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1. 发明授权

US06890671B2 Fuel mixing control for fuel cell power plants operating on multiple fuels 有权
标题翻译：用于燃料电池发电厂的燃料混合控制，用于多种燃料
公开(公告)号：US06890671B2
公开(公告)日：2005-05-10
申请号：US10324454
申请日：2002-12-19
申请人： Robert P. Roche , Paul R. Margiott , John C. Trocciola
发明人： Robert P. Roche , Paul R. Margiott , John C. Trocciola
IPC分类号： C01B3/02 , H01M8/04 , H01M8/06 , H02J20060101
CPC分类号： H01M8/04089 , H01M8/0612 , Y02E70/20
摘要： Fuel mixing control arrangements are provided for fuel cell power plants (10) operating on multiple fuels (22, 24, 26). A fuel delivery system (16) supplies hydrogen-rich fuel (20) to the cell stack assembly (CSA) (12) after controlled mixing of a primary fuel (22) and at least a secondary fuel (24), each having a respective “equivalent hydrogen (H2) content”. The relative amounts of the primary fuel (22) and secondary fuel (24) mixed are regulated (18, 34, 36) to provide at least a minimum level (LL) of hydrogen-rich fuel having an equivalent hydrogen content sufficient for normal operation of the CSA (12). The primary fuel (22) is a bio-gas or the like having a limited, possibly variable, equivalent H2 content, and the secondary fuel (22) has a greater and relatively constant equivalent H2 content and is mixed with the primary fuel in an economic, constant relationship that assures adequate performance of the CSA (12). One or more parameters (IDC, P, V, E. C.) of the operating power plant (10) related to the equivalent H2 content of at least the primary fuel may be sensed (72, 26, 78, 84, 176) and used to control (18, 36) the relative amounts of secondary and primary fuels (22, 24) mixed in response thereto.
摘要翻译：为燃料电池发电厂（10）提供燃料混合控制装置，燃料电池发电厂（10）在多种燃料（22,24,26）上运行。燃料输送系统（16）在主燃料（22）和至少二级燃料（24）的受控混合之后，向细胞堆叠组件（CSA）（12）供应富氢燃料（20） “等同氢（H 2 N 2）含量”。调节混合的主燃料（22）和二次燃料（24）的相对量（18,34,36）以提供具有足够正常操作的等效氢含量的至少最低水平（LL）的富氢燃料的CSA（12）。主要燃料（22）是具有有限的，可能变化的等同H 2 O 2含量的生物气体等，并且二次燃料（22）具有更大且相对恒定的等效H 2含量，与主要燃料混合，经济，不断的关系，确保CSA的充分表现（12）。可以感测与至少主要燃料的等效H 2 N 2含量有关的工作电厂（10）的一个或多个参数（IDC，P，V，EC）（72,26,78 ，84,176），并且用于控制（18,36）响应于此混合的二级和一级燃料（22,24）的相对量。

2. 发明授权

US4782669A Cooling system for a burst power fuel cell 失效
标题翻译：爆破式燃料电池的冷却系统
公开(公告)号：US4782669A
公开(公告)日：1988-11-08
申请号：US931592
申请日：1986-11-17
申请人： John C. Trocciola , Leslie L. VanDine
发明人： John C. Trocciola , Leslie L. VanDine
IPC分类号： H01M8/04 , F25D17/02
CPC分类号： H01M8/04007 , H01M8/04156 , H01M8/04014 , H01M8/04029 , H01M8/04097
摘要： Spaced based burst power fuel cells generate large thermal loads in very short time periods. In order to avoid external venting or the use of heavy radiators in space vehicles, such fuel cells must include onboard closed-loop cooling systems. Utilizing subcooled ice as a cooling medium, contactable with either the anode, cathode or coolant recirculating stream provides the fuel cell with a safe, highly efficient and low weight heat absorption capability.
摘要翻译：基于间歇的突发动力燃料电池在非常短的时间内产生大的热负荷。为了避免外部排放或在太空车辆中使用重型散热器，这种燃料电池必须包括板载闭环冷却系统。利用过冷冰作为冷却介质，可与阳极，阴极或冷却剂再循环流接触，为燃料电池提供安全，高效和低重量的吸热能力。

3. 发明授权

US4760713A Multiple heat sink cooling system for a burst power fuel cell 失效
标题翻译：用于突发式燃料电池的多个散热器冷却系统
公开(公告)号：US4760713A
公开(公告)日：1988-08-02
申请号：US931593
申请日：1986-11-17
申请人： John C. Trocciola , Donald R. McVay
发明人： John C. Trocciola , Donald R. McVay
IPC分类号： F25D3/02 , H01M8/04 , H01M10/50 , F25D17/02
CPC分类号： H01M8/04029 , F25D3/02 , H01M8/04007
摘要： Spaced based burst power fuel cells generate large thermal loads in very short time periods. In order to avoid external venting or the use of heavy radiators in space vehicles, such fuel cells must include onboard closed-loop cooling systems. Utilizing multiple heat sinks containing subcooled ice as a cooling medium, sequentially contactable with a coolant that passes through the fuel cell, provides a safe, highly efficient and low weight heat absorption capability.
摘要翻译：基于间歇的突发动力燃料电池在非常短的时间内产生大的热负荷。为了避免外部排放或在太空车辆中使用重型散热器，这种燃料电池必须包括板载闭环冷却系统。使用含有过冷冰的多个散热器作为冷却介质，其顺序地与通过燃料电池的冷却剂接触，提供安全，高效和低重量的吸热能力。

4. 发明授权

US4756981A Seal structure for an electrochemical cell 失效
标题翻译：电化学电池的密封结构
公开(公告)号：US4756981A
公开(公告)日：1988-07-12
申请号：US947168
申请日：1986-12-29
申请人： Richard D. Breault , Michael J. Rajpolt , John C. Trocciola
发明人： Richard D. Breault , Michael J. Rajpolt , John C. Trocciola
IPC分类号： H01M8/02 , H01M8/24 , H01M2/08
CPC分类号： H01M8/2415 , H01M8/0271 , H01M8/0297 , Y02P70/56
摘要： A seal structure 60 for a porous plate of an electrochemical cell, such as plates 18, 20, includes a sealing material disposed in a seal region 66 of the plate to form a hydrophilic barrier to gas with an electrolyte and a hydrophobic layer 62 to block the loss of electrolyte from the hydrophilic layer is disclosed. Various construction details including a method for making the plate are disclosed which increase the cross pressure the sealing region of the plate can withstand. In one embodiment, the seal region 66 is impregnated with powder having a low structure and predetermined particle size using a pressurized liquid carrier. A FEP Teflon film bonds adjacent electrolyte reservoir plates together.

5. 发明授权

US4248941A Solid electrolyte electrochemical cell 失效
标题翻译：固体电解质电池
公开(公告)号：US4248941A
公开(公告)日：1981-02-03
申请号：US107191
申请日：1979-12-26
申请人： George A. Louis , John M. Lee , Donald L. Maricle , John C. Trocciola
发明人： George A. Louis , John M. Lee , Donald L. Maricle , John C. Trocciola
IPC分类号： H01M4/88 , H01M4/90 , H01M8/10 , H01M8/24
CPC分类号： H01M8/241 , H01M4/9016 , H01M8/1007 , H01M8/1004 , H01M8/1016
摘要： A new type of electrochemical cell which can be used for generating electricity or in an electrolysis mode for producing gases such as hydrogen and oxygen comprises laterally spaced apart or side-by-side catalyst layers as electrodes with the gap between the catalyst layers being bridged by a solid electrolyte which provides an ion conductive path from one catalyst layer to the other. The catalyst layers and the electrolyte are preferably in the form of thin films or layers on the surface of an inert supporting substrate. A plurality of these cells may be disposed on the substrate and interconnected electrically forming a network of series and parallel connected cells. Means are provided to feed fuel and oxidant to the electrodes either as separate gases or mixed together if appropriate catalytic materials are selected.
摘要翻译：可用于产生电力或用于产生气体如氢气和氧气的电解模式的新型电化学电池包括横向间隔开的或并排的催化剂层作为电极，催化剂层之间的间隙由提供从一个催化剂层到另一个催化剂层的离子传导路径的固体电解质。催化剂层和电解质优选在惰性支撑基材的表面上呈薄膜或多层的形式。多个这些单元可以设置在基板上并互连成电连接形成串联和并联的单元的网络。提供了用于将燃料和氧化剂作为单独的气体供给到电极的装置，或者如果选择适当的催化材料则混合在一起。

6. 发明授权

US06617068B2 Bi-zone water transport plate for a fuel cell 有权
标题翻译：用于燃料电池的双区水输送板
公开(公告)号：US06617068B2
公开(公告)日：2003-09-09
申请号：US09940198
申请日：2001-08-27
申请人： Brian F. Dufner , Michael L. Perry , John C. Trocciola , Deliang Yang , Jung S. Yi
发明人： Brian F. Dufner , Michael L. Perry , John C. Trocciola , Deliang Yang , Jung S. Yi
IPC分类号： H01M202
CPC分类号： H01M8/086 , H01M8/0221 , H01M8/0228 , H01M8/0239 , H01M8/0258 , H01M8/0267 , H01M8/0271 , H01M8/0276 , H01M8/0297 , H01M8/04126 , H01M8/241
摘要： The invention is a bi-zone water transport plate for a fuel cell wherein the plate includes a water permeability zone and a bubble barrier zone. The bubble barrier zone extends between all reactive perimeters of the plate, has a pore size of less than 20 microns, and has a thickness of less than 25 percent of a shortest distance between opposed contact surfaces of the plate. The water permeability zone has a pore size of at least 100 percent greater than the pore size of the bubble barrier zone, and has a thickness of greater than 75 percent of the shortest distance between the opposed contact surfaces of the plate. By having a separate bubble barrier zone, the plate affords enhanced water permeability while the bubble barrier maintains a gas seal.
摘要翻译：本发明是用于燃料电池的双区水输送板，其中板包括透水区和气泡阻挡区。气泡阻挡区在板的所有反应性周长之间延伸，孔径小于20微米，并且具有小于板的相对接触表面之间最短距离的25％的厚度。透水性区域的孔径比气泡阻挡区域的孔径大至少100％，并且具有大于板的相对的接触表面之间最短距离的75％的厚度。通过具有单独的气泡阻挡区，当气泡阻挡层保持气体密封时，板提供增强的透水性。

7. 发明授权

US6010675A Method of and apparatus for removing carbon monoxide from gaseous media 失效
标题翻译：从气体介质中除去一氧化碳的方法和设备
公开(公告)号：US6010675A
公开(公告)日：2000-01-04
申请号：US853663
申请日：1992-03-19
申请人： John C. Trocciola , Craig R. Schroll , Roger R. Lesieur
发明人： John C. Trocciola , Craig R. Schroll , Roger R. Lesieur
IPC分类号： B01D53/86 , C01B3/58 , C10K3/04 , H01M8/06 , B01J8/00 , C01B31/18
CPC分类号： C01B3/583 , B01D53/864 , B01D53/8696 , C10K3/04 , H01M8/0662 , C01B2203/044 , C01B2203/047
摘要： The concentration of carbon monoxide in a gaseous medium is reduced by selective catalytic oxidation in the presence of gaseous oxygen by passing the gaseous medium through a catalyst capable of oxidizing carbon monoxide in an exothermic reaction at temperatures within a given temperature range and by controlling the temperatures encountered in the catalyst in such a manner that the exothermic reaction takes place first above a threshold temperature below which the catalyst would be rapidly inactivated at the relatively high carbon monoxide concentrations present in the gaseous medium as it enters the catalyst, and subsequently, after the carbon monoxide concentration has been reduced to an acceptable level, at less than the threshold temperature to further reduce the carbon monoxide concentration to a desired minimum level below that achievable at temperatures above the threshold temperature.
摘要翻译：气态介质中一氧化碳的浓度通过气态介质存在下的选择性催化氧化而降低，气态介质通过能够在给定温度范围内的温度下在放热反应中氧化一氧化碳的催化剂，并通过控制温度在催化剂中遇到，使得放热反应首先发生在高于阈值温度的阈值温度以下，在气体介质进入催化剂之前，催化剂将在气态介质中存在的相对较高的一氧化碳浓度下迅速失活，随后，在一氧化碳浓度已经降低到可接受的水平，低于阈值温度，以进一步将一氧化碳浓度降低到低于在高于阈值温度的温度下可实现的最低水平。

8. 发明授权

US4824739A Method of operating an electrochemical cell stack 失效
标题翻译：操作电化学电池堆的方法
公开(公告)号：US4824739A
公开(公告)日：1989-04-25
申请号：US115298
申请日：1987-11-02
申请人： Richard D. Breault , Michael J. Rajpolt , John C. Trocciola
发明人： Richard D. Breault , Michael J. Rajpolt , John C. Trocciola
IPC分类号： H01M8/02 , H01M8/24
CPC分类号： H01M8/0271 , H01M8/0297 , H01M8/2415 , Y02P70/56 , Y10T29/4911
摘要： A seal structure 60 for a porous plate of an electrochemical cell, such as plates 18, 20, includes a sealing material disposed in a seal region 66 of the plate to form a hydrophilic barrier to gas with an electrolyte and a hydrophobic layer 62 to block the loss of electrolyte from the hydrophilic layer is disclosed. Various construction details including a method for making the plate are disclosed which increase the cross pressure the sealing region of the plate can withstand. In one embodiment, the seal region 66 is impregnated with powder having a low structure and predetermined particle size using a pressurized liquid carrier. A FEP Teflon film bonds adjacent electrolyte reservoir plates together.
摘要翻译：用于诸如板18,20的电化学电池的多孔板的密封结构60包括设置在板的密封区域66中的密封材料，以形成与电解质和疏水层62阻挡气体的亲水屏障，以阻挡公开了来自亲水层的电解质的损失。公开了包括制造板的方法的各种构造细节，其增加了板的密封区域可承受的交叉压力。在一个实施例中，密封区域66使用加压液体载体浸渍具有低结构和预定粒度的粉末。 FEP聚四氟乙烯膜将相邻的电解质储存器板粘合在一起。

9. 发明授权

US4800052A Method of fabricating molten carbonate cathodes 失效
标题翻译：制造熔融碳酸盐阴极的方法
公开(公告)号：US4800052A
公开(公告)日：1989-01-24
申请号：US943232
申请日：1986-12-17
申请人： Thomas E. Swarr , John C. Trocciola
发明人： Thomas E. Swarr , John C. Trocciola
IPC分类号： H01M4/32 , H01M4/86 , H01M4/88 , H01M8/14 , C04B35/64
CPC分类号： H01M4/9016 , H01M4/32 , H01M4/8621 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： Molten carbonate fuel cell cathodes formed from a composition comprising oxides of nickel, lithium salts and barium salts having improved strength. These cathodes are fabricated by prefiring oxides of nickel and optionally lithium salts. The prefired powder is optionally leached with an organic acid and optional barium salts may be added. These powders are formed into an electrode and sintered. The resulting electrodes have improved strength.
摘要翻译：由包含具有改进的强度的镍，锂盐和钡盐的氧化物的组合物形成的熔融碳酸盐燃料电池阴极。这些阴极通过预处理镍和任选的锂盐的氧化物来制造。预制粉末任选地用有机酸浸出，并且可以加入任选的钡盐。将这些粉末形成电极并烧结。所得电极具有改善的强度。

10. 发明授权

US4695518A Silicon carbide matrix for fuel cells 失效
标题翻译：燃料电池用碳化硅基体
公开(公告)号：US4695518A
公开(公告)日：1987-09-22
申请号：US722176
申请日：1985-04-10
申请人： John C. Trocciola , Joseph Powers , Ronald G. Martin
发明人： John C. Trocciola , Joseph Powers , Ronald G. Martin
IPC分类号： H01M2/16 , H01M8/02 , H01M8/14
CPC分类号： H01M2/1646 , H01M8/0293 , H01M2300/0005
摘要： A matrix for holding the electrolyte within a phosphoric acid fuel cell is made from silicon carbide and a binder of polyestersulfone. Preferably the matrix consists of 10-20 weight percent polyethersulfone with a balance of silicon carbide. The matrix has improved strength, wettability and bubble pressure compared to the best known prior art matrix.
摘要翻译：在磷酸燃料电池内保持电解质的基质由碳化硅和聚酯砜的粘合剂制成。优选地，基质由10-20重量％的聚醚砜和余量的碳化硅组成。与最为已知的现有技术的基质相比，该基质具有改善的强度，润湿性和气泡压力。

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