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1. 发明授权

US06906317B2 Ion detector 有权
标题翻译：离子检测器
公开(公告)号：US06906317B2
公开(公告)日：2005-06-14
申请号：US10733925
申请日：2003-12-11
申请人： Robert Harold Bateman , Jeff Brown , Daniel James Kenny
发明人： Robert Harold Bateman , Jeff Brown , Daniel James Kenny
IPC分类号： B01D59/44 , G01K1/08 , H01J49/00
CPC分类号： H01J43/246
摘要： An ion detector for a mass spectrometer is disclosed comprising one or more microchannel plates and an anode arranged to receive electrons emitted from the one or more microchannel plates. The anode is permanently magnetized and electrons emitted from the microchannel plates preferably spiral around lines of magnetic field towards the anode.
摘要翻译：公开了一种用于质谱仪的离子检测器，其包括一个或多个微通道板和布置成接收从一个或多个微通道板发射的电子的阳极。阳极被永久磁化，并且从微通道板发射的电子优选地绕着磁场线向着阳极旋转。

2. 发明授权

US07199363B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US07199363B2
公开(公告)日：2007-04-03
申请号：US10964791
申请日：2004-10-14
申请人： Robert Harold Bateman , Jeffery Mark Brown , Daniel James Kenny
发明人： Robert Harold Bateman , Jeffery Mark Brown , Daniel James Kenny
IPC分类号： B01D59/44 , H01J49/00
CPC分类号： H01J49/405 , H01J49/0031
摘要： A mass spectrometer is disclosed comprising an ion source 4, a field free or drift region 5 and an ion mirror 7 comprising a reflectron. Metastable parent ions which spontaneously fragment by Post Source Decay whilst passing through the field free or drift region 5 are arranged to enter the ion mirror 7 and be reflected by the reflectron towards an ion detector 8 when the reflectron is maintained at a certain voltage. The process is then repeated with the reflectron being maintained at a slightly lower voltage. Two related sets of time of flight or mass spectral data are obtained for the two different voltage settings of the reflectron. From the two data sets the different times of flight for the same species of fragment ion can be determined. The mass to charge ratio of the parent ion which fragmented to produce the particular species of fragment ion can then be determined from the times of flight of the fragment ions.
摘要翻译：公开了一种质谱仪，其包括离子源4，无场或漂移区5以及包括反射镜的离子镜7。当通过场自由或漂移区域5时通过后源衰变自发分裂的亚稳态亲本离子被布置成当反射器保持在一定电压时进入离子反射镜7并被反射器反射离子检测器8。然后重复该过程，其中反射器保持在稍低的电压。对于反射镜的两个不同的电压设置，获得两组相关的飞行时间或质谱数据。从两个数据集可以确定相同种类的碎片离子的不同飞行时间。然后可以从片段离子的飞行时间确定碎片化以产生特定种类的碎片离子的母体离子的质荷比。

3. 发明授权

US08633435B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US08633435B2
公开(公告)日：2014-01-21
申请号：US12445774
申请日：2007-10-16
申请人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
发明人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
IPC分类号： H01J49/42 , H01J49/00 , H01J49/06
CPC分类号： H01J49/005 , H01J49/0031 , H01J49/004 , H01J49/0045 , H01J49/065 , H01J49/34 , H01J49/4235
摘要： A collision or fragmentation cell is disclosed comprising a plurality of electrodes wherein a first RF voltage is applied to an upstream group of electrodes and a second different RF voltage is applied to a downstream group of electrodes. The radial confinement of parent ions entering the collision or fragmentation cell is optimized by the first RF voltage applied to the upstream group of electrodes and the radial confinement of daughter or fragment ions produced within the collision or fragmentation cell is optimized by the second different RF voltage applied to the downstream group of electrodes.
摘要翻译：公开了包括多个电极的碰撞或分裂单元，其中将第一RF电压施加到上游电极组，并且将第二不同的RF电压施加到下游电极组。通过施加到上游电极组的第一RF电压来优化进入碰撞或破碎电池的母体离子的径向约束，并且通过第二不同RF电压优化在碰撞或断裂电池内产生的子或碎片离子的径向约束应用于下游电极组。

4. 发明申请

US20100294923A1 MASS SPECTROMETER 有权
标题翻译：质谱仪
公开(公告)号：US20100294923A1
公开(公告)日：2010-11-25
申请号：US12445774
申请日：2007-10-16
申请人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
发明人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
IPC分类号： H01J49/26 , H01J49/06
CPC分类号： H01J49/005 , H01J49/0031 , H01J49/004 , H01J49/0045 , H01J49/065 , H01J49/34 , H01J49/4235
摘要： A collision or fragmentation cell (4) is disclosed comprising a plurality of electrodes wherein a first RF voltage (7a) is applied to an upstream group of electrodes and a second different RF voltage (7b) is applied to a downstream group of electrodes. The radial confinement of parent ions entering the collision or fragmentation cell (4) is optimised by the first RF voltage applied to the upstream group of electrodes and the radial confinement of daughter or fragment ions produced within the collision or fragmentation cell (4) is optimised by the second different RF voltage applied to the downstream group of electrodes.
摘要翻译：公开了一种碰撞或分裂单元（4），其包括多个电极，其中将第一RF电压（7a）施加到上游电极组，并且将第二不同RF电压（7b）施加到下游电极组。通过施加到上游电极组的第一RF电压来优化进入碰撞或破碎电池（4）的母体离子的径向约束，并且优化在碰撞或断裂电池（4）内产生的子或碎片离子的径向约束通过施加到下游组电极的第二不同RF电压。

5. 发明授权

US07087897B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US07087897B2
公开(公告)日：2006-08-08
申请号：US10797242
申请日：2004-03-10
申请人： Robert Harold Bateman , Jeff Brown
发明人： Robert Harold Bateman , Jeff Brown
IPC分类号： H01J49/40
CPC分类号： H01J49/401
摘要： A mass spectrometer is disclosed comprising an electric field region L2 wherein a time-varying electric field is applied thereto. In a mode of operation a pulse of ions 3 comprising ions having different mass to charge ratios passes through the electric field region L2 and the electric field is varied with time such that at least some of the ions 3 having different mass to charge ratios subsequently arrive at the extraction or acceleration region 10 of a Time of Flight mass analyser at substantially the same time.
摘要翻译：公开了一种质谱仪，其包括施加时变电场的电场区域L 2。在操作模式中，包含不同质荷比的离子的离子3的脉冲通过电场区L 2，并且电场随时间而变化，使得至少一些离子3 具有不同的质荷比随后在几乎相同的时间到达飞行时间质量分析仪的提取或加速区域10。

6. 发明授权

US06794642B2 Mass spectrometer 有权
公开(公告)号：US06794642B2
公开(公告)日：2004-09-21
申请号：US10636811
申请日：2003-08-08
申请人： Robert Harold Bateman , Jeff Brown
发明人： Robert Harold Bateman , Jeff Brown
IPC分类号： H01J4926
CPC分类号： H01J49/42 , H01J49/004
摘要： A mass spectrometer is disclosed comprising at least first and second ion traps which are arranged in series. A relatively high AC or RF voltage is applied to the electrodes forming the first ion trap in order to improve the trapping of energetic or high mass to charge ratio ions. The relatively high AC or RF voltage applied to the first ion trap also has the effect of raising the low mass cut-off of the first ion trap. The second ion trap, arranged downstream of the first ion trap, is arranged to have a lower low mass cut-off than the first ion trap, and hence ions which are not trapped in the first ion trap are trapped in the second ion trap.

7. 发明授权

US07205538B2 Mass spectrometer 有权
公开(公告)号：US07205538B2
公开(公告)日：2007-04-17
申请号：US11472278
申请日：2006-06-22
申请人： Robert Harold Bateman , Kevin Giles , John Brian Hoyes , Steve Pringle , Jeff Brown
发明人： Robert Harold Bateman , Kevin Giles , John Brian Hoyes , Steve Pringle , Jeff Brown
IPC分类号： H01J49/40
CPC分类号： H01J49/4225
摘要： A mass spectrometer is disclosed comprising an ion trap wherein ions which have been temporally separated according to their mass to charge ratio or ion mobility enter the ion trap. Once at least some of the ions have entered the ion trap, a plurality of ion trapping regions are created along the length of the ion trap in order to fractionate the ions. Alternatively, the ions may be received within one or more axial trapping regions which are translated along the ion trap with a velocity which is progressively reduced to zero.

8. 发明授权

US07071467B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US07071467B2
公开(公告)日：2006-07-04
申请号：US10633702
申请日：2003-08-05
申请人： Robert Harold Bateman , Kevin Giles , John Brian Hoyes , Steve Pringle , Jeff Brown
发明人： Robert Harold Bateman , Kevin Giles , John Brian Hoyes , Steve Pringle , Jeff Brown
IPC分类号： H01J49/40
CPC分类号： H01J49/4225
摘要： A mass spectrometer is disclosed comprising an ion trap wherein ions which have been temporally separated according to their mass to charge ratio or ion mobility enter the ion trap. Once at least some of the ions have entered the ion trap, a plurality of ion trapping regions are created along the length of the ion trap in order to fractionate the ions. Alternatively, the ions may be received within one or more axial trapping regions which are translated along the ion trap with a velocity which is progressively reduced to zero.
摘要翻译：公开了一种质谱仪，其包括离子阱，其中根据其质荷比或离子迁移率暂时分离的离子进入离子阱。一旦至少一些离子已经进入离子阱，沿着离子阱的长度产生多个离子捕获区域，以分离离子。或者，离子可以被接收在一个或多个沿着离子阱平移的轴向捕获区域中，其速度逐渐减小到零。

9. 发明授权

US06770872B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US06770872B2
公开(公告)日：2004-08-03
申请号：US10301580
申请日：2002-11-22
申请人： Robert Harold Bateman , Jeff Brown , Anthony James Gilbert
发明人： Robert Harold Bateman , Jeff Brown , Anthony James Gilbert
IPC分类号： H01J4934
CPC分类号： H01J49/004 , H01J49/401 , H01J49/42
摘要： A mass spectrometer is disclosed comprising a mass selective ion trap such as a 3D quadrupole field ion trap upstream of a pusher electrode of an orthogonal acceleration Time of Flight mass analyser. According to a first embodiment bunches of ions are released from the ion trap and the pusher electrode is energized after a delay time which is progressively varied. According to a second embodiment ions are released from the ion trap in reverse order of mass to charge ratio with the ions having the largest mass to charge ratio being released first. By appropriate release of the ions from the ion trap it is possible to ensure that substantially all of the ions arrive at the pusher electrode at substantially the same time. According to both embodiments it is possible to achieve a duty cycle approaching 100% across a large range of mass to charge ratios.
摘要翻译：公开了一种质谱仪，其包括质量选择性离子阱，例如正交加速时间飞行质量分析仪的推进器电极上游的3D四极场离子阱。根据第一实施例，一束离子从离子阱中释放出来，并且推进器电极在逐渐变化的延迟时间之后通电。根据第二实施方案，离子从离子阱以与质荷比最大的离子的质荷比相反的顺序被释放。通过从离子阱适当释放离子，可以确保基本上所有的离子基本上同时到达推动器电极。根据两个实施例，可以实现在大范围的质荷比之间接近100％的占空比。

10. 发明授权

US07202473B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US07202473B2
公开(公告)日：2007-04-10
申请号：US10821548
申请日：2004-04-09
申请人： Robert Harold Bateman , Jeff Brown , Martin Green
发明人： Robert Harold Bateman , Jeff Brown , Martin Green
IPC分类号： H01J49/00 , H01J49/40
CPC分类号： H01J49/0036
摘要： A mass spectrometer is disclosed wherein the experimentally determined mass to charge ratios of ions are reported together with an error band for each mass to charge ratio determination. The error band may, for example, reflect a 95% probability or confidence that the real, true, actual or accepted mass to charge ratio of the ion lies within the error band. By accurately determining the error band the possible candidate ions in a database can be accurately restricted whilst also guarding against over restriction.
摘要翻译：公开了一种质谱仪，其中实验确定的离子质量与电荷比率与每个质荷比确定的误差带一起报告。例如，误差带可以反映出真实的，真实的，实际的或接受的离子质量与电荷比在误差带内的概率或置信度。通过精确地确定误差带，可以准确地限制数据库中的可能候选离子，同时也防止过度限制。

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