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    • 5. 发明授权
    • Column holder for on-column photometric detection
    • 色谱柱用于柱上光度检测
    • US4854700A
    • 1989-08-08
    • US207699
    • 1988-06-15
    • Sergio S. CutieMartin A. LanghorstStewart P. Wood
    • Sergio S. CutieMartin A. LanghorstStewart P. Wood
    • G01N30/60G01N30/74
    • G01N30/74G01N30/6047
    • A column holder for on-column photometric detection capillary liquid chromatography incorporating a body and a pair of straight edges attached to the body. The straight edges can be conveniently made from a razor blade. The body has two passageways through it that are transverse and intersecting. The first passageway is dimensioned so that a capillary column can be slipped into it or removed from it by hand. The other passageway is for the passage of a light beam from a liquid chromatography photometric detector. The straight edges are slightly separated to form an optical slit in front of the capillary column and are securely clamped to the body of the column holder. A capillary column can be removed from the column holder and be replaced with another capillary column without damaging it and without the necessity of repositioning the slit.
    • 用于柱内光度检测毛细管液相色谱柱的柱保持器,其包含主体和附接到身体的一对直边。 直边可以方便地用剃刀刀片制成。 身体有两条通过它的横向和相交的通道。 第一个通道的尺寸设计使得毛细管柱可以滑入其中或用手从其中移除。 另一个通道用于通过来自液相色谱测光检测器的光束。 直边缘稍微分开,在毛细管柱前面形成一个光学狭缝,并牢固地夹在柱保持器的主体上。 毛细管柱可以从柱保持器中取出,并用另一个毛细管柱替换,而不会损坏毛细管柱,无需重新定位狭缝。
    • 6. 发明授权
    • High performance analytical column for anion determination
    • 用于阴离子测定的高性能分析柱
    • US4519905A
    • 1985-05-28
    • US626569
    • 1984-07-02
    • Timothy S. StevensMartin A. Langhorst
    • Timothy S. StevensMartin A. Langhorst
    • B01D15/08B01J20/286B01J41/20G01N30/56G01N30/96
    • B01J20/286B01J20/3221B01J41/20G01N30/56G01N30/96B01J2220/54B01J2220/58
    • An improved chromatographic analytical column, the column containing a pellicular type (agglomerated) anion-exchange packing, comprising:Component A, which comprises a pressure packed bed of substrate particles of insoluble synthetic resin, having cation-exchanging sites at least on their available surfaces, the Component A particles being of low porosity relative to Component B microparticles, described below, andComponent B, derived by agglomerating microparticles of insoluble synthetic resin onto the pressure packed bed of Component A particles, the microparticles having a volume average diameter of less than about 1,500 and greater than about 50 Angstroms and having anion-exchanging sites, at least on their outer surfaces, which attract available cation sites of Component A, wherein the microparticles of Component B are attached as a monolayer to the available surfaces of the Component A particles.
    • 一种改进的色谱分析柱,该柱包含薄膜型(聚集)阴离子交换填料,其包含:组分A,其包含不溶性合成树脂的基质颗粒的压力填充床,至少在其可用表面上具有阳离子交换位点 组分A颗粒相对于下述组分B微粒具有低孔隙率,以及组分B,其通过将不溶性合成树脂的微粒聚集到组分A颗粒的加压填充床上而得到,微粒的体积平均直径小于 至少在其外表面上具有阴离子交换位点,其吸引组分A的可用阳离子位点,其中组分B的微粒以单层的形式附着到组分A的可用表面上 粒子。