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1. 发明申请

US20120053260A1 AQUEOUS EMULSION POLYMERS, THEIR PREPARATION AND USE 有权
标题翻译：水性乳液聚合物，其制备和使用
公开(公告)号：US20120053260A1
公开(公告)日：2012-03-01
申请号：US13221021
申请日：2011-08-30
申请人： Roelof BALK , Rolf Dersch , Sebastian Roller , Bernhard Schuler
发明人： Roelof BALK , Rolf Dersch , Sebastian Roller , Bernhard Schuler
IPC分类号： C09D5/02 , C08F2/46 , C09D4/02
CPC分类号： C09D5/022 , C08F2/24 , C08F2/46 , C08F220/18 , C08F220/40 , C08F2220/1825 , C09D4/00 , C09D133/066 , C08F212/08 , C08F220/06 , C08F220/56 , C08F2220/283
摘要： The present invention provides aqueous emulsion polymers comprising (A) monomers A (B) at least one (meth)acrylate with olefinically unsaturated side groups (monomers B), and (C) at least one photoinitiator, and also the use thereof in coating materials, more particularly in exterior architectural paints.
摘要翻译：本发明提供包含（A）单体A（B）至少一种具有烯属不饱和侧基（单体B）的（甲基）丙烯酸酯和（C）至少一种光引发剂的水性乳液聚合物，以及其在涂料中的用途，更具体地在外部建筑涂料中。

2. 发明授权

US08722756B2 Aqueous emulsion polymers, their preparation and use 有权
标题翻译：水乳液聚合物，其制备和用途
公开(公告)号：US08722756B2
公开(公告)日：2014-05-13
申请号：US13221021
申请日：2011-08-30
申请人： Roelof Balk , Rolf Dersch , Sebastian Roller , Bernhard Schuler
发明人： Roelof Balk , Rolf Dersch , Sebastian Roller , Bernhard Schuler
IPC分类号： C08F290/14 , B29C71/04 , C08F2/46 , A61L2/08
CPC分类号： C09D5/022 , C08F2/24 , C08F2/46 , C08F220/18 , C08F220/40 , C08F2220/1825 , C09D4/00 , C09D133/066 , C08F212/08 , C08F220/06 , C08F220/56 , C08F2220/283
摘要： The present invention provides aqueous emulsion polymers comprising (A) monomers A (B) at least one (meth)acrylate with olefinically unsaturated side groups (monomers B), and (C) at least one photoinitiator, and also the use thereof in coating materials, more particularly in exterior architectural paints.
摘要翻译：本发明提供包含（A）单体A（B）至少一种具有烯属不饱和侧基（单体B）的（甲基）丙烯酸酯和（C）至少一种光引发剂的水性乳液聚合物，以及其在涂料中的用途，更具体地在外部建筑涂料中。

3. 发明授权

US09169380B2 Use of aqueous polymer dispersions for improving resistance to chemical influences 有权
标题翻译：使用聚合物水分散体改善对化学影响的抗性
公开(公告)号：US09169380B2
公开(公告)日：2015-10-27
申请号：US13710952
申请日：2012-12-11
申请人： Sebastian Roller , Rolf Dersch , Uwe Dittrich , Roelof Balk , Bas Lohmeijer , Ulrich Tromsdorf
发明人： Sebastian Roller , Rolf Dersch , Uwe Dittrich , Roelof Balk , Bas Lohmeijer , Ulrich Tromsdorf
IPC分类号： C08L33/14 , C09D133/14
CPC分类号： C08L33/14 , C09D133/14
摘要： Coating compositions containing an aqueous polymer dispersion having improved resistance toward chemicals. The aqueous polymer dispersion is prepared by polymerizing a first composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization and then, in the presence of a product mixture from the previous polymerization, polymerizing a second composition containing at least one ethylenically unsaturated group (monomers) by radical aqueous emulsion polymerization. The coating compositions are such that the difference between a glass transition temperature of a polymer prepared from the first polymerization and a glass transition temperature of a polymer prepared from the second polymerization is at least 50° C.
摘要翻译：含有对化学物质具有改善的耐水性聚合物分散体的涂料组合物。聚合物水分散体是通过使含有至少一个烯键式不饱和基团（单体）的第一组合物通过自由基水乳液聚合聚合制备的，然后在来自先前聚合的产物混合物存在下，将含有至少一个烯键式不饱和基团（单体）通过自由基水乳液聚合。涂料组合物使得由第一聚合制备的聚合物的玻璃化转变温度与由第二聚合制备的聚合物的玻璃化转变温度之间的差为至少50℃。

4. 发明授权

US08785557B2 Use of aqueous hybrid binders for gloss paints 有权
标题翻译：使用水性混合粘合剂进行光泽漆
公开(公告)号：US08785557B2
公开(公告)日：2014-07-22
申请号：US12966528
申请日：2010-12-13
申请人： Sebastian Roller , Roelof Balk , Rolf Dersch
发明人： Sebastian Roller , Roelof Balk , Rolf Dersch
IPC分类号： C08K5/103 , C08G63/49 , C08G63/48
CPC分类号： C08K5/103 , C08G63/48 , C08L75/04 , C08L2201/50 , C09D133/08 , C09D133/12
摘要： The present invention relates to the use of aqueous hybrid binders for producing coating compositions, more particularly in high-gloss coating materials (high-gloss paints), and also to a process for their preparation with low residual monomer content.
摘要翻译：本发明涉及用于制备涂料组合物，特别是高光泽涂料（高光泽涂料））的水性复合粘合剂的用途，以及它们制备低残留单体含量的方法。

5. 发明申请

US20100286325A1 LOW-VOC AQUEOUS HYBRID BINDERS 有权
标题翻译： LOW-VOC水性混合胶粘剂
公开(公告)号：US20100286325A1
公开(公告)日：2010-11-11
申请号：US12601293
申请日：2008-06-12
申请人： Roelof Balk , Sebastian Roller , Rolf Dersch , Uwe Dittrich
发明人： Roelof Balk , Sebastian Roller , Rolf Dersch , Uwe Dittrich
IPC分类号： C08L33/10
CPC分类号： C08L51/003 , C08F2/22 , C08F283/01 , C08F291/00 , C08L25/02 , C08L33/06 , C09D5/02 , C09D133/06 , C09D135/06 , C09D167/08 , C08L2666/02 , C08L2666/04 , C08L2666/18
摘要： The present invention relates to aqueous binder compositions obtainable by emulsion polymerization of (A) at least one C1-C10 alkyl (meth)acrylate, and/or a vinylaromatic compound having up to 20 C atoms, or mixtures thereof (monomers A), (B) and also, if appropriate, further monomers B, and (C) at least one water-soluble alkyd resin having a weight-average molecular weight between 5000 and 40 000 Da, wherein the polymerization of the monomers A and also, if appropriate, B and the alkyds C is carried out in the form of a parallel feed process, and also to their preparation and use in coating materials.
摘要翻译：本发明涉及通过（A）至少一种（甲基）丙烯酸C 1 -C 10烷基酯和/或具有至多20个C原子的乙烯基芳族化合物或其混合物（单体A），（甲基）丙烯酸酯 B），并且如果合适，还可以含有另外的单体B和（C）至少一种重均分子量在5000至40000Da之间的水溶性醇酸树脂，其中单体A的聚合，以及如果合适，B和醇酸树脂C以平行进料工艺的形式进行，以及它们在涂料中的制备和用途。

6. 发明授权

US09315660B2 Low-VOC aqueous hybrid binders 有权
标题翻译：低VOC含水混合粘合剂
公开(公告)号：US09315660B2
公开(公告)日：2016-04-19
申请号：US12601293
申请日：2008-06-12
申请人： Roelof Balk , Sebastian Roller , Rolf Dersch , Uwe Dittrich
发明人： Roelof Balk , Sebastian Roller , Rolf Dersch , Uwe Dittrich
IPC分类号： C08L33/10 , C08L51/00 , C08F2/22 , C08F283/01 , C08F291/00 , C09D5/02 , C09D133/06 , C09D135/06 , C09D167/08 , C08L25/02 , C08L33/06
CPC分类号： C08L51/003 , C08F2/22 , C08F283/01 , C08F291/00 , C08L25/02 , C08L33/06 , C09D5/02 , C09D133/06 , C09D135/06 , C09D167/08 , C08L2666/02 , C08L2666/04 , C08L2666/18
摘要： The present invention relates to aqueous binder compositions obtainable by emulsion polymerization of (A) at least one C1-C10 alkyl (meth)acrylate, and/or a vinylaromatic compound having up to 20 C atoms, or mixtures thereof (monomers A), (B) and also, if appropriate, further monomers B, and (C) at least one water-soluble alkyd resin having a weight-average molecular weight between 5000 and 40 000 Da, wherein the polymerization of the monomers A and also, if appropriate, B and the alkyds C is carried out in the form of a parallel feed process, and also to their preparation and use in coating materials.
摘要翻译：本发明涉及通过（A）至少一种（甲基）丙烯酸C 1 -C 10烷基酯和/或具有至多20个C原子的乙烯基芳族化合物或其混合物（单体A），（甲基）丙烯酸酯 B），并且如果合适，还可以含有另外的单体B和（C）至少一种重均分子量在5000至40000Da之间的水溶性醇酸树脂，其中单体A的聚合，以及如果合适，B和醇酸树脂C以平行进料工艺的形式进行，以及它们在涂料中的制备和用途。

7. 发明授权

US08399554B2 Use of highly branched polymers in polymer dispersions for gloss colours 有权
标题翻译：在聚合物分散体中使用高度支化的聚合物用于光泽颜色
公开(公告)号：US08399554B2
公开(公告)日：2013-03-19
申请号：US12741244
申请日：2008-11-19
申请人： Sebastian Roller , Bernd Bruchmann , Rolf Dersch , Daniel Schoenfelder
发明人： Sebastian Roller , Bernd Bruchmann , Rolf Dersch , Daniel Schoenfelder
IPC分类号： C09B67/00 , C08G18/42
CPC分类号： C09D133/04 , C08L33/04 , C08L69/00 , C08L2666/18 , C08L2666/04
摘要： The present invention relates to a method of producing coatings with increased gloss, to aqueous coating materials for such a method, and to the use of highly branched polymers as an additive for aqueous polymer dispersions for coating materials that lead to coatings having increased gloss.
摘要翻译：本发明涉及一种生产具有增加光泽度的涂料的方法，用于这种方法的水性涂料，以及使用高度支化的聚合物作为用于涂料的水性聚合物分散体的添加剂，其导致具有增加的光泽度的涂料。

8. 发明申请

US20110237736A1 AQUEOUS BINDER COMPOSITION COMPRISING OLIGOMERS 有权
标题翻译：包含低聚物的水性粘合剂组合物
公开(公告)号：US20110237736A1
公开(公告)日：2011-09-29
申请号：US13132197
申请日：2009-11-23
申请人： Sebastian Roller , Rolf Dersch , Felix Baah
发明人： Sebastian Roller , Rolf Dersch , Felix Baah
IPC分类号： C09D133/14 , C08L33/14 , C08L33/08 , C08L25/06
CPC分类号： C08L33/00 , C08L2205/02 , C09D133/00 , C08L2666/04
摘要： The present invention relates to an aqueous binder composition comprising: at least one polymer P having a glass transition temperature Tg in the range from −20 to +60° C., in the form of an aqueous polymer dispersion PD which is obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer M, and 0.1 to 10% by weight, based on the sum of polymer P and oligomer, of one or more oligomers which are composed of ethylenically unsaturated monomers and have an average molecular weight Mw of 1000 to 30 000 g/mol, a glass transition temperature Tg in the range from +60 to +120° C., and an acid number in the range from 50 to 350, to a process for preparing it, to coating materials comprising it, and also to the use of water-soluble oligomers in a mixture with aqueous polymer dispersions in coating materials that lead to coatings featuring increased gloss.
摘要翻译：本发明涉及水性粘合剂组合物，其包含：至少一种聚合物P，其聚合物P的玻璃化转变温度Tg为-20℃至+ 60℃，呈聚合物水分散体PD的形式，至少一种烯键式不饱和单体M的自由基乳液聚合和基于聚合物P和低聚物的总和的0.1至10重量％的一种或多种由烯键式不饱和单体构成的低聚物并且具有平均分子量Mw 1000〜30000g / mol，玻璃化转变温度Tg在+ 60〜+ 120℃的范围内，酸值在50〜350的范围内，其制备方法，包括它的涂料，以及在涂料中使用水溶性低聚物与含水聚合物分散体的混合物，导致涂层具有增加的光泽度。

9. 发明授权

US09096753B2 Aqueous binder composition comprising oligomers 有权
标题翻译：包含低聚物的水性粘合剂组合物
公开(公告)号：US09096753B2
公开(公告)日：2015-08-04
申请号：US13132197
申请日：2009-11-23
申请人： Sebastian Roller , Rolf Dersch , Felix Baah
发明人： Sebastian Roller , Rolf Dersch , Felix Baah
IPC分类号： C10G50/00 , C08L33/00 , B01F3/12 , C09D133/00
CPC分类号： C08L33/00 , C08L2205/02 , C09D133/00 , C08L2666/04
摘要： The present invention relates to an aqueous binder composition comprising: at least one polymer P having a glass transition temperature Tg in the range from −20 to +60° C., in the form of an aqueous polymer dispersion PD which is obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer M, and 0.1 to 10% by weight, based on the sum of polymer P and oligomer, of one or more oligomers which are composed of ethylenically unsaturated monomers and have an average molecular weight Mw of 1000 to 30 000 g/mol, a glass transition temperature Tg in the range from +60 to +120° C., and an acid number in the range from 50 to 350, to a process for preparing it, to coating materials comprising it, and also to the use of water-soluble oligomers in a mixture with aqueous polymer dispersions in coating materials that lead to coatings featuring increased gloss.
摘要翻译：本发明涉及水性粘合剂组合物，其包含：至少一种聚合物P，其聚合物P的玻璃化转变温度Tg为-20℃至+ 60℃，呈聚合物水分散体PD的形式，至少一种烯键式不饱和单体M的自由基乳液聚合和基于聚合物P和低聚物的总和的0.1至10重量％的一种或多种由烯键式不饱和单体构成的低聚物并且具有平均分子量Mw 1000〜30000g / mol，玻璃化转变温度Tg在+ 60〜+ 120℃的范围内，酸值在50〜350的范围内，其制备方法，包括它的涂料，以及在涂料中使用水溶性低聚物与含水聚合物分散体的混合物，导致涂层具有增加的光泽度。

10. 发明申请

US20100267886A1 USE OF HIGHLY BRANCHED POLYMERS IN POLYMER DISPERSIONS FOR GLOSS COLOURS 有权
标题翻译：高分子聚合物在聚合物分散体中的应用
公开(公告)号：US20100267886A1
公开(公告)日：2010-10-21
申请号：US12741244
申请日：2008-11-19
申请人： Sebastian Roller , Bernd Bruchmann , Rolf Dersch , Daniel Schoenfelder
发明人： Sebastian Roller , Bernd Bruchmann , Rolf Dersch , Daniel Schoenfelder
IPC分类号： C09D131/00
CPC分类号： C09D133/04 , C08L33/04 , C08L69/00 , C08L2666/18 , C08L2666/04
摘要： The present invention relates to a method of producing coatings with increased gloss, to aqueous coating materials for such a method, and to the use of highly branched polymers as an additive for aqueous polymer dispersions for coating materials that lead to coatings having increased gloss.
摘要翻译：本发明涉及一种生产具有增加光泽度的涂料的方法，用于这种方法的水性涂料，以及使用高度支化的聚合物作为用于涂料的水性聚合物分散体的添加剂，其导致具有增加的光泽度的涂料。

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