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1. 发明授权

US07855236B2 Method to start a process for producing hydrocarbons from synthesis gas 有权
标题翻译：从合成气开始生产烃的方法
公开(公告)号：US07855236B2
公开(公告)日：2010-12-21
申请号：US12096412
申请日：2006-12-06
申请人： Robert Martijn Van Hardeveld , Hans Michiel Huisman , Lip Piang Kueh , Thomas Joris Remans
发明人： Robert Martijn Van Hardeveld , Hans Michiel Huisman , Lip Piang Kueh , Thomas Joris Remans
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译：开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性合成气转化为稳定状态，混合物流中的惰性气体的量减少。

2. 发明申请

US20080275144A1 Method to Start a Process for Producing Hydrocarbons from Synthesis Gas 有权
标题翻译：从合成气体开始生产碳氢化合物的方法
公开(公告)号：US20080275144A1
公开(公告)日：2008-11-06
申请号：US12096412
申请日：2006-12-06
申请人： Robert Martijn Van Hardeveld , Hans Michiel Huisman , Lip Piang Kueh , Thomas Joris Remans
发明人： Robert Martijn Van Hardeveld , Hans Michiel Huisman , Lip Piang Kueh , Thomas Joris Remans
IPC分类号： C07C1/04
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译：开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性合成气转化为稳定状态，混合物流中的惰性气体的量减少。

3. 发明授权

US09005538B2 Stacked catalyst bed for Fischer-Tropsch 有权
标题翻译：堆叠的费 - 托催化剂床
公开(公告)号：US09005538B2
公开(公告)日：2015-04-14
申请号：US13535040
申请日：2012-06-27
申请人： Robert Martijn Van Hardeveld , Thomas Joris Remans , Erwin Roderick Stobbe
发明人： Robert Martijn Van Hardeveld , Thomas Joris Remans , Erwin Roderick Stobbe
IPC分类号： B01J8/06 , B01J8/04 , C10G2/00 , B01J35/02 , B01J8/02 , B01J35/00 , B01J23/75
CPC分类号： C10G2/00 , B01J8/025 , B01J8/06 , B01J8/067 , B01J23/75 , B01J35/0006 , B01J35/026 , B01J2208/00672 , B01J2208/025 , B01J2219/00038 , B01J2219/0004
摘要： The invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5%-40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm-1, and the remaining catalyst particles have an average S/V of between 4.5 to 8.0 mm-1, and wherein the difference between the average S/V of the particles at the upstream end and the remaining fixed bed volume is at least 0.5 mm-1. Additionally the fixed bed volume at the upstream end shows a full-bed apparent catalytic activity per volume unit lower than the full-bed apparent catalytic activity per volume unit in the remaining fixed bed volume and/or the weight of catalytically active metal per weight unit at the upstream end is more than 70% lower than in the remaining fixed bed volume.
摘要翻译：本发明涉及一种包含费 - 托催化剂颗粒固定床的反应器管，其中上游端固定床体积的5％-40％的催化剂颗粒具有平均的外表面与体积比（S / V）为3.0〜4.5mm -1，剩余的催化剂粒子的平均S / V为4.5〜8.0mm -1，上游侧的粒子的平均S / V与剩余的固定床体积至少为0.5mm-1。此外，上游端的固定床体积显示出比在剩余固定床体积中每单位体积单体的全床视在催化活性和/或每重量单位的催化活性金属重量的每体积单位的全床表观催化活性在上游端比剩下的固定床体积低70％以上。

4. 发明授权

US07790648B2 Process for preparing a catalyst 有权
标题翻译：催化剂的制备方法
公开(公告)号：US07790648B2
公开(公告)日：2010-09-07
申请号：US11793671
申请日：2005-12-21
申请人： Ronald Jan Dogterom , Robert Martijn Van Hardeveld , Marinus Johannes Reynhout , Bastiaan Anton Van De Werff
发明人： Ronald Jan Dogterom , Robert Martijn Van Hardeveld , Marinus Johannes Reynhout , Bastiaan Anton Van De Werff
IPC分类号： B01J31/00 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C10G2/331 , B01J21/06 , B01J21/063 , B01J23/75 , B01J35/0053 , B01J35/1014 , B01J37/0009 , C10G2/33 , C10G2/332
摘要： The invention relates to a process for preparing a catalyst. The process allows the delamination of layered crystals which are used as a starting material for a catalyst. The starting material is subsequently converted into an active portion of a catalyst with an increased dispersion resulting in a higher activity. Preferred delaminating agents are di-carboxylic acids and one particular example is citric acid. Preferably at least 0.75 wt %, more preferably at least 1.5 wt % of a delaminating agent is added to the catalyst starting material.
摘要翻译：本发明涉及一种制备催化剂的方法。该方法允许用作催化剂原料的层状晶体的分层。随后将起始材料转化为催化剂的活性部分，其分散度增加，导致更高的活性。优选的分层剂是二羧酸，一个具体实例是柠檬酸。优选地，在催化剂原料中加入至少0.75重量％，更优选至少1.5重量％的脱层剂。

5. 发明申请

US20090234031A1 Multi stage fischer-tropsch process 有权
标题翻译：多级费托法
公开(公告)号：US20090234031A1
公开(公告)日：2009-09-17
申请号：US11988964
申请日：2006-07-14
申请人： Robert Martijn Van Hardeveld
发明人： Robert Martijn Van Hardeveld
IPC分类号： C07C27/00
CPC分类号： C01B3/36 , B01J23/76 , C01B2203/025 , C01B2203/062 , C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： A multi-stage process for the production of hydrocarbon products from syngas, each stage of the process comprising one or more syngas conversion reactors in which syngas is partially converted into hydrocarbon products at conversion conditions, each conversion reactor having a syngas entry stream system which system combines two or more entry streams of syngas and which system delivers the combined syngas to the syngas conversion reactor, the syngas entry system combining at least one entry stream of syngas being a syngas stream obtained in a partial oxidation process (for the first stage) or an exit stream of syngas from the previous stage, together with a reformed syngas (for all stages except the first stage), with another syngas stream being a recycle stream from the conversion reactor and a syngas exit stream system which discharges an exit stream of syngas from the reactor, the exit stream partly being used as the recycle stream to the syngas entry system as mentioned above, and, in the case that there is a further stage in the process, as feed for the next stage.
摘要翻译：用于从合成气生产烃产物的多阶段方法，该方法的每个阶段包括一个或多个合成气转化反应器，其中合成气在转化条件下部分转化为烃产物，每个转化反应器具有合成气进入流系统，该系统组合合成气的两个或更多个入口流，并且该系统将合并的合成气输送到合成气转化反应器，合成气进入系统将至少一个合成气进入流合并为在部分氧化过程（第一阶段）中获得的合成气流，或来自前一阶段的合成气的出口流，以及重整合成气（除第一阶段之外的所有阶段），另一种合成气流是来自转化反应器的再循环流和合成气出口流系统，其排出合成气的出口流来自反应器的出口流部分地用作如上所述的合成气进入系统的再循环流，在这个过程中还有一个进一步的阶段，作为下一阶段的饲料。

6. 发明授权

US06715546B2 In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore 失效
标题翻译：从含烃地层通过热源井筒原位生产合成气
公开(公告)号：US06715546B2
公开(公告)日：2004-04-06
申请号：US09841290
申请日：2001-04-24
申请人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , Ilya Emil Berchenko , George Leo Stegemeier , Robert Martijn Van Hardeveld
发明人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , Ilya Emil Berchenko , George Leo Stegemeier , Robert Martijn Van Hardeveld
IPC分类号： E21B4324
CPC分类号： C09K8/592 , E21B36/001 , E21B36/04 , E21B41/0057 , E21B43/24 , E21B43/2401 , E21B43/243 , E21B43/247 , E21B43/30 , Y02C10/14
摘要： A hydrocarbon containing formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. Production wells may be operated at selected temperatures to obtain a desired synthesis gas composition.
摘要翻译：可以使用原位热处理来处理含烃地层。碳氢化合物，H2和/或其他地层流体可以从地层中产生。可以将热量施加到地层以将地层的一部分的温度升高到合成气的产生温度。可以将合成气生产流体引入地层以产生合成气。生产井可以在选定的温度下运行以获得所需的合成气组成。

7. 发明授权

US07087191B2 Shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst 有权
标题翻译：壳金属催化剂及其前体，其制备方法和催化剂的用途
公开(公告)号：US07087191B2
公开(公告)日：2006-08-08
申请号：US10333889
申请日：2001-07-11
申请人： Robert Martijn Van Hardeveld , Carolus Matthias Anna Maria Mesters , Gerardus Petrus Lambertus Niesen
发明人： Robert Martijn Van Hardeveld , Carolus Matthias Anna Maria Mesters , Gerardus Petrus Lambertus Niesen
IPC分类号： B01J23/00 , C01C1/02 , C10K1/02
CPC分类号： C10G2/332 , B01J23/70 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J37/0221
摘要： A process for preparing a shell metal catalyst or a precursor of a shell metal catalyst which process includes the steps of: applying a slurry having a diluent; a catalytically active metal or a precursor compound thereof; and optionally a refractory oxide; designated hereinafter as “first refractory oxide” of an element having an atomic number of at least 20 or a precursor of the first refractory oxide; onto the surface of particles of a core carrier; forming a wet coating; and removing at least a part of the diluent from the wet coating; wherein the slurry has at least 5% w of the catalytically active metal or the precursor compound thereof; calculated on the weight of the metal relative to the weight of calcinations residue which can be formed from the slurry by drying the slurry and calcining. The invention also relates to a shell metal catalyst or a precursor of a shell metal catalyst which is obtainable by the process; and the use of the shell metal catalyst in a chemical conversion process. The invention also relates to a process for producing hydrocarbons; which process involves contacting a mixture of carbon monoxide and hydrogen with a shell metal catalyst, wherein the catalytically active metal is a Group VIII metal which is present at least partly in metallic form.
摘要翻译：一种制备壳金属催化剂或壳金属催化剂前体的方法，该方法包括以下步骤：施加具有稀释剂的浆料; 催化活性金属或其前体化合物; 和任选的耐火氧化物; 以下称为原子序数至少为20的元素或第一难熔氧化物的前体的“第一难熔氧化物” 到核心载体的颗粒的表面上; 形成湿涂层; 并从湿涂层中除去至少一部分稀释剂; 其中所述浆料具有至少5％w的催化活性金属或其前体化合物; 根据金属的重量相对于通过干燥浆料并煅烧可以由浆料形成的煅烧残余物的重量计算。本发明还涉及可通过该方法获得的壳金属催化剂或壳金属催化剂的前体; 以及在化学转化过程中使用壳金属催化剂。本发明还涉及一种生产烃的方法; 该方法包括将一氧化碳和氢气的混合物与壳金属催化剂接触，其中催化活性金属是至少部分以金属形式存在的VIII族金属。

8. 发明授权

US06761216B2 In situ thermal processing of a coal formation to produce hydrocarbon fluids and synthesis gas 失效
标题翻译：煤层的原位热处理生产烃类流体和合成气
公开(公告)号：US06761216B2
公开(公告)日：2004-07-13
申请号：US09841304
申请日：2001-04-24
申请人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , John Michael Karanikas , Ilya Emil Berchenko , George Leo Stegemeier , Ajay Madhav Madgavkar , Robert Martijn Van Hardeveld
发明人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , John Michael Karanikas , Ilya Emil Berchenko , George Leo Stegemeier , Ajay Madhav Madgavkar , Robert Martijn Van Hardeveld
IPC分类号： E21B4324
CPC分类号： E21B43/24 , C09K8/592 , E21B36/001 , E21B36/04 , E21B41/0057 , E21B43/2401 , E21B43/243 , E21B43/247 , E21B43/30 , Y02C10/14 , Y02P20/582 , Y10S48/06
摘要： A coal formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. After pyrolysis, the portion may be heated to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the portion to generate synthesis gas. Synthesis gas may be produced from the formation in a batch manner or in a substantially continuous manner.
摘要翻译：可以使用原位热处理来处理煤层。烃，H2和/或其他地层流体的混合物可以从地层中产生。可以将热量施加到地层以将地层的一部分的温度升高至热解温度。热解后，可将该部分加热至合成气产生温度。可以将合成气产生流体引入该部分以产生合成气。合成气体可以以间歇方式或基本上连续的方式由地层制备。

9. 发明授权

US06732796B2 In situ production of synthesis gas from a hydrocarbon containing formation, the synthesis gas having a selected H2 to CO ratio 失效
标题翻译：从含烃地层原位生产合成气，合成气具有选定的H 2至CO比
公开(公告)号：US06732796B2
公开(公告)日：2004-05-11
申请号：US09841311
申请日：2001-04-24
申请人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , Ilya Emil Berchenko , Robert Martijn Van Hardeveld
发明人： Harold J. Vinegar , Scott Lee Wellington , Eric Pierre de Rouffignac , Ilya Emil Berchenko , Robert Martijn Van Hardeveld
IPC分类号： C01B324
CPC分类号： E21B43/24 , C09K8/592 , E21B36/001 , E21B36/04 , E21B41/0057 , E21B43/2401 , E21B43/243 , E21B43/247 , E21B43/30 , Y02C10/14 , Y02P20/582 , Y10S48/06
摘要： A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. A portion of a formation may be heated from a plurality of heat sources to a temperature sufficient to allow generation of a first synthesis gas having a low H2 to CO ratio. A second portion of a formation may generate synthesis gas having a H2 to CO ratio greater than the first synthesis gas. A portion of the first synthesis gas may be blended with a portion of the second synthesis gas to produce a blend synthesis gas having a desired H2 to CO ratio.
摘要翻译：可以使用原位热处理来处理含烃地层。烃，H2和/或其他地层流体的混合物可以从地层中产生。可以将热量施加到地层以将地层的一部分的温度升高至热解温度。地层的一部分可以从多个热源加热到足以产生具有低H 2至CO比率低的第一合成气的温度。地层的第二部分可以产生具有大于第一合成气的H 2至CO比的合成气。第一合成气的一部分可与第二合成气的一部分共混以产生具有所需H 2至CO比的共混合成气。

10. 发明授权

US06609570B2 In situ thermal processing of a coal formation and ammonia production 失效
公开(公告)号：US06609570B2
公开(公告)日：2003-08-26
申请号：US09841131
申请日：2001-04-24
申请人： Scott Lee Wellington , Harold J. Vinegar , Eric Pierre de Rouffignac , Ilya Emil Berchenko , Kevin Albert Maher , John Michael Ward , Robert Martijn Van Hardeveld
发明人： Scott Lee Wellington , Harold J. Vinegar , Eric Pierre de Rouffignac , Ilya Emil Berchenko , Kevin Albert Maher , John Michael Ward , Robert Martijn Van Hardeveld
IPC分类号： C01C104
CPC分类号： E21B43/24 , C09K8/592 , E21B36/001 , E21B36/04 , E21B41/0057 , E21B43/2401 , E21B43/243 , E21B43/247 , E21B43/30 , Y02C10/14 , Y02P20/582 , Y10S48/06
摘要： A coal formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas generating fluid may be introduced into the portion. Synthesis gas may be produced from the formation Synthesis gas may be used as a feed stream in an ammonia synthesis process. Ammonia may be used as a feed stream in a urea synthesis process.

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