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    • 1. 发明授权
    • Pesticidal heterocyclic dihaloallyl compounds
    • 杀虫杂环二卤代烯化合物
    • US07723362B2
    • 2010-05-25
    • US10597005
    • 2005-01-07
    • Roger Graham HallStephan TrahWerner ZambachJuraj Tuleja
    • Roger Graham HallStephan TrahWerner ZambachJuraj Tuleja
    • C07D401/12C07D257/04A61K31/4439A61K31/41C07D285/13C07D271/113C07D249/12C07D237/12C07D241/18C07D239/36C07D273/04C07D233/72
    • C07D271/113C07D233/72C07D237/14C07D239/36C07D241/18C07D249/12C07D273/04C07D285/13
    • The invention relates to compounds of formula wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.
    • 本发明涉及下式的化合物,其中Het,A1,A2,A3,A4,D,W,T,Q,Y,X1,X2,R1,R2,R3,R4,k和m如上所定义, 在适用的情况下,可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备和使用这些化合物的方法E / Z异构体,E / Z异构体和/或互变异构体的混合物,其中活性成分选自那些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离 形式或农业化学上可用的盐形式,涉及制备和使用这些组合物,用这些组合物处理的繁殖材料的方法,控制害虫的方法,中间体和适用时可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备这些化合物 ds,E / Z异构体,E / Z异构体和/或互变异构体的混合物,以及制备和使用那些中间体的方法,以及在适用时可能的E / Z异构体,E / Z异构体的混合物 和/或其互变异构体。
    • 2. 发明申请
    • PESTICIDAL HETEROCYCLIC DIHALOALLYL COMPOUNDS
    • 杀虫剂杂环二氢化合物
    • US20100197696A1
    • 2010-08-05
    • US12756596
    • 2010-04-08
    • Roger Graham HallStephan TrahWerner ZambachJuraj Tuleja
    • Roger Graham HallStephan TrahWerner ZambachJuraj Tuleja
    • A01N43/824C07D285/13C07D271/10C07D249/12C07D257/04C07D237/14C07D239/36C07D241/18A01N43/653A01N43/713A01N43/58A01N43/60A01N43/54
    • C07D271/113C07D233/72C07D237/14C07D239/36C07D241/18C07D249/12C07D273/04C07D285/13
    • The invention relates to compounds of formula wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.
    • 本发明涉及下式的化合物,其中Het,A1,A2,A3,A4,D,W,T,Q,Y,X1,X2,R1,R2,R3,R4,k和m如上所定义, 在适用的情况下,可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备和使用这些化合物的方法E / Z异构体,E / Z异构体和/或互变异构体的混合物,其中活性成分选自那些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离 形式或农业化学上可用的盐形式,涉及制备和使用这些组合物,用这些组合物处理的繁殖材料的方法,控制害虫的方法,中间体和适用时可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备这些化合物 ds,E / Z异构体,E / Z异构体和/或互变异构体的混合物,以及制备和使用那些中间体的方法,以及在适用时可能的E / Z异构体,E / Z异构体的混合物 和/或其互变异构体。
    • 3. 发明申请
    • Pesticidal Heterocyclic Dihaloallyl Compounds
    • 杀虫杂环二卤代烯化合物
    • US20070299064A1
    • 2007-12-27
    • US10597005
    • 2005-01-07
    • Roger HallStephan TrahWerner ZambachJuraj Tuleja
    • Roger HallStephan TrahWerner ZambachJuraj Tuleja
    • A01N43/653A01N43/54A01N43/58A01N43/824A01P17/00C07D239/22C07D249/12C07D271/113C07D273/04C07D257/04C07D241/08C07D237/04A01N43/88A01N43/713A01N43/60
    • C07D271/113C07D233/72C07D237/14C07D239/36C07D241/18C07D249/12C07D273/04C07D285/13
    • The invention relates to compounds of formula wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.
    • 本发明涉及下式的化合物,其中Het,A 1,A 2,A 3,A 4, D,W,T,Q,Y,X 1,X 2,R 1,R 2, R 3,R 4,k和m如上所定义,并且在适用的情况下,可能的E / Z异构体,E / Z异构体和/或互变异构体的混合物 在各种情况下以游离形式或盐形式,涉及制备和使用这些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物的方法,其中所述化合物 活性成分选自这些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下以游离形式或以农业化学上可用的盐形式,用于制备和/ 这些组合物,用这些组合物处理的繁殖材料,控制害虫的方法,中间体以及可能的E / Z异构体的E / Z异构体的混合物 其各自为游离形式或盐形式,用于制备这些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物,以及制备和/或 使用这些中间体,并且在适用的情况下可能使用E / Z异构体,E / Z异构体和/或其互变异构体的混合物。
    • 5. 发明申请
    • PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES
    • 杀虫活性酮和氧化衍生物
    • US20090298898A1
    • 2009-12-03
    • US12533302
    • 2009-07-31
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • A01N43/80C07C233/02C07C249/02C07D261/06A01N37/18A01N33/02A01P7/00
    • C07D333/58A01N33/24A01N35/10A01N37/52A01N41/06A01N43/10A01N43/40A01N43/78A01N43/80C07C49/753C07C49/755C07C49/84C07C235/84C07C251/44C07C251/48C07C251/54C07C251/58C07C311/04C07C311/05C07C311/09C07C323/47C07D213/50C07D213/53C07D213/61C07D213/64C07D261/08C07D277/24C07D277/28C07D307/52C07D307/81C07D333/22
    • Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
    • 下式化合物其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O,S,SO或SO 2; M为O或NOR6,X1和X2各自独立地为氟,氯或溴; R1,R2和R3是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基,C2-C6链烯基,C2-C6卤代烯基或C2-C6炔基; Q是例如O,S,SO或SO 2; W是例如O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从这些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的繁殖材料以及控制害虫的方法。
    • 7. 发明授权
    • Pesticidally active phenol derivatives
    • 农药活性酚衍生物
    • US07638514B2
    • 2009-12-29
    • US10568993
    • 2004-08-25
    • Werner ZambachStephan TrahRoger Graham HallWilliam Lutz
    • Werner ZambachStephan TrahRoger Graham HallWilliam Lutz
    • A01N37/20A01N31/16A01N35/10A01N43/40A01N43/713C07C231/02C07C43/225C07C249/08
    • A01N37/20A01N31/16A01N35/10A01N43/10A01N43/40A01N43/54A01N43/56A01N43/653A01N43/713A01N43/80A01N43/82A01N43/84C07C43/225C07C49/255C07C49/84C07C69/65C07C205/37C07C233/22C07C251/48C07C255/54C07D213/53C07D213/64C07D231/20C07D239/38C07D249/12C07D257/04C07D261/18C07D271/07C07D295/096C07D333/22C07D401/04C07F7/081
    • There are described compounds of formula (I) wherein X1 and X2 are each independently of the other fluorine, chlorine or bromine; A1 and A2 are, for example, a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge; R1 and R2 are, for example, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkyl-carbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C3-C6alkynyl; R,3 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R4 and R5 are, for example, H, halogen, cyano, nitro, C1-C6alkyl or C1-C3haloalkyl; m is 1 or 2; Y is, for example, O, S, SO or SO2; Q is, for example, O, S, SO or SO2; W is, for example, a bond, O, S, SO, S02, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; and E is aryl unsubstituted or substituted from one to five times or heterocyclyl unsubstituted or, depending upon the possibilities of substitution on the ring, substituted from one to four times; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 描述了式(I)的化合物,其中X 1和X 2各自独立地为其它氟,氯或溴; A1和A2是例如键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; R 1和R 2是例如卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基 - 羰基,C 2 -C 6烯基,C 2 -C 6卤代烯基或C 3 -C 6炔基; R 3是例如H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基或C 1 -C 6卤代烷基; R4和R5是例如H,卤素,氰基,硝基,C1-C6烷基或C1-C3卤代烷基; m为1或2; Y是例如O,S,SO或SO 2; Q是例如O,S,SO或SO 2; W是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; 并且E是未取代的或未取代的取代的芳基或未取代的杂环基,或取决于环上取代的可能性,取代1-4次; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物及其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 8. 发明授权
    • Pesticidally active ketone and oxime derivatives
    • 杀虫活性酮和肟衍生物
    • US07569727B2
    • 2009-08-04
    • US12098594
    • 2008-04-07
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • C07C251/32C07D213/24A01N33/24A01N43/40
    • C07D333/58A01N33/24A01N35/10A01N37/52A01N41/06A01N43/10A01N43/40A01N43/78A01N43/80C07C49/753C07C49/755C07C49/84C07C235/84C07C251/44C07C251/48C07C251/54C07C251/58C07C311/04C07C311/05C07C311/09C07C323/47C07D213/50C07D213/53C07D213/61C07D213/64C07D261/08C07D277/24C07D277/28C07D307/52C07D307/81C07D333/22
    • Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
    • 下式化合物其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O,S,SO或SO 2; M为O或NOR6,X1和X2各自独立地为氟,氯或溴; R1,R2和R3是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基,C2-C6链烯基,C2-C6卤代烯基或C2-C6炔基; Q是例如O,S,SO或SO 2; W是例如O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从这些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的繁殖材料以及控制害虫的方法。