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1. 发明授权

US4740489A Method of preparing a hydroconversion sulfided molybdenum catalyst concentrate 失效
标题翻译：制备加氢转化硫化钼催化剂浓缩物的方法
公开(公告)号：US4740489A
公开(公告)日：1988-04-26
申请号：US944443
申请日：1986-12-22
申请人： Roby Bearden, Jr. , Clyde L. Aldridge , Francis X. Mayer , James H. Taylor , William E. Lewis
发明人： Roby Bearden, Jr. , Clyde L. Aldridge , Francis X. Mayer , James H. Taylor , William E. Lewis
IPC分类号： B01J23/28 , B01J27/19 , B01J37/20 , C10G47/26 , B01J31/34 , B01J27/051
CPC分类号： B01J37/20 , B01J23/28 , B01J27/19 , C10G47/26
摘要： An improved method of preparing a catalyst from a catalyst precursor concentrate is provided. The catalyst precursor concentrate, which is preferably phosphomolybdic acid, is treated at relatively low pressures in a specified manner.
摘要翻译：提供了一种从催化剂前体浓缩物制备催化剂的改进方法。催化剂前体浓缩物（其优选为磷钼酸）以指定的方式在相对低的压力下进行处理。

2. 发明授权

US4740295A Hydroconversion process using a sulfided molybdenum catalyst concentrate 失效
标题翻译：使用硫化钼催化剂浓缩物的加氢转化法
公开(公告)号：US4740295A
公开(公告)日：1988-04-26
申请号：US944444
申请日：1986-12-22
申请人： Roby Bearden, Jr. , Clyde L. Aldridge , Francis X. Mayer , James H. Taylor , William E. Lewis
发明人： Roby Bearden, Jr. , Clyde L. Aldridge , Francis X. Mayer , James H. Taylor , William E. Lewis
IPC分类号： B01J23/28 , B01J27/19 , B01J37/20 , C10G47/26 , C10G47/02 , C10G1/08
CPC分类号： C10G47/26 , B01J23/28 , B01J27/19 , B01J37/20
摘要： Hydroconversion processes utilizing a catalyst prepared from a catalyst precursor concentrate such as phosphomolybdic acid, is provided. The catalyst precursor concentrate is treated at relatively low pressures in a specified manner.
摘要翻译：提供了使用由催化剂前体浓缩物如磷钼酸制备的催化剂的加氢转化方法。催化剂前体浓缩物以指定的方式在相对低的压力下处理。

3. 发明授权

US4762607A Hydroconversion process with combined temperature and feed staging 失效
标题翻译：加氢转化过程与组合温度和饲料分期
公开(公告)号：US4762607A
公开(公告)日：1988-08-09
申请号：US037511
申请日：1987-04-13
申请人： Clyde L. Aldridge , William E. Lewis , Roby Bearden, Jr. , Francis X. Mayer
发明人： Clyde L. Aldridge , William E. Lewis , Roby Bearden, Jr. , Francis X. Mayer
IPC分类号： C10G49/12 , C10G65/10
CPC分类号： C10G49/12 , C10G65/10
摘要： A slurry catalytic hydroconversion process comprising at least two hydroconversion zones is provided in which the heavy hydrocarbonaceous fresh oil feed is added to more than one hydroconversion zone. Additional portions of catalysts or catalyst precursors are also added to the first hydroconversion zone and to additional hydroconversion zones wherein said additional hydroconversion zones are maintained at a temperature of at least 10.degree. F. higher than an immediate preceding hydroconversion zone.
摘要翻译：提供了包含至少两个加氢转化区的淤浆催化加氢转化方法，其中将重质烃类新鲜油进料加入多于一个加氢转化区。催化剂或催化剂前体的另外部分也加入到第一加氢转化区和另外的加氢转化区中，其中所述另外的加氢转化区保持在比紧邻的前一个加氢转化区高至少10°F的温度。

4. 发明授权

US4765882A Hydroconversion process 失效
标题翻译：加氢转化过程
公开(公告)号：US4765882A
公开(公告)日：1988-08-23
申请号：US857358
申请日：1986-04-30
申请人： Clyde L. Aldridge , William E. Lewis , Roby Bearden, Jr. , Francis X. Mayer
发明人： Clyde L. Aldridge , William E. Lewis , Roby Bearden, Jr. , Francis X. Mayer
IPC分类号： C10G49/12 , C10G65/10
CPC分类号： C10G49/12 , C10G65/10
摘要： A slurry catalytic hydroconversion process comprising at least two hydroconversion zones is provided in which the heavy hydrocarbonaceous fresh oil feed is added to more than one hydroconversion zone. Additional portions of catalysts or catalyst precursors are also added to the first hydroconversion zone and to additional hydroconversion zones.
摘要翻译：提供了包含至少两个加氢转化区的淤浆催化加氢转化方法，其中将重质烃类新鲜油进料加入多于一个加氢转化区。催化剂或催化剂前体的另外部分也加入到第一加氢转化区和另外的加氢转化区。

5. 发明授权

US5108581A Hydroconversion of heavy feeds by use of both supported and unsupported catalysts 失效
标题翻译：通过使用载体和未负载的催化剂对重质进料进行加氢转化
公开(公告)号：US5108581A
公开(公告)日：1992-04-28
申请号：US607928
申请日：1990-11-01
申请人： Clyde L. Aldridge , Roby Bearden, Jr. , William E. Lewis
发明人： Clyde L. Aldridge , Roby Bearden, Jr. , William E. Lewis
IPC分类号： C10G1/08
CPC分类号： C10G1/086
摘要： Disclosed is a catalytic process for hydroconverting heavy hydrocarbonaceous feedstocks to lower boiling products wherein a catalyst precursor concentrate or catalyst concentrate is first prepared in a heavy oil medium then fed to a hydroconversion zone which may also contain a supported hydrotreating catalyst. The hydroconversion zone may be operated in either slurry or ebullating bed mode.
摘要翻译：公开了一种用于将重质烃原料加氢转化成低沸点产物的催化方法，其中首先在重油介质中制备催化剂前体浓缩物或催化剂浓缩物，然后将其加入到还可以含有负载型加氢处理催化剂的加氢转化区。加氢转化区可以以浆料或沸腾床模式操作。

6. 发明授权

US5039392A Hydroconversion process using a sulfided molybdenum catalyst concentrate 失效
标题翻译：使用硫化钼催化剂浓缩物的加氢转化法
公开(公告)号：US5039392A
公开(公告)日：1991-08-13
申请号：US532728
申请日：1990-06-04
申请人： Roby Bearden, Jr. , Clyde L. Aldridge
发明人： Roby Bearden, Jr. , Clyde L. Aldridge
IPC分类号： C10G47/26
CPC分类号： C10G47/26
摘要： A process for converting a heavy hydrocarbonaceous chargestock to lower boiling products which process comprises reacting the chargestock with a catalyst concentrate in the presence of hydrogen, at hydroconversion conditions, said catalyst concentrate having been prepared by the steps comprising: (a) forming a precursor catalyst concentrate by mixing together: (i) a hydrocarbonaceous oil comprising constituents boiling above about 1050.degree. F.; (ii) a metal compound, said metal being selected from the group consisting of Groups II, III, IV, V, VIB, VIIB, and VIII of the Periodic Table of the Elements, in an amount to provide from about 0.2 to 2 wt. % metal, based on said hydrocarbonaceous oil; (b) heating the precursor concentrate to an effective temperature to produce a catalyst concentrate, wherein elemental sulfur is used an a sulfiding agent in an amount such that the atomic ratio of sulfur to metal is from about 1/1 to 8/1.
摘要翻译：一种将重质含烃物料转化成较低沸点产物的方法，该方法包括在氢气存在下，在加氢转化条件下使所述原料与催化剂浓缩物反应，所述催化剂浓缩物已经通过以下步骤制备，所述步骤包括：（a）形成前体催化剂通过混合在一起浓缩：（i）包含沸点高于约1050°F的组分的含烃油; （ii）金属化合物，所述金属选自元素周期表的第II，III，IV，V，VIB，VIIB和VIII族，其量为约0.2至2wt 。基于所述烃油的％金属; （b）将前体浓缩物加热到有效温度以产生催化剂浓缩物，其中元素硫使用硫化剂，其量使得硫与金属的原子比为约1/1至8/1。

7. 发明授权

US4578182A Catalysts and hydroconversion processes utilizing the same 失效
公开(公告)号：US4578182A
公开(公告)日：1986-03-25
申请号：US762276
申请日：1985-08-05
申请人： Roby Bearden, Jr. , Clyde L. Aldridge
发明人： Roby Bearden, Jr. , Clyde L. Aldridge
IPC分类号： B01J23/26 , C10G1/08 , C10G47/06 , C10G47/26 , B01J27/047
CPC分类号： C10G47/06 , B01J23/26 , C10G1/086 , C10G47/26
摘要： A catalyst is prepared by heating the reaction product of CrO.sub.3 and tert-butyl alcohol as catalyst precursor in a hydrocarbon medium in the presence of hydrogen sulfide to convert the catalyst precursor to a solid chromium-containing catalyst. Hydroconversion processes utilizing the catalyst to convert oil, coal, and mixtures thereof are also provided.

8. 发明授权

US4424110A Hydroconversion process 失效
标题翻译：加氢转化过程
公开(公告)号：US4424110A
公开(公告)日：1984-01-03
申请号：US345340
申请日：1982-02-03
申请人： Roby Bearden, Jr. , William C. Baird, Jr. , Clyde L. Aldridge
发明人： Roby Bearden, Jr. , William C. Baird, Jr. , Clyde L. Aldridge
IPC分类号： C10G1/08 , C10G47/00 , C10G47/02
CPC分类号： C10G1/086 , C10G1/083 , C10G2300/107
摘要： Carbonaceous feeds such as hydrocarbonaceous oils and coal are hydroconverted in the presence of a combination of a hydrogen halide and a metal-containing catalyst produced in situ in the feed. The hydrogen halide is present in an amount to provide from about 0.1 to 20 moles of hydrogen halide per atom of the metal constituent of the catalyst to increase the activity of the catalyst.
摘要翻译：碳氢化合物如碳氢化合物油和煤炭在原料在原料中生产的卤化氢和含金属催化剂的组合存在下进行加氢转化。卤化氢的存在量为每原子催化剂金属组分约0.1至20摩尔卤化氢以增加催化剂的活性。

9. 发明授权

US4196072A Hydroconversion process 失效
标题翻译：加氢转化过程
公开(公告)号：US4196072A
公开(公告)日：1980-04-01
申请号：US909200
申请日：1978-05-23
申请人： Clyde L. Aldridge , Roby Bearden, Jr.
发明人： Clyde L. Aldridge , Roby Bearden, Jr.
IPC分类号： B01J27/188 , C10G1/08 , C10G47/06 , C10G47/26 , C10G1/06 , C10G13/02
CPC分类号： C10G47/06 , B01J27/188 , C10G1/086 , C10G47/26
摘要： In the hydroconversion of carbonaceous materials such as hydrocarbonaceous oils and coal or mixtures thereof, in which inorganic poly acids comprising molybdenum or tungsten or salts thereof are used as catalyst precursors which are converted to catalysts, the use of a combination of phosphoric acid and said poly acids or salts thereof as catalyst precursor wherein the amount of phosphoric acid is such as to provide from about 0.5 to about 3.5 atoms of phosphorus per atom of molybdenum or tungsten results in a catalyst having improved activity.
摘要翻译：在含碳材料和煤或其混合物的碳质材料的加氢转化中，其中使用包含钼或钨的无机多元酸或其盐作为转化为催化剂的催化剂前体，使用磷酸和所述聚酸或其盐作为催化剂前体，其中磷酸的量为每原子钼或钨提供约0.5至约3.5原子的磷，导致催化剂具有改善的活性。

10. 发明授权

US4954240A Combination coking and hydroconversion process 失效
标题翻译：组合焦化和加氢转化过程
公开(公告)号：US4954240A
公开(公告)日：1990-09-04
申请号：US286100
申请日：1988-12-19
申请人： Clarence M. Eidt, Jr. , Clyde L. Aldridge , Roby Bearden, Jr.
发明人： Clarence M. Eidt, Jr. , Clyde L. Aldridge , Roby Bearden, Jr.
IPC分类号： C10G1/08 , C10B55/00 , C10G9/00 , C10G9/32 , C10G31/11 , C10G45/16 , C10G69/06
CPC分类号： C10G31/11 , C10B55/00 , C10G9/00 , C10G9/005 , C10G2300/107
摘要： A hydrocarbonaceous feed, such as petroleum vacuum distillation bottoms, is upgraded by a combination coking and catalytic slurry hydroconversion process wherein a bottoms fraction from coking is passed to a slurry hydroconversion zone, and the bottoms fraction from the slurry hydroconversion zone is also passed thorugh a microfiltration system to remove catalyst particles.
摘要翻译：通过组合焦化和催化浆料加氢转化方法提高烃原料如石油真空蒸馏塔底馏分，其中将焦化的塔底馏分通入浆料加氢转化区，并且来自浆料加氢转化区的塔底馏分也通过微量过滤系统去除催化剂颗粒。

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