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1. 发明授权

US5858208A Methods for improving conversion in fluidized catalytic cracking units 失效
标题翻译：改善流化催化裂化装置转化率的方法
公开(公告)号：US5858208A
公开(公告)日：1999-01-12
申请号：US858178
申请日：1997-02-25
申请人： Robert L. Flanders , Roy W. Greenlee , George G. Duggan , Michael J. Zetlmeisl
发明人： Robert L. Flanders , Roy W. Greenlee , George G. Duggan , Michael J. Zetlmeisl
IPC分类号： C10G11/05 , C10G11/18 , C10G11/00
CPC分类号： C10G11/05 , C10G11/18 , Y10S502/516 , Y10S502/521
摘要： The present invention, therefore, is directed to a novel method for improving conversion in a fluidized catalytic cracking unit feed stream containing vanadium. According to the method, an effective amount of a composition comprising at least one overbase complex of a magnesium or aluminum salt or a mixture thereof and an organic acid complexing agent is incorporated into the feed stream.
摘要翻译：因此，本发明涉及一种用于改善流化催化裂化装置含钒的进料流中的转化率的新方法。根据该方法，将有效量的包含至少一种镁盐或铝盐的高碱性配合物或其混合物和有机酸络合剂的组合物掺入进料流中。

2. 发明授权

US4204945A Removing pollutants from flue gas in nonzeolitic catalytic cracking 失效
标题翻译：在非沸石催化裂化中除去废气中的污染物
公开(公告)号：US4204945A
公开(公告)日：1980-05-27
申请号：US923427
申请日：1978-07-10
申请人： Robert L. Flanders , William A. Blanton, Jr.
发明人： Robert L. Flanders , William A. Blanton, Jr.
IPC分类号： B01D53/50 , B01D53/86 , C10G11/18 , B01J29/06 , C01B17/00
CPC分类号： C10G11/18 , B01D53/508 , B01D53/8609 , B01D53/864 , Y10S502/517
摘要： Carbon monoxide and sulfur oxides are removed from flue gas produced in a catalyst regenerator in an FCC system and sulfur from the flue gas is shifted to form hydrogen sulfide, which is recovered in the gases removed from the cracking reactor in the system by introducing sufficient molecular oxygen into the catalyst regenerator to provide an atmosphere therein having a molecular oxygen concentration of at least 0.1 volume percent, reacting carbon monoxide in the regenerator flue gas with oxygen in contact with a particulate carbon monoxide combustion promoter physically admixed with the cracking catalyst, reacting sulfur oxides in the regenerator flue gas with silica-free alumina included as a discrete phase in the FCC catalyst to form a sulfur-containing solid in the catalyst, and forming hydrogen sulfide in the cracking reactor by contacting the sulfur-containing solid with the hydrocarbon feed.
摘要翻译：一氧化碳和硫氧化物从在FCC系统中的催化剂再生器中产生的烟道气中除去，并且来自烟道气的硫被转移以形成硫化氢，其通过引入足够的分子引入体系中从裂解反应器中除去的气体中回收将氧气输入到催化剂再生器中以提供其中分子氧浓度为至少0.1体积％的气氛，使再生器烟道气中的一氧化碳与与物理混合的裂化催化剂的颗粒一氧化碳燃烧促进剂接触的氧反应，使硫在FCC催化剂中作为离散相包含在二氧化硅不含氧化铝的再生器烟气中的氧化物在催化剂中形成含硫固体，并通过使含硫固体与烃进料接触形成硫化氢。

3. 发明授权

US4332672A Process for controlling sulfur oxides using an alumina-impregnated catalyst 失效
标题翻译：使用氧化铝浸渍催化剂控制硫氧化物的方法
公开(公告)号：US4332672A
公开(公告)日：1982-06-01
申请号：US923428
申请日：1978-07-10
申请人： William A. Blanton, Jr. , Robert L. Flanders
发明人： William A. Blanton, Jr. , Robert L. Flanders
IPC分类号： B01D53/50 , B01J21/20 , C10G11/18 , B01J29/06 , C01B17/00
CPC分类号： B01J21/20 , B01D53/508 , C10G11/18 , Y10S502/517
摘要： Sulfur oxides are removed from flue gas in a catalyst regenerator in a fluid catalyst cracking system while liquid-hydrocarbon product yield from the system is maintained at a high level by heating a nonzeolitic, silica-containing catalyst to 800.degree.-1500.degree. F.; impregnating 0.1 to 25 weight percent aluminum onto the catalyst particles; and cycling the resulting particles through the cracking reactor and catalyst regenerator in the cracking system, the impregnated catalyst being particularly adaptable for cracking heavy, metals-containing feeds such as residua.
摘要翻译：在流化催化裂化系统中的催化剂再生器中，从烟道气中除去硫氧化物，同时通过将非沸石，含二氧化硅的催化剂加热至800-1500°，将体系的液烃产物产率保持在高水平。将0.1至25重量％的铝浸渍到催化剂颗粒上; 并且将所得到的颗粒循环通过裂解反应器和裂化系统中的催化剂再生器，所述浸渍的催化剂特别适用于破裂含重金属的进料如残渣。

4. 发明授权

US4259176A Restricting silica content of catalyst inventory to prevent alumina poisoning for SO.sub.x control 失效
标题翻译：限制二氧化硅含量的催化剂库存，以防止氧化铝中毒的SOx控制
公开(公告)号：US4259176A
公开(公告)日：1981-03-31
申请号：US74838
申请日：1979-09-13
申请人： William A. Blanton , Robert L. Flanders
发明人： William A. Blanton , Robert L. Flanders
IPC分类号： B01D53/50 , B01D53/81 , B01D53/86 , B01J21/04 , B01J29/90 , C01B17/16 , C10G11/00 , C10G11/05 , C10G11/18
CPC分类号： B01J29/90 , B01D53/8609 , C10G11/05 , C10G11/18 , Y10S502/517
摘要： Removal of sulfur oxides from cracking catalyst regenerator flue gas using particulate alumina is enhanced by employing a zeolitic cracking catalyst containing little or no silica in the catalyst matrix.
摘要翻译：通过使用在催化剂基体中含有很少或不含二氧化硅的沸石裂化催化剂，可以增加使用颗粒氧化铝从裂化催化剂再生器烟道气中除去硫氧化物。

5. 发明授权

US4152298A Catalyst for removing sulfur from a gas 失效
标题翻译：催化剂从气体中去除硫
公开(公告)号：US4152298A
公开(公告)日：1979-05-01
申请号：US872514
申请日：1978-01-26
申请人： William A. Blanton, Jr. , Robert L. Flanders
发明人： William A. Blanton, Jr. , Robert L. Flanders
IPC分类号： B01D53/86 , B01D53/50 , B01J29/06 , B01J29/08 , B01J29/90 , C01B17/16 , C10G11/18
CPC分类号： B01D53/508 , C10G11/18
摘要： Sulfur oxides are removed from a gas and the sulfur is converted to hydrogen sulfide by the steps of: (1) reacting sulfur oxides in the gas with alumina to form a solid sulfur-containing compound and remove sulfur oxides from the gas; and (2) contacting the solid compound resulting from step (1) with a hydrocarbon at a temperature of about 800.degree.-1300.degree. F. and reacting the solid sulfur-containing compound with components of the hydrocarbon to form hydrogen sulfide.

6. 发明授权

US4115251A Process for removing pollutants from catalyst regenerator flue gas 失效
标题翻译：从催化剂再生器烟气中去除污染物的工艺
公开(公告)号：US4115251A
公开(公告)日：1978-09-19
申请号：US786724
申请日：1977-04-11
申请人： Robert L. Flanders , William A. Blanton, Jr.
发明人： Robert L. Flanders , William A. Blanton, Jr.
IPC分类号： B01D53/86 , B01D53/50 , B01J29/06 , B01J29/08 , B01J29/90 , C01B17/16 , C10G11/18 , C10G11/02 , C01B17/00
CPC分类号： B01D53/508 , C10G11/18
摘要： Carbon monoxide and sulfur oxides are removed from flue gas produced in a catalyst regenerator in an FCC system and sulfur from the flue gas is shifted to form hydrogen sulfide, which is recovered in the gases removed from the cracking reactor in the system by reacting carbon monoxide in the regenerator flue gas with oxygen in contact with a particulate carbon monoxide combustion promoter, reacting sulfur oxides in the regenerator flue gas with particulate alumina physically mixed with the FCC catalyst to form a sulfur-containing solid, and forming hydrogen sulfide in the cracking reactor by contacting the sulfur-containing solid with the hydrocarbon feed.
摘要翻译：一氧化碳和硫氧化物从在FCC系统中的催化剂再生器中产生的烟道气中除去，并且来自烟道气的硫被转移以形成硫化氢，其在系统中从裂解反应器中除去的气体中回收，通过使一氧化碳在具有氧气的再生器烟道气中与颗粒一氧化碳燃烧促进剂接触，将再生器烟道气中的硫氧化物与与FCC催化剂物理混合的颗粒氧化铝反应以形成含硫固体，并在裂解反应器中形成硫化氢通过使含硫固体与烃进料接触。

7. 发明授权

US4115249A Process for removing sulfur from a gas 失效
标题翻译：从气体中除去硫的方法
公开(公告)号：US4115249A
公开(公告)日：1978-09-19
申请号：US751640
申请日：1976-12-17
申请人： William A. Blanton, Jr. , Robert L. Flanders
发明人： William A. Blanton, Jr. , Robert L. Flanders
IPC分类号： B01D53/86 , B01D53/50 , B01J29/06 , B01J29/08 , B01J29/90 , C01B17/16 , C10G11/18 , C10G11/02 , C01B17/00
CPC分类号： B01D53/508 , C10G11/18
摘要： Sulfur oxides are removed from flue gas in a catalyst regenerator in a fluid catalyst cracking system while liquid-hydrocarbon product yield from the system is maintained at a high level by heating a particulate silica-containing cracking catalyst to 800-1500.degree. F; impregnating 0.1 to 25 weight percent aluminum onto the catalyst particles; and cycling the resulting particles through the cracking reactor and catalyst regenerator in the cracking system.
摘要翻译：在催化剂再生器中，在流化催化剂裂解系统中，从烟道气中除去硫氧化物，同时通过将含微粒二氧化硅的裂化催化剂加热至800-1500°F，将体系的液烃产物产率维持在高水平; 将0.1至25重量％的铝浸渍到催化剂颗粒上; 并将所得颗粒循环通过裂解反应器和裂解系统中的催化剂再生器。

8. 发明授权

US4435272A Process for upgrading crude oil and residual fractions thereof by vaporizing the charge in a falling curtain of contact particles 失效
$Process for upgrading crude oil and residual fractions thereof by vaporizing the charge in a falling curtain of contact particles$
标题翻译：通过在下降的接触颗粒幕中蒸发电荷来提高原油及其残余馏分的方法
公开(公告)号：US4435272A
公开(公告)日：1984-03-06
申请号：US369056
申请日：1982-04-16
申请人： David B. Bartholic , Robert L. Flanders
发明人： David B. Bartholic , Robert L. Flanders
IPC分类号： C10G9/30 , C10G25/00 , C10G31/06 , C10G9/42
CPC分类号： C10G25/00 , C10G31/06 , C10G9/30
摘要： A process for upgrading a petroleum charge of crude oil or residual fractions thereof, in which the charge is dispersed into a descending curtain of heated, substantially inert contact material. This contact material preferably has a conversion rate not substantially greater than 10% in the CAT D test. The vapors generated on contact of the charge with the curtain are collected on the side of the curtain opposite from where the charge is dispersed. The recovered product has a substantially reduced metals content and Conradson Carbon number and is suitable for catalytic cracking or use as heavy fuel or a heavy fuel precursor.
摘要翻译：用于升级原油或其残余馏分的石油装料的方法，其中电荷分散到加热的基本上惰性的接触材料的下降帘中。该接触材料优选在CAT D试验中的转化率基本上不大于10％。电荷与窗帘的接触产生的蒸气被收集在与电荷分散的地方相反的一侧。回收的产品具有显着降低的金属含量和康拉逊碳数，并且适用于催化裂化或用作重质燃料或重质燃料前体。

9. 发明授权

US4204944A Process for removing pollutants from nonzeolitic catalyst regenerator flue gas 失效
标题翻译：从非沸石催化剂再生器烟气中去除污染物的工艺
公开(公告)号：US4204944A
公开(公告)日：1980-05-27
申请号：US923426
申请日：1978-07-10
申请人： Robert L. Flanders , William A. Blanton, Jr.
发明人： Robert L. Flanders , William A. Blanton, Jr.
IPC分类号： B01D53/50 , B01D53/86 , C10G11/18 , B01J29/06 , C01B17/00
CPC分类号： B01D53/8609 , B01D53/508 , B01D53/864 , C10G11/18 , Y10S502/517
摘要： Carbon monoxide and sulfur oxides are removed from catalyst regenerator flue gas in an FCC system using a nonzeolitic cracking catalyst and sulfur from the flue gas is shifted to form hydrogen sulfide, which is recovered in the gases removed from the cracking reactor in the system by reacting carbon monoxide in the regenerator flue gas with oxygen in contact with a particulate carbon monoxide combustion promoter, reacting sulfur oxides in the regenerator flue gas with particulate alumina physically mixed with the nonzeolitic catalyst to form a sulfur-containing solid, and forming hydrogen sulfide in the cracking reactor by contacting the sulfur-containing solid with the hydrocarbon feed.
摘要翻译：一氧化碳和硫氧化物在使用非沸石裂化催化剂的FCC系统中从催化剂再生器烟道气中除去，并且来自烟道气的硫被转移以形成硫化氢，其在系统中从裂解反应器中除去的气体中回收，通过反应再生器烟气中的一氧化碳与氧与颗粒一氧化碳燃烧促进剂接触，使再生器烟道气中的硫氧化物与与非沸石催化剂物理混合的颗粒氧化铝反应，形成硫化氢通过使含硫固体与烃进料接触来开裂反应器。

10. 发明授权

US4115250A Method for removing pollutants from catalyst regenerator flue gas 失效
标题翻译：从催化剂再生器烟气中去除污染物的方法
公开(公告)号：US4115250A
公开(公告)日：1978-09-19
申请号：US786723
申请日：1977-04-11
申请人： Robert L. Flanders , William A. Blanton, Jr.
发明人： Robert L. Flanders , William A. Blanton, Jr.
IPC分类号： B01D53/86 , B01D53/50 , B01J29/06 , B01J29/08 , B01J29/90 , C01B17/16 , C10G11/18 , C10G11/02
CPC分类号： B01D53/508 , C10G11/18
摘要： Carbon monoxide and sulfur oxides are removed from flue gas produced in a catalyst regenerator in an FCC system and sulfur from the flue gas is shifted to form hydrogen sulfide, which is recovered in the gases removed from the cracking reactor in the system by introducing sufficient molecular oxygen into the catalyst regenerator to provide an atmosphere therein having a molecular oxygen concentration of at least 0.1 volume percent, reacting carbon monoxide in the regenerator flue gas with oxygen in contact with a particulate carbon monoxide combustion promoter physically admixed with the cracking catalyst, reacting sulfur oxides in the regenerator flue gas with silica-free alumina included as a discrete phase in the FCC catalyst to form a sulfur-containing solid in the catalyst, and forming hydrogen sulfide in the cracking reactor by contacting the sulfur-containing solid with the hydrocarbon feed.
摘要翻译：一氧化碳和硫氧化物从在FCC系统中的催化剂再生器中产生的烟道气中除去，并且来自烟道气的硫被转移以形成硫化氢，其通过引入足够的分子引入体系中从裂解反应器中除去的气体中回收将氧气输入到催化剂再生器中以提供其中分子氧浓度为至少0.1体积％的气氛，使再生器烟道气中的一氧化碳与与物理混合的裂化催化剂的颗粒一氧化碳燃烧促进剂接触的氧反应，使硫在FCC催化剂中作为离散相包含在二氧化硅不含氧化铝的再生器烟气中的氧化物在催化剂中形成含硫固体，并通过使含硫固体与烃进料接触形成硫化氢。

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