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    • 4. 发明申请
    • Amphoteric and cationic fluorescent whitening agents
    • US20050161184A1
    • 2005-07-28
    • US10508444
    • 2003-03-13
    • Goetz SchefflerPeter RohringerRene SchlatterTed Deisenroth
    • Goetz SchefflerPeter RohringerRene SchlatterTed Deisenroth
    • C07D251/70C07D251/50C07D251/68D21H21/30C07D413/14C07D43/14
    • C07D251/50B41M5/5227C07D251/68D21H21/30
    • A compound of the formula wherein A1 and A2 each, independently of one another, represent —SO3 or —SO3M, where M represents hydrogen, an alkaline or alkaline earth metal, ammonium or alkylammonium, B1 and B2 each, independently of one another, represent the moiety in which R1 represents hydrogen, a straight-chain C1-C12alkyl or branched C3-C12alkyl group which C2-C12alkyl and C3-C12alkyl group, respectively, may be interrupted by one or two heteroatoms and is unsubstituted or substituted by one or two —OH, —OC1-C4alkyl, —NH2, —NHC1-C4alkyl, —N(C1-C4alkyl)2, -N-pyrrolidino, -N-piperidino, -N-morpholino or —N+(C1C4alkyl)3 groups and R2 represents C1-C4alkyl, C2-C4hydroxyalkyl, —CH2CONH2, —CH2OOOH or —CH2OOO C1C4alkyl or, alternatively, B1 and B2 each, independently of one another, represent a group of the formula in which R3, R4 and R5 each, independently of each other, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl, the group —X′—NR6R7 or the group —X′—N+R3R6R7, whereby at least one of the substituents R4 and/or R5 represents —X′—NR6R7 or —X′—N+R3R6R7, X and X′ each, independently of each other, represent a straight-chain C2-C8alkylene or branched C3-Cealkylene chain, which is unsubstituted or substituted by one or two —OH or —C(═O)— groups, R6 and R7 each, independently of each other, represent hydrogen, C1-C4alkyl or, together with the nitrogen atom to which they are bound, complete a pyrrolidino, piperidino or morpholino ring and R2 is as previously defined and each D1 and D2, independently of one another, are either defined as for B1 and B2 or represent halogen, —NH2, C1-C4monoalkyl- or dialkylamino, said alkyl groups being unsubstituted or substituted by C1-C4alkoxy, amino, mono- or di-C1-C4alkylamino or tri-C1-C4alkylammonium; C2-C4hydroxyalkylamino, C2 C4di(hydroxyalkyl)amino, anilino, an aniline monosulphonic acid or sulphonamide residue or a 5- or 6-membered, saturated heterocyclic ring or, alternatively, mixtures of compounds of formula (1), a process for their preparation and the use thereof as fluorescent whitening agents, especially for paper.