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    • 1. 发明授权
    • Application of coil tube evaporators for the production of polyamides
    • 卷管式蒸发器用于生产聚酰胺的应用
    • US08263733B2
    • 2012-09-11
    • US12446274
    • 2007-10-19
    • Robert WeissJens Becker
    • Robert WeissJens Becker
    • C08G69/02
    • C08G69/16C08G69/46
    • Helical tube evaporators are used to concentrate aqueous extract solutions from the extraction of polyamides based on polyamide 6.A process for preparing polyamides based on polyamide 6 comprises the stages of b) monophasic or biphasic reaction of aqueous extract solutions from the extraction of polyamides based on polyamide 6, which may be enriched with caprolactam, aminocapronitrile, aminocaproic acid or mixtures thereof, in a prereactor at pressures in the range from 5 to 40 bar and temperatures in the range from 150 to 300° C., the gaseous phase formed being removable from the liquid phase in the case of the biphasic reaction, c) discharge of the reaction mixture from stage b) through a helical tube evaporator at a temperature in the range from 220 to 300° C. with pressure reduction to about atmospheric pressure and removal of a gaseous phase to obtain a liquid phase, d) further reaction of the liquid phase from stage c) at temperatures in the range from 240 to 300° C. and pressures in the range from atmospheric pressure to 2 bar with removal of a gaseous phase.
    • 螺旋管蒸发器用于从基于聚酰胺6的聚酰胺的萃取中浓缩水提取物溶液。基于聚酰胺6制备聚酰胺的方法包括以下阶段:b)基于聚酰胺萃取的水提取物溶液的单相或双相反应 聚酰胺6,其可以在预反应器中在己烷内酰胺,氨基己腈,氨基己酸或其混合物中富集,其压力范围为5至40巴,温度范围为150-300℃,形成的气相可除去 在两相反应的情况下,从液相中,c)将反应混合物从阶段b)通过螺旋管蒸发器在220-300℃的温度下排出,同时减压至约大气压并除去 的气相以获得液相,d)液相从步骤c)在240-300℃的温度范围内进一步反应, 在大气压至2巴的范围内,除去气相。
    • 2. 发明申请
    • APPLICATION OF COIL TUBE EVAPORATORS FOR THE PRODUCTION OF POLYAMIDES
    • 用于生产聚氨酯的卷管蒸发器的应用
    • US20100317810A1
    • 2010-12-16
    • US12446274
    • 2007-10-19
    • Robert WeissJens Becker
    • Robert WeissJens Becker
    • C08F2/01
    • C08G69/16C08G69/46
    • Helical tube evaporators are used to concentrate aqueous extract solutions from the extraction of polyamides based on polyamide 6.A process for preparing polyamides based on polyamide 6 comprises the stages of b) monophasic or biphasic reaction of aqueous extract solutions from the extraction of polyamides based on polyamide 6, which may be enriched with caprolactam, aminocapronitrile, aminocaproic acid or mixtures thereof, in a prereactor at pressures in the range from 5 to 40 bar and temperatures in the range from 150 to 300° C., the gaseous phase formed being removable from the liquid phase in the case of the biphasic reaction, c) discharge of the reaction mixture from stage b) through a helical tube evaporator at a temperature in the range from 220 to 300° C. with pressure reduction to about atmospheric pressure and removal of a gaseous phase to obtain a liquid phase, d) further reaction of the liquid phase from stage c) at temperatures in the range from 240 to 300° C. and pressures in the range from atmospheric pressure to 2 bar with removal of a gaseous phase.
    • 螺旋管蒸发器用于从基于聚酰胺6的聚酰胺的萃取中浓缩水提取物溶液。基于聚酰胺6制备聚酰胺的方法包括以下阶段:b)基于聚酰胺萃取的水提取物溶液的单相或双相反应 聚酰胺6,其可以在预反应器中在己烷内酰胺,氨基己腈,氨基己酸或其混合物中富集,其压力范围为5至40巴,温度范围为150-300℃,形成的气相可除去 在两相反应的情况下,从液相中,c)将反应混合物从阶段b)通过螺旋管蒸发器在220-300℃的温度下排出,同时减压至约大气压并除去 的气相以获得液相,d)液相从步骤c)在240-300℃的温度范围内进一步反应, 在大气压至2巴的范围内,除去气相。
    • 3. 发明授权
    • Process for continuously preparing copolyamides from lactams and salts of diamines and dicarboxylic acids
    • 从内酰胺和二胺和二羧酸的盐连续制备共聚酰胺的方法
    • US09200115B2
    • 2015-12-01
    • US13139133
    • 2009-12-09
    • Christoph PlachettaAchim GerstlauerReinhard LangThomas SauerJens Becker
    • Christoph PlachettaAchim GerstlauerReinhard LangThomas SauerJens Becker
    • C08G69/36C08L77/00C08G69/28C08G69/08
    • C08G69/36C08G69/08C08G69/28C08L77/00
    • A process for continuously preparing copolyamides from lactams and salts of diamines and dicarboxylic acids, in which lactams together with salts of diamines and dicarboxylic acids are passed from the top downward through a vertical polymerization tube at polyamide-forming temperatures, which comprises a) intensively mixing an aqueous solution of lactams with salts of diamines and dicarboxylic acids under elevated pressure which is greater than the vapor pressure of the mixture which arises in a mixing apparatus at a temperature of from 80 to 300° C., b) feeding the mixture thus obtained to a heated helical tube evaporator in which a liquid phase and a vapor phase form at a temperature of from 140 to 300° C., a stream of water vapor and/or inert gas also being introduced into the mixture if appropriate upstream of the helical tube, c) removing the vapor phase formed in stage b) from the liquid phase and separating it in a column into water vapor and into organic components comprising diamines, dicarboxylic acids and lactams, and recycling the organic components into the polymerization, d) passing the liquid phase from the helical tube of stage b) mixed with the organic components of stage c) from the top downward through a vertical polymerization tube at polyamide-forming temperatures to obtain a copolyamide.
    • 其中内酰胺和二胺和二羧酸的盐连续制备共聚酰胺和二胺和二羧酸的盐,其中内酰胺与二胺和二羧酸的盐在聚酰胺形成温度下从顶部向下通过垂直聚合管,其包括a)浓缩混合 在升高的压力下具有二胺和二羧酸的盐的内酰胺的水溶液,其大于在混合装置中在80至300℃的温度下产生的混合物的蒸气压,b)将如此获得的混合物 到一个加热的螺旋管式蒸发器,其中液相和气相在140-300℃的温度下形成,如果合适的话,水蒸气和/或惰性气体也被引入到混合物的上游 管,c)从液相中除去阶段b)中形成的气相,并将其在塔中分离成水蒸汽,并加入有机组分,包括 二胺,二羧酸和内酰胺,并将有机组分再循环到聚合中,d)将来自与阶段c)的有机组分混合的阶段b)的螺旋管的液相从顶部向下通过垂直聚合管在聚酰胺 得到共聚酰胺。