06
CPC分类号： C08F220/28 , C08F8/14 , C08F2220/285 , C08F8/44 , C08F120/06
摘要： The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.
摘要翻译：本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。该方法能够简单地形成梳状聚合物。

7. 发明申请

US20150093952A1 METHACRYLIC ACID POLYMER EXTENDED UREA-FORMALDEHYDE RESIN COMPOSITION FOR MAKING FIBERGLASS PRODUCTS 有权
标题翻译：甲基丙烯酸聚合物扩展尿素 - 甲醛树脂组合物制备纤维玻璃制品
公开(公告)号：US20150093952A1
公开(公告)日：2015-04-02
申请号：US14501638
申请日：2014-09-30
申请人： Rohm and Haas Company
发明人： William C. Finch , Michael D. Kelly , Sudhir M. Mulik , C. Damien Rodowski
IPC分类号： C09D161/24 , B05D3/00
CPC分类号： B05D3/007 , B32B17/04 , C08J5/043 , C08L33/02 , C08L61/24 , Y10T442/2959 , C08L33/14
摘要： The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.
摘要翻译：本发明提供甲基丙烯酸聚合物改性的含水尿素甲醛树脂（UF树脂）粘合剂组合物，其可用于制备经处理的玻璃垫，例如对于屋顶瓦片，其中所述甲基丙烯酸聚合物包含至少50wt。％，基于用于制备甲基丙烯酸聚合物的单体的总重量，甲基丙烯酸或其盐或其混合物，水溶性含磷或含硫化合物和其余含羧酸基团的单体，例如丙烯酸。甲基丙烯酸聚合物具有亚磷酸酯基，次磷酸酯基，次膦酸酯基，二亚膦酸酯基和/或磺酸酯基中的至少一种，并且使得改性的UF树脂即使当粘合剂组合物包含0.1至小于5wt 。基于UF树脂和聚合物改性剂的总固体的聚合物改性剂的％。

8. 发明申请

US20140303317A1 RESINS OF B-HYDROXY PROPYL GAMMA-POLYOXYALKYLENE ETHERS AND POLYMERS THEREOF 有权
标题翻译： B-羟基丙酸酯 - 聚氧乙烯醚及其聚合物的树脂
公开(公告)号：US20140303317A1
公开(公告)日：2014-10-09
申请号：US14353821
申请日：2012-10-25
申请人： ROHM AND HAAS COMPANY
发明人： William C. Finch , Sudhir M. Mulik , C. Damien Rodowski , Barry Weinstein
IPC分类号： C08F220/28
CPC分类号： C08F220/28 , C08F8/14 , C08F2220/285 , C08F8/44 , C08F120/06
摘要： The present invention provides aqueous compositions comprising β-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether β-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.
摘要翻译：本发明提供包含选自（聚）氧化烯醚和（ - ）羟基丙基（甲基）丙烯酸酯，马来酸酯和衣康酸酯，其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。水溶性共聚物是梳状聚合物，（甲基）丙烯酸酯，马来酸酯和衣康酸酯单体树脂可加成聚合以形成适用于许多用途的梳状聚合物，如超增塑剂，分散剂，洗涤剂和地板护理组合物。此外，本发明提供了通过在水或水性溶剂中反应制备所述树脂的方法，一种或多种反应物a）任选具有烷基或芳基端基的缩水甘油醚或缩水甘油醚与一种或多种反应物b）羧酸根阴离子含有乙烯基化合物或聚合物，优选聚合物如聚（甲基）丙烯酸。该方法能够简单地形成梳状聚合物。

9. 发明授权

US09962731B2 Methacrylic acid polymer extended urea-formaldehyde resin composition for making fiberglass products 有权
公开(公告)号：US09962731B2
公开(公告)日：2018-05-08
申请号：US14501638
申请日：2014-09-30
申请人： Rohm and Haas Company
发明人： William C. Finch , Michael D. Kelly , Sudhir M. Mulik , C. Damien Rodowski
IPC分类号： C08K5/00 , B05D3/00 , C08J5/04 , C08L61/24 , B32B17/04 , C08L33/02
CPC分类号： B05D3/007 , B32B17/04 , C08J5/043 , C08L33/02 , C08L61/24 , Y10T442/2959 , C08L33/14
摘要： The present invention provides methacrylic acid polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g. for roofing shingles, wherein the methacrylic acid polymer comprises the reaction product of at least 50 wt. %, based on the total weight of monomers used to make the methacrylic acid polymer, of methacrylic acid or its salts, or mixtures thereof, a water-soluble phosphorous or sulfur containing compound and the remainder of a carboxylic acid group containing monomer, such as acrylic acid. The methacrylic acid polymers have at least one of a phosphite group, hypophosphite group, phosphinate group, diphosphinate group, and/or sulfonate group and enable modified UF resins to have early strength development even when the binder compositions comprise from 0.1 to less than 5 wt. % of the polymer modifier, based on total solids of the UF resin and the polymer modifier.

10. 发明公开

US20230174771A1 HIGH ACID ACRYLIC STYRENE ACRYLIC AND ACRYLIC EMULSION COPOLYMER MODIFIED UREA FORMALDEHYDE BINDERS FOR MINERAL FIBERS 审中-公开
公开(公告)号：US20230174771A1
公开(公告)日：2023-06-08
申请号：US17923000
申请日：2021-07-23
申请人： Rohm and Haas Company
发明人： Sudhir M. Mulik , William C. Finch , C. Damien Rodowski
IPC分类号： C08L61/24 , D04H1/4218 , D04H1/587 , D04H1/645
CPC分类号： C08L61/24 , D04H1/4218 , D04H1/587 , D04H1/645 , D10B2101/06
摘要： The present invention provides modified urea formaldehyde (UF) resin binder compositions and mineral fiber mats having an emulsion polymer modifier comprising, in copolymerized form, from 5 to 25 wt. % of co polymerized carboxylic acid functional monomers. The emulsion polymers have a measured glass transition temperature (DSC) ranging from −40° C. to 70° C. and a large average particle size. Further, the emulsion polymers comprise less than 30% of the copolymerized acid in neutralized form and do not excessively thicken aqueous compositions containing them. The modified UF resin binder compositions enable good dilution stability in use and high tensile strength in products containing them.

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