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    • 5. 发明授权
    • Multilayer nonwoven laminiferous structure
    • 多层非织造层状结构
    • US5149576A
    • 1992-09-22
    • US618354
    • 1990-11-26
    • David C. PottsGeorge A. YoungDennis S. EverhartJ. Gavin MacDonaldRonald S. Nohr
    • David C. PottsGeorge A. YoungDennis S. EverhartJ. Gavin MacDonaldRonald S. Nohr
    • B32B5/26D04H13/00
    • B32B5/26D04H1/42D04H1/559D04H1/56D04H3/005Y10T428/24826Y10T428/31Y10T428/31544Y10T428/31663Y10T442/62Y10T442/659Y10T442/671
    • A nonwoven laminiferous structure is provided which has at least two melt-extruded nonwoven layers:(A) a first layer which includes at least a portion of a first nonwoven web; and(B) a second layer adjacent to said first layer which includes at least a portion of a second nonwoven web; in which,(1) the boundary between any two adjacent melt-extruded nonwoven layers is distinct in that fibers at or near the surfaces of such adjacent layer are not significantly intermingled;(2) the fibers of at least one of such first and second layers are prepared by melt extrusion through a die at a shear rate of from about 50 to about 30,000 sec.sup.-1 and a throughput of no more than about 5.4 kg/cm/hour of a mixture of an additive and a thermoplastic polymer, which additive (a) is present at a level of from about 0.05 to about 15 percent by weight, based on the amount of thermoplastic polymer, and (b) imparts to the surfaces of the fibers, as a consequence of the preferential migration of the additive to the surfaces of the fibers as they are formed, at least one characteristic which is different from the surface characteristics of fibers prepared from the thermoplastic polymer alone, said preferential migration taking place spontaneously upon the formation of the fibers without the need for a post-formation treatment of any kind;(3) the additive present in any melt-extruded nonwoven layer does not migrate to an adjacent layer to a significant degree in use, so that the surface characteristics of each layer remain substantially as originally prepared;(4) the thermoplastic polymer is elected from the group consisting of polyolefins, polyesters, polyetheresters, and polyamides; and(5) the laminiferous structure has been pattern bonded by the application of heat and pressure.
    • 提供了一种非织造层状结构,其具有至少两个熔融挤出非织造层:(A)第一层,其包括第一非织造纤维网的至少一部分; 和(B)邻近所述第一层的第二层,其包括第二非织造纤维网的至少一部分; 其中,(1)任何两个相邻的熔融挤出非织造层之间的边界是不同的,因为在相邻层的表面处或附近的纤维没有明显混合; (2)这样的第一和第二层中的至少一个的纤维通过熔融挤出通过模具以约50至约30,000秒-1的剪切速率和不超过约5.4kg / cm 2的生产量来制备, 添加剂和热塑性聚合物的混合物的小时,该添加剂(a)以基于热塑性聚合物的量的约0.05至约15重量%的量存在,和(b)赋予 作为添加剂在形成纤维表面时优先迁移到纤维表面的结果,纤维具有与单独由热塑性聚合物制备的纤维的表面特性不同的至少一个特征,所述优先迁移自发地发生 在形成纤维时,不需要任何形式的后处理; (3)存在于任何熔融挤出的非织造层中的添加剂在使用中不会显着地迁移到相邻层,使得每层的表面特性基本上保持原样制备; (4)热塑性聚合物选自聚烯烃,聚酯,聚醚酯和聚酰胺; 和(5)通过施加热和压力将层状结构图案结合。
    • 6. 发明授权
    • Multilayer nonwoven composite structure
    • 多层非织造复合结构
    • US5145727A
    • 1992-09-08
    • US618352
    • 1990-11-26
    • David C. PottsGeorge A. YoungDennis S. EverhartJ. Gavin MacDonaldRonald S. Nohr
    • David C. PottsGeorge A. YoungDennis S. EverhartJ. Gavin MacDonaldRonald S. Nohr
    • B32B5/08D04H13/00
    • B32B5/08D04H1/42D04H1/559D04H1/56D04H3/005D04H3/14Y10T428/24826Y10T428/31Y10T428/31544Y10T428/31663Y10T442/614Y10T442/668Y10T442/671
    • A nonwoven composite structure is provided which has at least two melt-extruded nonwoven layers:(A) a first layer which includes at least a portion of a first nonwoven web; and(B) a second layer which includes at least a portion of a second nonwovfen web;in which,(1) the boundary between any two adjacent melt-extruded nonwoven layers is indistinct in that fibers at or near the surfaces of such adjacent layers are significantly intermingled;(2) the fibers of at least one of such first and second layers are prepared by melt extrusion through a die at a shear rate of from about 50 to about 30,000 sec.sup.-1 and a throughput of no more than about 5.4 kg/cm/hour of a mixture of an additive and a thermoplastic polymer, which additive imparts to the surfaces of the fibers, as a consequence of the preferential migration of the additive to the surfaces of the fibers as they are formed, at least one characteristic which is different from the surface characteristics of fibers prepared from the thermoplastic polymer alone, said preferential migration taking place spontaneously upon the formation of the fibers without the need for a post-formation treatment of any kind;(3) the additive present in any melt-extruded nonwoven layer does not migrate to an adjacent layer to a significant degree in use, so that the surface characteristics of each layer remain substantially as originally prepared; and(4) the composite has been pattern bonded by the application of heat and pressure.
    • 提供了一种非织造复合结构,其具有至少两个熔融挤出非织造层:(A)第一层,其包括第一非织造纤维网的至少一部分; 和(B)第二层,其包括第二非织造网的至少一部分; 其中,(1)任何两个相邻的熔融挤出非织造层之间的边界是不明确的,因为在这些相邻层的表面处或附近的纤维显着混合; (2)这样的第一和第二层中的至少一个的纤维通过熔融挤出通过模具以约50至约30,000秒-1的剪切速率和不超过约5.4kg / cm 2的生产量来制备, 添加剂和热塑性聚合物的混合物的时间小于该添加剂与热塑性聚合物的混合物,这种添加剂赋予纤维的表面,这是由于添加剂在形成时优先迁移到纤维表面的结果,至少一种不同的特性 从仅由热塑性聚合物制备的纤维的表面特性,所述优先迁移在纤维形成时自发发生,而不需要任何形式的后处理; (3)存在于任何熔融挤出的非织造层中的添加剂在使用中不会显着地迁移到相邻层,使得每层的表面特性基本上保持原样制备; 和(4)复合材料通过施加热和压力进行图案粘结。
    • 9. 发明授权
    • Laminating method and products made thereby
    • 由此形成的层压方法和产品
    • US5455074A
    • 1995-10-03
    • US997799
    • 1992-12-29
    • Ronald S. NohrJohn G. MacDonald
    • Ronald S. NohrJohn G. MacDonald
    • B32B5/18B32B7/12B32B27/08B32B27/12B32B27/28B32B37/00B32B37/16C09J163/00B05D3/00B32B27/00
    • B32B37/12B29K2201/00B29K2223/00B32B2305/20B32B2310/0831B32B2310/0843B32B2327/06B32B2329/00B32B2363/00B32B37/1284Y10S428/934Y10T428/19Y10T428/192Y10T428/24041Y10T428/31504Y10T428/31573Y10T442/66Y10T442/668
    • A method of preparing a laminate having increased peel strength and solvent resistance which involves (A) applying an adhesive composition to a surface of a first sheet; (B) exposing the adhesive composition on the surface of the first sheet to incoherent, pulsed ultraviolet radiation from a dielectric barrier discharge excimer lamp; (C) bringing a surface of a second sheet in contact with the adhesive composition-bearing surface of the first article; and (D) allowing the adhesive composition to cure. The incoherent, pulsed ultraviolet radiation has a single narrow wavelength band within the range of from about 260 to about 360 nanometers. The adhesive composition includes from about 94 to about 60 percent by weight of a cycloaliphatic diepoxide, from about 1 to about 10 percent by weight of a cationic photoinitiator, and from about 5 to about 30 percent by weight of a vinyl chloride-vinyl acetate-vinyl alcohol terpolymer, all based on the weight of adhesive composition. The sheets desirably are films and nonwoven webs composed of cellulosic fibers, polyolefin fibers, or a mixture of cellulosic fibers and polyolefin fibers. The method is particularly well suited for the preparation of such laminates as industrial wipers, workwear, medical fabrics, and the like.
    • 一种制备具有增加的剥离强度和耐溶剂性的层压体的方法,其包括(A)将粘合剂组合物施加到第一片的表面; (B)将第一片表面上的粘合剂组合物暴露于来自介电阻挡放电准分子灯的非相干的脉冲紫外线辐射; (C)使第二片材的表面与第一制品的粘合剂组合物承载表面接触; 和(D)使粘合剂组合物固化。 非相干脉冲紫外线辐射具有在约260至约360纳米范围内的单个窄波长带。 粘合剂组合物包含约94至约60重量%的脂环族二环氧化物,约1至约10重量%的阳离子光引发剂和约5至约30重量%的氯乙烯 - 乙酸乙烯酯 - 乙烯醇三元共聚物,均基于粘合剂组合物的重量。 片材期望地是由纤维素纤维,聚烯烃纤维或纤维素纤维和聚烯烃纤维的混合物组成的膜和非织造纤维网。 该方法特别适用于制备诸如工业擦拭器,工作服,医用织物等的这样的层压材料。