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    • 9. 发明授权
    • Process for controlling iron
    • 控制铁的工艺
    • US5972849A
    • 1999-10-26
    • US553964
    • 1995-11-06
    • Jean-Pierre FeraudHerve PerthuisPhilippe DejeuxPierre Maroy
    • Jean-Pierre FeraudHerve PerthuisPhilippe DejeuxPierre Maroy
    • C09K8/528C09K8/74C09K7/00E21B43/00
    • C09K8/528C09K8/74
    • In the presence of certain crude oils, when ferric iron exists in very acidic fluid, it practically instantaneously forms precipitates known as sludges which lead to irreversible damage. Iron control compositions and acid fluids containing such iron control compositions are disclosed. For acid fluids containing up to 15% acid, the iron control composition includes a reducing agent selected from a substituted and unsubstituted thiourea compounds, and a reduction catalyst including a copper (cuprous or cupric) compound. When the acid fluid contains more than 15% acid, for example from 15 to 28% acid, the reducing agent is again selected from substituted or unsubstituted thiourea compounds, and the reduction catalyst is a combination of a copper (cuprous or cupric) compound and iodine (iodine or iodide ions). The invention also includes a process for treatment of oil, water, gas, geothermal or analogous wells using an acid fluid containing an iron control composition according to the present invention, and an industrial cleaning process using a cleaning fluid including an acid fluid containing an iron control agent according to the present invention.
    • 在某些原油的存在下,当三价铁存在于非常酸性的流体中时,它几乎瞬间形成称为淤泥的沉淀物,这导致不可逆的损伤。 公开了含铁控制组合物的铁控制组合物和酸流体。 对于含有高达15%酸的酸性流体,铁控制组合物包括选自取代和未取代的硫脲化合物的还原剂和包含铜(亚铜或铜)化合物的还原催化剂。 当酸性流体含有超过15%的酸,例如15至28%的酸时,还原剂再次选自取代或未取代的硫脲化合物,还原催化剂是铜(亚铜或铜)化合物和 碘(碘或碘离子)。 本发明还包括使用含有根据本发明的铁控制组合物的酸性流体处理油,水,气体,地热或类似井的方法,以及使用包括含有铁的酸性流体的清洁流体的工业清洁方法 根据本发明的控制剂。