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    • 2. 发明授权
    • Catalyst configuration for catalytic combustion systems
    • 用于催化燃烧系统的催化剂配置
    • US5474441A
    • 1995-12-12
    • US22248
    • 1993-02-25
    • Robert J. FarrautoJennifer S. FeeleyDianne O. SimoneYiu K. LuiTeresa Kennelly
    • Robert J. FarrautoJennifer S. FeeleyDianne O. SimoneYiu K. LuiTeresa Kennelly
    • B01J23/10F23C13/00F23R3/40F23D3/40
    • F23C13/00F23C13/08F23R3/40
    • A catalyst bed (30) for a combustor (18) for supporting the catalytic combustion of a gaseous air/fuel (e.g., methane or natural gas) combustion mixture contains an igniter catalyst member (1) upstream of a promoter catalyst member (2). The catalyst members each comprise carrier monoliths, the igniter catalyst member (1) having an igniter catalyst material deposited thereon and the promoter catalyst member (2) having a promoter catalyst material deposited thereon. The igniter catalyst material is distinguished from the promoter catalyst material in one or more of the following ways: the igniter catalyst material may have (a) a higher catalytic activity for combustion of the air/fuel mixture, (b) a lower catalyst deactivation temperature than the promoter catalyst material, and/or (c) the promoter catalyst regeneration temperature range brackets the upper limit of the regeneration temperature range of the igniter catalyst.
    • 用于支撑气态空气/燃料(例如,甲烷或天然气)燃烧混合物的催化燃烧的燃烧器(18)的催化剂床(30)在促进剂催化剂构件(2)的上游含有点火器催化剂构件(1) 。 催化剂构件各自包括载体整料,其上沉积有点火器催化剂材料的点火器催化剂构件(1)和其上沉积有助催化剂材料的助催化剂构件(2)。 点火器催化剂材料以一种或多种以下方式与助催化剂材料不同:点火器催化剂材料可具有(a)对于空气/燃料混合物燃烧的较高催化活性,(b)较低的催化剂失活温度 和/或(c)助催化剂催化剂再生温度范围包括点火器催化剂的再生温度范围的上限。
    • 10. 发明授权
    • Lean NO.sub.x catalyst/trap method
    • 精益NOx催化剂/捕集法
    • US5874057A
    • 1999-02-23
    • US500657
    • 1995-07-12
    • Michel DeebaJennifer S. FeeleyRobert J. Farrauto
    • Michel DeebaJennifer S. FeeleyRobert J. Farrauto
    • B01D53/86B01D53/94B01J23/58B01J23/63B01J23/648B01J23/652B01D53/56
    • B01D53/9422B01J23/58B01J23/63B01D2255/102B01D2255/202B01D2255/204B01D2255/902B01D2255/91F01N2570/16
    • A NO.sub.x abatement composition comprises a NO.sub.x abatement catalyst and a NO.sub.x sorbent material which are dispersed in proximity to, but segregated from, each other on a common refractory carrier member (10). The NO.sub.x sorbent material comprises a basic oxygenated metal compound and optionally further comprises ceria. The NO.sub.x abatement catalyst contains a catalytic metal component including a platinum metal catalytic component. The catalytic metal component is segregated from the NO.sub.x sorbent material, which may be one or more of metal oxides, metal carbonates, metal hydroxides and mixed metal oxides. At least the catalytic metal component and the NO.sub.x sorbent material must be on, or comprise separate, particles; the particles may either be admixed or may be disposed in separate layers (20a, 20b) on the carrier member (10). A NO.sub.x abatement method employs the composition and includes periodically adjusting the gas being treated between lean and stoichiometric/rich operating cycles.
    • NOx消除组合物包括在普通耐火材料承载构件(10)上分散在彼此附近但彼此分离的NOx消除催化剂和NOx吸附剂材料。 NOx吸附剂材料包含碱性氧化金属化合物,并且任选地还包含二氧化铈。 NOx消除催化剂含有包含铂金属催化组分的催化金属成分。 催化金属组分与NO x吸附剂材料分离,其可以是金属氧化物,金属碳酸盐,金属氢氧化物和混合金属氧化物中的一种或多种。 至少催化金属组分和NOx吸附剂材料必须在或包含分开的颗粒; 可以将颗粒混合或者可以设置在载体构件(10)上的分开的层(20a,20b)中。 NOx减排方法采用该组合物并且包括周期性地调节在稀薄和理论空燃比/丰富的操作循环之间被处理的气体。