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1. 发明授权

US6066706A Process for the preparation of crystalline vinylaromatic polymers with a predominately syndiotactic structure 失效
标题翻译：制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法
公开(公告)号：US6066706A
公开(公告)日：2000-05-23
申请号：US716882
申请日：1996-09-20
申请人： Roberto Santi , Giuseppe Cometti , Riccardo Po'
发明人： Roberto Santi , Giuseppe Cometti , Riccardo Po'
IPC分类号： C08F4/642 , C08F4/60 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F12/00 , C08F12/04 , C08F12/08 , C08F12/06
CPC分类号： C08F12/04 , C08F10/00 , Y10S526/943
摘要： Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure which comprises polymerizing the vinylaromatic monomers, alone or mixed with at least another copolymerizable ethylenically unsaturated monomer, in the presence of a catalytic system essentially consisting of:a) an adduct between a derivative of titanium having the formula R.sub.1 R.sub.2 R.sub.3 R.sub.4 Ti and a calix-[n]-arene, or an oxa-calix-[n]-arene;b) a co-catalyst selected from an alkylalumoxane and a compound of boron having the formula (II):BX.sub.1 X.sub.2 X.sub.3 or its salt.
摘要翻译：用于制备主要间同立构结构的结晶乙烯基芳族聚合物的方法，该方法包括在催化体系存在下单独或与至少另一种可共聚的烯属不饱和单体混合的乙烯基芳族单体聚合，所述催化体系基本上由以下组成：a）衍生物之间的加合物具有式R1R2R3R4Ti和杯[ - ] - 芳烃或氧杂 - 杯 - [n] - 芳烃的钛; b）选自烷基铝氧烷和具有式（II）的硼化合物的助催化剂：BX1X2X3或其盐。

2. 发明授权

US5629391A Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure 失效
标题翻译：具有主要间同立构结构的结晶乙烯基芳族聚合物的制备方法
公开(公告)号：US5629391A
公开(公告)日：1997-05-13
申请号：US654202
申请日：1996-05-28
申请人： Nicoletta Cardi , Riccardo Po' , Roberto Santi , Giuseppe Cometti
发明人： Nicoletta Cardi , Riccardo Po' , Roberto Santi , Giuseppe Cometti
IPC分类号： C08F4/642 , C08F4/60 , C08F4/643 , C08F4/646 , C08F12/04 , C08F12/06 , C08F12/08 , C08F212/00
CPC分类号： C08F12/04 , C08F12/08 , C08F2420/04
摘要： Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure which comprises polymerizing the vinylaromatic monomers in the presence of a catalytic system consisting essentially of:a) a complex of titanium having the formula (I):Ti(OCONRR').sub.n (I) wherein R and R', the same or different, represent a C.sub.1 -C.sub.12 aliphatic radical or C.sub.6 -C.sub.12 aromatic radical whereas n is an integer equal to 3 or 4;b) a cocatalyst selected from aluminoxane and a compound of boron having formula (II):BX.sub.1 X.sub.2 X.sub.3 (II) wherein X.sub.1, X.sub.2 and X.sub.3, the same or different, represent a C.sub.1 -C.sub.20 perfluorinated hydrocarbon radical.
摘要翻译：制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下聚合乙烯基芳族单体，催化体系基本上由以下组成：a）具有式（I）的钛络合物：Ti（OCONRR'）n（ I）其中R和R'相同或不同，表示C1-C12脂族基或C6-C12芳族基，而n是等于3或4的整数; b）选自铝氧烷和具有式（II）的硼化合物的助催化剂：BX1X2X3（II）其中X1，X2和X3相同或不同，表示C1-C20全氟烃基。

3. 发明授权

US5728784A Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure 失效
标题翻译：具有主要间同立构结构的结晶乙烯基芳族聚合物的制备方法
公开(公告)号：US5728784A
公开(公告)日：1998-03-17
申请号：US757251
申请日：1996-11-27
申请人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
发明人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
IPC分类号： C08F2/02 , C08F2/04 , C08F2/06 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/80 , C08F12/00 , C08F12/04
CPC分类号： C08F12/08 , C08F2410/01 , C08F2410/03 , C08F4/65912
摘要： Process for the preparation of crystalline vinylaromatic polymers with a predominantly syndiotactic structure which comprises polymerizing vinylaromatic monomers, alone or mixed with at least one other monomer, in the presence of a catalytic system essentially consisting of: a) a complex of titanium or zirconium selected from those having general formula: MR.sub.1 R.sub.2 R.sub.3 R.sub.4, A.sub.1 MR.sub.1 R.sub.2 R.sub.3, A.sub.1 A.sub.2 MR.sub.1 R.sub.2 (I) b) a co-catalyst selected from an alkylalumoxane and a compound of boron having formula (II): BX.sub.1 X.sub.2 X.sub.3 (II) or one of its salts; c) a derivative of tin having general formula: SnR.sub.5 R.sub.6 R.sub.7 R.sub.8 (III)
摘要翻译：制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下单独或与至少一种其它单体混合的乙烯基芳族单体聚合，所述催化体系基本上由以下组成：a）选自具有通式：MR1R2R3R4，A1MR1R2R3，A1A2MR1R2（I）的共催化剂b）选自烷基铝氧烷和具有式（II）的硼化合物的助催化剂：BX1X2X3（Ⅱ）或其盐之一; c）具有以下通式的锡衍生物：SnR 5 R 6 R 7 R 8（III）

4. 发明授权

US5830959A Process for the production of vinylaromatic polymers with a high degree of syndiotacticity 失效
标题翻译：用于制备具有高度间同立构规整度的乙烯基芳族聚合物的方法
公开(公告)号：US5830959A
公开(公告)日：1998-11-03
申请号：US944783
申请日：1997-10-06
申请人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
发明人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
IPC分类号： C08F4/646 , C08F12/08 , C08F12/02
CPC分类号： C08F12/08 , C08F4/65912
摘要： Process for the preparation of crystalline vinylaromatic polymers with a high degree of syndiotacticity which comprises polymerizing vinylaromatic monomers in the presence of a catalytic system essentially consisting of: a) a complex of titanium selected from those having the general formula: (CpR.sub.1 R.sub.2 R.sub.3 R.sub.4 R.sub.5)TiX.sub.3 (I) wherein the groups R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent a hydrogen atom or C.sub.1 -C.sub.10 alkyl groups; X represents a hydrogen atom, a halogen such as chlorine, a C.sub.1 -C.sub.10 alkyl or oxyalkyl radical or a C.sub.6 -C.sub.12 oxyaryl radical; b) an alkylaluminoxane; and c) an organic derivative of tin; characterized in that the alkylaluminoxane is methylaluminoxane (MAO) treated at 20.degree.-80.degree. C. under vacuum for 1-100 hours and the organic derivative of tin is tin tetraphenyl.
摘要翻译：用于制备具有高程度间同立构规整度的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下聚合乙烯基芳族单体，所述催化体系基本上由以下组成：a）选自具有以下通式的那些钛络合物：（CpR1R2R3R4R5）TiX3（I ）其中基团R 1，R 2，R 3，R 4和R 5表示氢原子或C 1 -C 10烷基; X表示氢原子，卤素如氯，C1-C10烷基或烷氧基或C6-C12氧芳基; b）烷基铝氧烷; 和c）锡的有机衍生物; 其特征在于烷基铝氧烷是在20-80℃下真空处理1-100小时的甲基铝氧烷（MAO），锡的有机衍生物是四苯基锡。

5. 发明授权

US6143824A Polymeric compositions 有权
标题翻译：聚合物组合物
公开(公告)号：US6143824A
公开(公告)日：2000-11-07
申请号：US316201
申请日：1999-05-21
申请人： Nicoletta Cardi , Riccardo Po' , Aldo Longo , Andrea Callaioli
发明人： Nicoletta Cardi , Riccardo Po' , Aldo Longo , Andrea Callaioli
IPC分类号： C08L25/06 , C08L25/08 , C08L25/10 , C08L25/12 , C08L53/00 , C08L55/00 , C08L55/02 , C08L69/00 , C08L71/12 , C08L33/00
CPC分类号： C08L55/00 , C08L25/06 , C08L53/00 , C08L55/02 , C08L69/00 , C08L71/123 , C08L2205/02 , C08L25/12
摘要： Polymeric compositions comprising:a) at least one aromatic thermoplastic polymer or a vinylaromatic thermoplastic (co)polymer;b) at least one thermoplastic resin selected from a (co)polymer optionally modified with rubber, comprising a vinylaromatic monomer and/or a monomer deriving from (meth)acrylic acid and thermoplastic polyesters;c) a compatibilizing block polymer, with at least two blocks, which can be obtained by means of a living radicalic polymerization process.
摘要翻译：聚合物组合物，其包含：a）至少一种芳族热塑性聚合物或乙烯基芳族热塑性（共）聚合物; b）至少一种选自任选用橡胶改性的（共）聚合物的热塑性树脂，其包含乙烯基芳族单体和/或衍生自（甲基）丙烯酸和热塑性聚酯的单体; c）具有至少两个嵌段的相容性嵌段聚合物，其可以通过活性自由基聚合方法获得。

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