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1. 发明申请

WO2014175964A1 A POLYMERIC POWDER COMPOSITION AND A METHOD OF PRODUCING SAME 审中-公开
标题翻译：聚合粉末组合物及其制造方法
公开(公告)号：WO2014175964A1
公开(公告)日：2014-10-30
申请号：PCT/US2014/020193
申请日：2014-03-04
申请人： ROHM AND HAAS COMPANY , NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , ADAMO, Joseph, Robert
发明人： NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , ADAMO, Joseph, Robert
IPC分类号： C08J3/12
CPC分类号： C08L33/14 , C08J3/122 , C08J3/126 , C08J2309/00 , C08J2311/02 , C08J2325/04 , C08J2327/06 , C08J2331/04 , C08J2333/08 , C08J2333/12 , C08J2335/04 , C08L2205/02
摘要： A polymeric powder composition prepared from an emulsion blend comprising from 95 to less than 100 percent by weight latex based substrate polymer, wherein the latex based substrate polymer comprises units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylates, functionalized alkyl(meth)acrylates styrene, acrylonitrile, butadiene, chloroprene, vinyl chloride, (meth)acrylates, vinyl acetate, and combinations of two or more thereof and wherein the latex based substrate polymer has a Tg equal to or greater than 60 °C and an average particle size between 100 nm and 10 μm; and from greater than 0 to 5 percent by weight binder latex polymer, wherein the binder has a Tg of equal to or less than 10 °C and has units derived from one or more (meth)acrylic monomers, and wherein the binder polymer has an average particle size from 50 to 250 nm is provided.
摘要翻译：由乳液混合物制备的聚合物粉末组合物，其包含95至小于100重量％的基于胶乳的基底聚合物，其中基于胶乳的基底聚合物包含衍生自一种或多种选自（甲基）丙烯酸烷基酯，官能化的（甲基）丙烯酸烷基酯，苯乙烯，丙烯腈，丁二烯，氯丁二烯，氯乙烯，（甲基）丙烯酸酯，乙酸乙烯酯及其两种或更多种的组合，其中胶乳基底物聚合物的Tg等于或大于60℃ 平均粒径为100nm〜10μm; 和大于0至5重量％的粘合剂胶乳聚合物，其中所述粘合剂的Tg等于或小于10℃，并且具有衍生自一种或多种（甲基）丙烯酸单体的单元，并且其中所述粘合剂聚合物具有平均粒度为50〜250nm。

2. 发明申请

WO2012058256A1 A THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 审中-公开
标题翻译：热塑性组合物，其制造方法及其制造方法
公开(公告)号：WO2012058256A1
公开(公告)日：2012-05-03
申请号：PCT/US2011/057793
申请日：2011-10-26
申请人： ROHM AND HAAS COMPANY , SAINT-GERARD, Yannick , NELLIAPPAN, Veera, D. , CHIQUET, Yannick , LUNDQUIST, Eric, G.
发明人： SAINT-GERARD, Yannick , NELLIAPPAN, Veera, D. , CHIQUET, Yannick , LUNDQUIST, Eric, G.
IPC分类号： C08L33/12
CPC分类号： C08L67/07 , B29C45/0001 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2205/22
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含熔融共混产物：（A）55至95重量％的包含一种或多种热塑性聚合物的热塑性基质; 和（B）5至45重量％的包含交联的（甲基）丙烯酸酯共聚物的分散相，其中（甲基）丙烯酸酯共聚物包含至少95重量％衍生自甲基丙烯酸甲酯单元，并且大于0至衍生自一种或多种多官能交联单体和/或接枝连接剂的小于0.5重量％其中组分（A）和（B）之间的折射率差大于0.08。

3. 发明申请

WO2012088345A1 A THERMOPLASTIC COMPOSITION, METHOD OF PROCUCING THE SAME, AND ARTICLES MADE THEREFROM 审中-公开
标题翻译：热塑性组合物及其制备方法及其制备方法
公开(公告)号：WO2012088345A1
公开(公告)日：2012-06-28
申请号：PCT/US2011/066636
申请日：2011-12-21
申请人： ROHM AND HAAS COMPANY , NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , SAINT-GERARD, Yannick
发明人： NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , SAINT-GERARD, Yannick
IPC分类号： C08L33/12 , C08L69/00
CPC分类号： C08L69/00 , C08L33/12 , C08F220/14 , C08F2222/1013
摘要： A thermoplastic composition comprising from 60 percent to 99 percent by weight of one or more thermoplastic polymers; and from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked methylmethacrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size of equal to or less than 1.0 micron; and wherein an article produced from the scratch-resistant thermoplastic composition has a hardness of greater than F is provided. Also provided are a method of making the thermoplastic composition, articles made from the polycarbonate composition, and a method of making the articles.
摘要翻译：一种热塑性组合物，其包含60重量％至99重量％的一种或多种热塑性聚合物; 和40重量％至1重量％的包含交联的（甲基）丙烯酸酯聚合物的添加剂，其中交联的甲基丙烯酸甲酯聚合物包含衍生自甲基丙烯酸甲酯单元的至少99.5重量％，并且从大于0至小于0.5％衍生自一种或多种多官能交联单体的重量; 其中所述交联的（甲基）丙烯酸酯聚合物具有等于或小于1.0微米的体积平均粒度; 并且其中由耐刮擦热塑性组合物制备的制品具有大于F的硬度。还提供了制造热塑性组合物的方法，由聚碳酸酯组合物制成的制品以及制造该制品的方法。

4. 发明授权

EP2655510B1 A THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：热塑性组合物，用于生产及其制品
公开(公告)号：EP2655510B1
公开(公告)日：2016-09-28
申请号：EP11813495.6
申请日：2011-12-21
申请人： Rohm and Haas Company
发明人： NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , SAINT-GERARD, Yannick
IPC分类号： C08L33/12 , C08L69/00
CPC分类号： C08L69/00 , C08L33/12 , C08F220/14 , C08F2222/1013

5. 发明公开

EP2655510A1 A THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：热塑性组合物，其制备方法和由其制造的制品
公开(公告)号：EP2655510A1
公开(公告)日：2013-10-30
申请号：EP11813495.6
申请日：2011-12-21
申请人： Rohm and Haas Company
发明人： NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , SAINT-GERARD, Yannick
IPC分类号： C08L33/12 , C08L69/00
CPC分类号： C08L69/00 , C08L33/12 , C08F220/14 , C08F2222/1013
摘要： A thermoplastic composition comprising from 60 percent to 99 percent by weight of one or more thermoplastic polymers; and from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked methylmethacrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size of equal to or less than 1.0 micron; and wherein an article produced from the scratch-resistant thermoplastic composition has a hardness of greater than F is provided. Also provided are a method of making the thermoplastic composition, articles made from the polycarbonate composition, and a method of making the articles.
摘要翻译：一种热塑性组合物，其包含60重量％至99重量％的一种或多种热塑性聚合物; 和40重量％至1重量％的包含交联的（甲基）丙烯酸酯聚合物的添加剂，其中所述交联的甲基丙烯酸甲酯聚合物包含至少99.5重量％的衍生自甲基丙烯酸甲酯单元的重量，以及大于0至小于0.5重量％的由一种或多种多官能交联单体衍生的重量; 其中交联的（甲基）丙烯酸酯聚合物具有等于或小于1.0微米的体积平均粒度; 并且其中提供由耐刮擦热塑性组合物制成的制品具有大于F的硬度。还提供了制造热塑性组合物的方法，由该聚碳酸酯组合物制成的制品以及制造该制品的方法。

6. 发明公开

EP2867266A1 MULTI-STAGE POLYMER COMPOSITION AND FILMS MADE THEREFROM 有权
标题翻译：多级聚合物组合物及薄膜由其制
公开(公告)号：EP2867266A1
公开(公告)日：2015-05-06
申请号：EP13747628.9
申请日：2013-08-05
申请人： Rohm and Haas Company
发明人： GUO, Hailan , BROADWATER, Steven, J. , NELLIAPPAN, Veera, D.
IPC分类号： C08F265/06 , C08J5/18 , C08F285/00
CPC分类号： C08J5/18 , C08F220/10 , C08F220/40 , C08F265/06 , C08F285/00 , C08J2333/06 , C08J2333/08 , C08J2433/12 , C08J2435/02 , C08F2222/1013
摘要： A multi-stage polymer composition comprising a crosslinked core having a Tg of from −85 to −10° C.; an intermediate region which comprises one or more intermediate layers, wherein each of the intermediate layers comprises from 88.5 to 99.9 weight percent of units derived from a one or more monomers selected from the group consisting of alkyl(meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, a graft-linking monomer, or a combination of two or more thereof, optionally from 0 to 2 weight percent units derived from one or more chain transfer agents; wherein there is a compositional gradient between the intermediate layers such that the Tg transitions from −30° C. to 70° C. over the width of the intermediate region, and an outermost layer which has a Tg of from 40° C. to 110° C. is provided.

7. 发明公开

EP2632981A1 A THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：热塑性组合物，其制备方法和由其制造的制品
公开(公告)号：EP2632981A1
公开(公告)日：2013-09-04
申请号：EP11782291.6
申请日：2011-10-26
申请人： Rohm and Haas Company
发明人： SAINT-GERARD, Yannick , NELLIAPPAN, Veera, D. , CHIQUET, Yannick , LUNDQUIST, Eric, G.
IPC分类号： C08L33/12
CPC分类号： C08L67/07 , B29C45/0001 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2205/22
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.
摘要翻译：本发明提供了一种热塑性组合物，其生产方法以及由此制造的制品。根据本发明的热塑性组合物包含以下熔体共混产物：（A）55-95重量％的包含一种或多种热塑性聚合物的热塑性基体; 和（B）5-45重量％的包含交联的（甲基）丙烯酸酯共聚物的分散相，其中所述（甲基）丙烯酸酯共聚物包含至少95重量％的衍生自甲基丙烯酸甲酯单元和大于0 衍生自一种或多种多官能交联单体和/或接枝交联剂的小于0.5重量％; 其中组分（A）和（B）之间的折射率差大于0.08。

8. 发明公开

EP2941449A1 A POLYMERIC POWDER COMPOSITION AND A METHOD OF PRODUCING SAME 有权
标题翻译：维多利亚ZER HERSTELLUNG DAVON的POLYMERPULVERZUSAMMENSETZUNG
公开(公告)号：EP2941449A1
公开(公告)日：2015-11-11
申请号：EP14713989.3
申请日：2014-03-04
申请人： Rohm and Haas Company
发明人： NELLIAPPAN, Veera, D. , LUNDQUIST, Eric, G. , ADAMO, Joseph, Robert
IPC分类号： C08J3/12
CPC分类号： C08L33/14 , C08J3/122 , C08J3/126 , C08J2309/00 , C08J2311/02 , C08J2325/04 , C08J2327/06 , C08J2331/04 , C08J2333/08 , C08J2333/12 , C08J2335/04 , C08L2205/02
摘要： A polymeric powder composition prepared from an emulsion blend comprising from 95 to less than 100 percent by weight latex based substrate polymer, wherein the latex based substrate polymer comprises units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylates, functionalized alkyl(meth)acrylates styrene, acrylonitrile, butadiene, chloroprene, vinyl chloride, (meth)acrylates, vinyl acetate, and combinations of two or more thereof and wherein the latex based substrate polymer has a Tg equal to or greater than 60° C. and an average particle size between 100 nm and 10 μm; and from greater than 0 to 5 percent by weight binder latex polymer, wherein the binder has a Tg of equal to or less than 10° C. and has units derived from one or more (meth)acrylic monomers, and wherein the binder polymer has an average particle size from 50 to 250 nm is provided.
摘要翻译：由乳液混合物制备的聚合物粉末组合物，其包含95至小于100重量％的基于胶乳的基底聚合物，其中基于胶乳的基底聚合物包含衍生自一种或多种选自（甲基）丙烯酸烷基酯，官能化的（甲基）丙烯酸烷基酯，苯乙烯，丙烯腈，丁二烯，氯丁二烯，氯乙烯，（甲基）丙烯酸酯，乙酸乙烯酯及其两种或更多种的组合，其中胶乳基底物聚合物的Tg等于或大于60℃ 平均粒径为100nm〜10μm; 和大于0至5重量％的粘合剂胶乳聚合物，其中所述粘合剂的Tg等于或低于10℃，并且具有衍生自一种或多种（甲基）丙烯酸单体的单元，并且其中所述粘合剂聚合物具有提供50〜250nm的平均粒径。

9. 发明授权

EP2632981B1 A THERMOPLASTIC COMPOSITION, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：热塑性组合物，用于生产及其制品
公开(公告)号：EP2632981B1
公开(公告)日：2015-03-18
申请号：EP11782291.6
申请日：2011-10-26
申请人： Rohm and Haas Company
发明人： SAINT-GERARD, Yannick , NELLIAPPAN, Veera, D. , CHIQUET, Yannick , LUNDQUIST, Eric, G.
IPC分类号： G02B1/04
CPC分类号： C08L67/07 , B29C45/0001 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2205/22
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08.

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